Application of AAPFCO’s SUIP #25 Calculation and Enforcement David L. Terry Division of Regulatory Services University of Kentucky Topics for Consideration 1.

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Transcript Application of AAPFCO’s SUIP #25 Calculation and Enforcement David L. Terry Division of Regulatory Services University of Kentucky Topics for Consideration 1.

Application of AAPFCO’s SUIP #25 Calculation and Enforcement

David L. Terry Division of Regulatory Services University of Kentucky

Topics for Consideration 1. A Brief History of the Metal Standards 2.

SUIP No. 25:

What is it, anyway?

3. Some Arithmetic in Using the Standards

SUIP No. 25 A Brief History • • • •

1993

: Heavy Metals Task Force Discussed by Labeling and Definitions Committee to Address Concerns in CA (OP#47,p158)

1993

: Uniform Bills Committee decides to define ‘Adulteration’ to Include injury to humans, etc.(OP#48, p159)

1997

: ‘Adulteration’ made “Official” OP#51, p129)

1997

: “Fear in the Fields”-Added Urgency

SUIP No. 25 A Brief History (Cont.) •

1999

: First AAPFCO Metal Standards (SUIP No. 25) were the Canadian Standards-(OP# 52, p 55) •

2002

: SUIP No. 25 with the Tabular Risk Based Standards (OP# 55, p 57)

SUIP No. 25 What is it, Anyway??

• Risk-Based (Human Health Protective) • Probability Level-90% • Considered Most Likely Pathways of Ingestion • Used Published Literature to Assess Risk • Not Technology Based • Defines Adulteration

Enlighten Enforcement • Acceptable Standards:

SUIP No. 25

• Validated Methods: AOAC, et. al.

• Used as a condition for registration • Metal analysis not required on label • Statements acceptable on label are:

SUIP No. 26 “When applied as directed, this product meets the guidelines for metals adopted by the AAPFCO”

SUIP No. 27 “Information regarding the contents and levels of metals in this product is available on the internet:

http://www.aapfco.org/metals”

SUIP No. 27 “Information regarding the contents and levels of metals in this product is available on the internet:

http://www.regulatory-info-xx.com”

Where xx = Co. ID

Now for the Arithmetic **Calculation of Limits** • Getting Started – Need the Standards – Need to Understand the Standards • Fertilizer Information Needed – Available Phosphate (P 2 O 5 ) Guarantee – Micro-Nutrient Guarantees • Turn on Calculator

SUIP No. 25 Metals,Max. Allowable Conc.

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

per 1% P 2 O 5 ppm

13 10 3,100 61 1 42 250 26 420

per 1% Micro.* ppm

112 83 23,000 ** 463 6 300 ** 1,900 180 2,900**

SUIP No. 25 Footnotes Explanations * Micro-nutrients as defined by T-9 are:

B, Cl, Co, Cu, Fe, Mn, Mo, Na, and Zn

** Applies only when NOT GUARANTEED

To use the Table:

Products with Either A Guarantee for P OR Micro Nutr’s but not both:

Multiply the percent guaranteed P 2 O 5

or

guaranteed percentages of all micronutrients sum of the

as defined in Official Fertilizer Term T-9

in each product by the value in the appropriate column in the Table to obtain the maximum allowable concentration (ppm) of these metals.

The minimum shall be 6.0

value for P 2 O 5 utilized as a multiplier

The minimum value for micronutrients utilized as a multiplier shall be 1.0

To use the Table:

Products with Guarantees for both P and Micro Nutr’s:

 Multiply the guaranteed percent P 2 O 5 appropriate column,

and

by the value in the  multiply the sum of the guaranteed percentages of the micronutrients by the value in the appropriate column.  Utilize the

higher

of the two resulting values as the maximum allowable concentrations.

•Biosolids, and all compost products 4 , shall be adulterated when they exceed the levels of metals permitted by the

US EPA 40 CFR Part 503

. • Dried biosolids and manure, as well as manipulated manure products either separately or in combination, shall also be deemed adulterated when they exceed the levels of metal permitted by the

US EPA 40 CFR Part 503

. •Hazardous waste derived fertilizers (as defined by EPA) shall be adulterated when they exceed the levels of metals permitted by the

US EPA 40 CFR Parts 261, 266 and 268

.

DAP 18-46-0 Calculate the heavy metal limits for DAP that is being used at the rate of 200 pounds per acre.

DAP 18-46-0 (Cont.)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

DAP 18-46-0 (Cont.)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

598

DAP 18-46-0 (Cont.)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

598 460

DAP 18-46-0 (Cont.)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

598 460 142,600

DAP 18-46-0 (Cont.)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

598 460 142,600 2,806

DAP 18-46-0 (Cont.)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

598 460 142,600 2,806 46

DAP 18-46-0 (Cont.)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

598 460 142,600 2,806 46 1,932

DAP 18-46-0 (Cont.)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

598 460 142,600 2,806 46 1,932 11,500

DAP 18-46-0 (Cont.)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

598 460 142,600 2,806 46 1,932 11,500 1,196

DAP 18-46-0 (Cont.)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

598 460 142,600 2,806 46 1,932 11,500 1,196 19,320

DAP 18-46-0 Typical Findings

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

Found, ppm

10 6 4 3 12 19 2 60

Limits

598 460 142,600 2,806 46 1,932 11,500 1,196 19,320

Calculate the Metal Limits for: • Calcium(Ca) Enhanced 13-13-13 1.0% • Magnesium(Mg) 0.50% • Sulfur(S) • Boron(B) • Cobalt(Co) • Copper(Cu) • Iron(Fe) • Manganese(Mn) 1.0% 0.02% 0.005% 0.05% 0.10% 0.05% • Molybdenum(Mo) • Sodium(Na) 0.005% 1.00% • Zinc(Zn) 0.05%

Enhanced 13-13-13 • Calcium(Ca) • Magnesium(Mg) • Sulfur(S) • Boron(B) • Cobalt(Co) • Copper(Cu) • Iron(Fe) • Manganese(Mn) • Molybdenum(Mo) • Sodium(Na) • Zinc(Zn) • Total Micro’s 1.0% 0.50% 1.0% 0.02% 0.005% 0.05% 0.10% 0.05% 0.005% 1.00% 0.05% ?????

Enhanced 13-13-13 • Calcium(Ca) • Magnesium(Mg) • Sulfur(S) • Boron(B) • Cobalt(Co) • Copper(Cu) • Iron(Fe) • Manganese(Mn) • Molybdenum(Mo) • Sodium(Na) • Zinc(Zn) • Total Micro’s 1.0% 0.50% 1.0% 0.02% 0.005% 0.05% 0.10% 0.05% 0.005% 1.00% 0.05% 1.28%

Metal Limits (Micro-Based) for the

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc 13-13-13

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

Metal Limits(Micro-Based) for the

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc 13-13-13

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

143

Metal Limits(Micro-Based) for the

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc 13-13-13

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

143 106

Metal Limits(Micro-Based) for the

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc 13-13-13

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

143 106 -

Metal Limits(Micro-Based) for the

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc 13-13-13

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

143 106 593

Metal Limits(Micro-Based) for the

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc 13-13-13

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

143 106 593 8

Metal Limits(Micro-Based) for the

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc 13-13-13

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

143 106 593 8 -

Metal Limits(Micro-Based) for the

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc 13-13-13

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

143 106 593 8 2432 -

Metal Limits(Micro-Based) for the

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc 13-13-13

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

143 106 593 8 2432 230

Metal Limits(Micro-Based) for the

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc 13-13-13

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

143 106 593 8 2432 230 -

Metal Limits(P-Based) for the

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc 13-13-13

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

Metal Limits (P-Based) for the

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc 13-13-13

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

169

Metal Limits (P-Based) for the 13-13-13

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

169 130

Metal Limits (P-Based) for the 13-13-13

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

169 130 -

Metal Limits (P-Based) for the 13-13-13

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

169 130 793

Metal Limits (P-Based) for the 13-13-13

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

169 130 793 13

Metal Limits (P-Based) for the 13-13-13

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

169 130 793 13 -

Metal Limits (P-Based) for the 13-13-13

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

169 130 793 13 3,250 -

Metal Limits (P-Based) for the 13-13-13

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

169 130 793 13 3,250 338

Metal Limits (P-Based) for the

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc 13-13-13

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

169 130 793 13 3,250 338 -

Metal Limits for the 13-13-13 Choose the Higher of the Two

Metal

Arsenic Cadmium Cobalt Lead Mercury

P-Based

169 130 793

-

Mic-Based

Molybdenum Nickel

3,250

Selenium Zinc

338

**P-Based limits are applicable** 143 106 593 8 2,432 230 -

Custom Mix 20-5-24 with 0.1% B • Calculate the metal limits for this Custom Mix • Note the guarantees for P and B • We calculate the limits for P and then for the sum of the Micro-Nutrients, then, • Take the higher of the two

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (P-Based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (P-Based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

65

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (P-Based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

65 50

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (P-Based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

65 50 15,500

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (P-Based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

65 50 15,500 305

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (P-Based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

65 50 15,500 305 5

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (P-Based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

65 50 15,500 305 5 210

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (P-Based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

65 50 15,500 305 5 210 1,250

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (P-Based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

65 50 15,500 305 5 210 1,250 130

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (P-Based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

65 50 15,500 305 5 210 1,250 130 2,100

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

11.2

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

11.2

8.3

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

11.2

8.3

2,300.0

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

11.2

8.3

2,300 46.3

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

11.2

8.3

2,300 46.3

0.6

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

11.2

8.3

2,300 46.3

0.6

30

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

11.2

8.3

2,300 46.3

0.6

30 190

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

11.2

8.3

2,300 46.3

0.6

30 190 18

Fertilizer: 20-5-24 w/0.1%B Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

11.2

8.3

2,300 46.3

0.6

30 190 18 290

Fertilizer: 20-5-24 w/0.1%B The Limits-Choose the Higher

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum

Mic Based

11.2

8.3

2,300 46.3

0.6

30

P-Based

15,500 305 210

Nickel Selenium 190 18

1,250 130

Zinc 290

**Phosphorus Based Limits Are Applicable**

2,100

Fertilizer: Typical Findings

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

15-7-6 No Micro

2 2 1 3 2 2 0 31

10-27-18 W/1% Zn

8 3 6 3 8 61 .2

10,818

Fertilizer: 20-5-24 w/0.66%Zn Used at 200 lb/a (P-Based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420

Limits

65 50 15,500 305 5 210 1,250 130 2,100

Fertilizer: 20-5-24 w/0.66%Zn Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

Fertilizer: 20-5-24 w/0.66%Zn Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

74

Fertilizer: 20-5-24 w/0.66%Zn Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

74 55

Fertilizer: 20-5-24 w/0.66%Zn Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

74 55 15,180

Fertilizer: 20-5-24 w/0.66%Zn Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

74 55 15,180 306

Fertilizer: 20-5-24 w/0.66%Zn Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

74 55 15,180 306 4

Fertilizer: 20-5-24 w/0.66%Zn Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

74 55 15,180 306 4 198

Fertilizer: 20-5-24 w/0.66%Zn Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

74 55 15,180 306 4 198 1,254

Fertilizer: 20-5-24 w/0.66%Zn Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

74 55 15,180 306 4 198 1,254 119

Fertilizer: 20-5-24 w/0.66%Zn Used at 200 lb/a (Micro-based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

74 55 15,180 306 4 198 1,254 119 -

Fertilizer: 20-5-24 w/0.66%Zn The Limits-Choose the Higher

Metal Mic Based P-Based

Arsenic Cadmium Cobalt Lead Mercury Molybdenum 15,180

306

4 198 Nickel Selenium Zinc

1,254

119 -

**Chose The Higher of the Two Limits**

65 50

15,500

305

210

1,250

130

-

Zinc Sulfate-36% Zn Calculate the Limits

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

Multiplier:____36___

Zinc Sulfate-36% Zn Calculate the Limits

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

4,032 Multiplier:____36___

Zinc Sulfate-36% Zn Calculate the Limits

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

4,032 2,988 Multiplier:____36___

Zinc Sulfate-36% Zn Calculate the Limits

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

4,032 2,988 828,000 Multiplier:____36___

Zinc Sulfate-36% Zn Calculate the Limits

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

4,032 2,988 828,000 16,668 Multiplier:____36___

Zinc Sulfate-36% Zn Calculate the Limits

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

4,032 2,988 828,000 16,668 216 Multiplier:____36___

Zinc Sulfate-36% Zn Calculate the Limits

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

4,032 2,988 828,000 16,668 216 10,800 Multiplier:____36___

Zinc Sulfate-36% Zn Calculate the Limits

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

4,032 2,988 828,000 16,668 216 10,800 68,400 Multiplier:____36___

Zinc Sulfate-36% Zn Calculate the Limits

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

4,032 2,988 828,000 16,668 216 10,800 68,400 6,480 Multiplier:____36___

Zinc Sulfate-36% Zn Calculate the Limits

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900

Limits

4,032 2,988 828,000 16,668 216 10,800 68,400 6,480 Multiplier:____36___

Zinc Sulfate-36% Zn Typical Findings

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

Findings, ppm

24 63 43 527 1,100 1,316 10 -

Limits

4032 2988 828,000 16,668 216 10,800 68,400 6,480 Multiplier:____36___

Fertilizer: (P-Based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% P 2 O 5

13 10 3,100 61 1 42 250 26 420 Multiplier:_________

Limits

Fertilizer:(Micro-Based)

Metal

Arsenic Cadmium Cobalt Lead Mercury Molybdenum Nickel Selenium Zinc

ppm/1% Micro's

112 83 23,000 463 6 300 1,900 180 2,900 Multiplier:_________

Limits