Transcript 슬라이드 1 - Daelim Corporation

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[ETHYLENE GLYCOL MONOBUTYL ETHER
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MATERIAL SAFETY DATA SHEET
PRODUCT :YD-128 Standard Liquid
Epoxy Resin
First Edition : 2000.01.01
Emergency Telephone Number
061-688-6188 (24 hours)
Rev. No./ Date : 0 - 02/ 2008.08.01
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
■ CHEMICAL FAMILY: EPOXY RESIN
■ CAS NO: 25068-38-6
■ SUPPLIER INFORMATION
◦ SUPPLIER : DAELIM CORPORATION
◦ ADDRESS : 10F BLDG, 45 4GA NAMDAEMUNRO, JUNG-GU, SEOUL, KOREA
◦ TEL NO. : 82-2-3708-3000, 3114
◦ FAX No. : 82-2-777-9523
2. INGREDIENT
■ INGREDIENTS: Diglycidyl ether of bisphenol-A
■ WT(%): 100
■ ACUTE ORAL TOXICITY DATA LD 50: 10,000 – 11,400 mg/Kg
■ Trace Components: EPICHLOROHYDRIN (CAS No.: 106-89-8)
3. HEALTH INFORMATION
POTENTIAL HEALTH EFFECTS :
■ EYE CONTACT:
Direct contact may cause mild irritation.
■ SKIN CONTACT
Direct contact may cause mild irritation.
■ INHALATION
Vapor, especially upon heating may cause irritation of the respiratory tract.
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■ INGESTION
Not a probable route of entry into the body
■ SIGNS AND SYMPTOMS
Repeated and/or prolonged contact with the skin may cause allergic
reaction/sensitization.
■ AGGRAVATED MEDICAL CONDITIONS
Preexisting eye, skin and respiratory disorders may be aggravated by exposure
to this product. Preexisting skin or respiratory tract alleries may increase the chance
of developing increased allergy symptoms from exposure to this product.
■ OTHER HEALTH EFFECTS
Not available
4. OCCUPATIONAL EXPOSURE LIMITS
NO DATA
5. EMERGENCY AND FIRST AID
■ EYE CONTACT
Flush eyes with plenty of water for at least 15 minutes while holding eyelids open.
Call a physician if signs of irrigation appear.
■ SKIN CONTACT
Immediately remove contaminated clothing or shoes, wipe excess from skin and
flush with plenty of water for at least 15 minutes. Use soap if readily available, or follow
by thoroughly washing with soap and water. Do not reuse clthing until thoroughly
decontaminated.
■ INHALATION
Remove victim to fresh air and provide oxygen if breathing is difficult. Get medical
attention
■ INGESTION
Do not induce vomitting. Give one glass of water unless victim is drowsy,
convulsing, or unconscious. Seek medical attention immediatedy
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6.
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SUPPLEMENTAL Ⅵ HEALTH INFORMATION
Animal experiments have shown disturbed blood formation. The degree of toxicity
of uncured epoxy resins varies and is partly dependent on the extent of un-reacted
curing agents. When heated to decomposition it emits acrid smoke and fumes.
7 . PHYSICAL DATA
■ Boiling Point: NA
■ Vapor Pressure: 1 mmHg at180℃
■ Melting Point: NA
■ Vapor Density: >1.0 (Air=1)
■ Specific Gravity: 1.17 (H2O=1)
■ Solubility: Negligible (in water)
■ EVAPORATION RATE (N-BUTYL ACETATE=1) : <1
■ APPEARANCE AND ODOR : Clear, pale yellow liquid
■ VISCOSITY: 11,500 - 13,500cps (at 25℃)
■ Molecular Weight : 368 – 380
8. FIRE AND EXPLOSION DATA
■ FLASH POINT AND METHOD : 489F(254C) (PMCC)
■ EXTINGUISHING MEDIA
Use water fog, foam, carbon dioxide or dry chemical.
■ SPECIAL PRECAUTIONS
Toxic gases may be released during fire. Use positive-pressure, self-contained
breathing apparatus and full protective clothing.
■ UNUSUAL FIRE AND EXPLOSION
Isolate from heat, electricalequipment, sparks and opened flame. Wear selfcontained breathing apparatus.
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9. STABILITY AND REACTIVITY
■ CHEMICAL STABILITY : Stable
■ CONDITIONS AND MATERIALS TO AVOID
This product is normally stable and is not reactive with water.
■ HAZARDOUS POLYMERIZATION
Will not occur
■ HAZARDOUS DECOMPOSITION PRODUCTS
Not available
10. EXPOSURE CONTROLS/ PERSONAL PROTECTION
■ RESPIRATORY PROTECTION
Do not breathe vapors/mists. If exposure may or does exceed occupational
exposure (SEC. Ⅱ) use a NIOSH approved respirator to prevent overexposure.
In accord with 29 CFR 1910. 124 use either a full-face, atmosphere- supplying
respirator or air-purifying respirator for organic vapors.
■ PROTECTIVE CLOTHING
Do not get in eyes. Wear chemical goggles if there is potential content with eyes.
Do not get on clothing. Wear chemical-resistant protective clothing such as gloves,
outer clothing or apron, overshoes and a face shield suitable to potential exposure.
■ ENGINEERING CONTROLS
For the product at ambient temperatuers, use adequate ventilation. For the heated
product, use exhaust ventilation to remove vapor.
■ ADDITIONAL PROTECTIVE MEASURES
Eye wash fountains and safety showers should be available for emergency use.
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11. ENVIRONMENTAL PROTECTION
SPILL OR LEAK PROCEDURES
Ventilate area. Avoid breathing vapor. Wear appropriate personal protective equipment,
including appropriate respiratory protection. Contain spill if possible. Wipe up or absorb
on suitable material and shovel up. Prevent entry into sewers and waterways. Avoid
contact with skin, eyes or clothing.
12. HANDLING AND STORAGE
Store in a cool, dry place with adequate ventilation. Keep away from open flames and
high temperatures. Do not pressurize containers to empty them.
13. TRANSPORTATION REQUIREMENTS
■ DOT HAZARD CLASSIFICATION
FLAMMABLE LIQUID:
■ DOT PROPER SHIPPING NAME
EPOXY RESIN, LIQUID
■ OTHER REQUIREMENTS
*DOT - DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS
REGULATIONS
14. ECOLOGICAL INFORMATION
There is no data available for this product.
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15. DISPOSAL CONSIDERATIONS
Incineration is the recommended disposal method for all chemical wastes. Material
collected on absorbent material may be deposited in a land fill in accordance with all
applicable local, state and federal regulations.
16. REGULATORY INFORMATION
■ U.S REGULATIONS;
TSCA INVENTORY STATUS : Y
TSCA 12(b) EXPORT NOTIFICATION: Not listed
CERCLA SECTION 103 (40CFR302.4): N
SARA SECTION 302 (40CFR355.30): N
SARA SECTION 304 (40CFR355.40): N
SARA HAZARD CATEGORIES, SARA SECTIONS 311/312(40CFR370.21):
ACUTE : N
CHRONIC : N
FIRE : N
SUDDEN RELEASE : N
OSAH PROCESS SAFETY (29CFR1910.119): N
■ STATE REGULATIONS:
California Proposition 65: N
■ EUROPEAN REGULATIONS:
EC NUMBER: Not assigned