Transcript Document

14. 1
Heat and Material Balance Table
UNIFAC
chlro:0.25
ETHAN: 0.75
Stream ID
1
From
To
B1
Phase
LIQ UID
2
3
B1
B1
VAPOR
LIQ UID
Substream: MIXED
Mole Flow
kmol/hr
CHLOR-01
. 2500000
5. 41198E-8
. 2499999
ETHAN-01
. 7500000
4. 58802E-8
. 7500000
CHLOR-01
. 2500000
. 5411976
. 2500000
ETHAN-01
. 7500000
. 4588024
. 7500000
Mole Frac
Total Flow
kmol/hr
1. 000000
1. 00000E-7
. 9999999
Total Flow
kg/hr
64. 39604
8. 57432E-6
64. 39603
Total Flow
l/min
1. 096332
7. 08421E-5
1. 096332
Temperature
C
55. 00000
55. 00000
55. 00000
Pressure
bar
1. 000000
. 6329322
. 6329322
Vapor Frac
0.0
1. 000000
0.0
Liquid Frac
1. 000000
0.0
1. 000000
0.0
0.0
0.0
Solid Frac
Enthalpy
cal/mol
-56819. 67
-38589. 51
-56820. 00
Enthalpy
cal/gm
-882. 3472
-450. 0593
-882. 3524
Enthalpy
cal/sec
-15783. 24
-1.0719E-3
-15783. 33
Entropy
cal/mol-K
-70. 55954
-35. 08371
-70. 55878
Entropy
cal/gm-K
-1. 095712
-. 4091721
-1. 095701
Density
mol/cc
. 0152022
2. 35265E-5
. 0152022
Density
gm/cc
. 9789621
2. 01724E-3
. 9789621
64. 39604
85. 74316
64. 39604
1. 062595
1. 17098E-7
1. 062595
Average MW
Liq Vol 60F
l/min
14. 1
UNIFAC
chlro:0.5
ETHAN: 0.5
Hea t an d Mat er ia l B a la nce Ta b le
S tre a m ID
1
F ro m
To
B1
P ha se
L IQUI D
2
3
B1
B1
V AP OR
L IQUI D
S ub st re am : MIX ED
Mol e Fl ow
k m ol /h r
CHL OR -0 1
.5 00 0 00 0 7 .2 24 2 4E -8
.4 99 9 99 9
ET HAN-0 1
.5 00 0 00 0 2 .7 75 7 6E -8
.5 00 0 00 0
CHL OR -0 1
.5 00 0 00 0
.7 22 4 23 9
.5 00 0 00 0
ET HAN-0 1
.5 00 0 00 0
.2 77 5 76 1
.5 00 0 00 0
Mol e Fr ac
T ot al F lo w
k m ol /h r
1. 00 0 00 0 1 .0 00 0 0E -7
.9 99 9 99 9
T ot al F lo w
k g/ hr
82 .7 2 30 4 9 .9 02 8 5E -6
82 .7 2 30 3
T ot al F lo w
l/ m in
1. 19 1 23 4 5 .6 67 7 3E -5
1. 19 1 23 4
T em p e ra tu re
C
55 .0 0 00 0
55 .0 0 00 0
55 .0 0 00 0
P re ssu re
b ar
1. 00 0 00 0
.7 87 7 45 0
.7 87 7 45 0
V ap o r F ra c
0 .0
1. 00 0 00 0
0 .0
L iq ui d Fr ac
1. 00 0 00 0
0 .0
1. 00 0 00 0
S ol id F ra c
0 .0
0 .0
0 .0
E nt ha lp y
ca l/ m ol
- 48 2 39 .9 0
- 32 8 81 .5 4
- 48 2 40 .1 1
E nt ha lp y
ca l/ gm
- 58 3 .1 49 5
- 33 2 .0 41 3
- 58 3 .1 52 0
E nt ha lp y
ca l/ se c
- 13 3 99 .9 7
-9 .1 3 38 E -4
- 13 4 00 .0 3
E nt ro py
ca l/ m ol -K
- 61 .8 6 80 6
- 30 .7 5 10 7
- 61 .8 6 75 8
E nt ro py
ca l/ gm - K
- .7 47 8 94 0
- .3 10 5 27 6
- .7 47 8 88 1
Den si ty
m o l/cc
.0 13 9 91 0 2 .9 40 6 3E -5
.0 13 9 91 0
Den si ty
g m /cc
1. 15 7 38 6 2 .9 12 0 6E -3
1. 15 7 38 6
82 .7 2 30 4
99 .0 2 84 9
82 .7 2 30 4
1. 15 5 64 6 1 .2 38 4 3E -7
1. 15 5 64 6
A ve ra g e MW
L iq V ol 6 0F
l/ m in
14. 1
UNIFAC
chlro:0.75
ETHAN: 0.25
He at and M ate rial Bala nce Tab e
l
St rea m ID
1
Fr om
To
B1
Ph ase
LI QUI D
2
3
B1
B1
VAPOR
LI QUI D
Su bst rea m: M IXE D
M ole Flow
km ol/ hr
CHL OR- 01
.75 000 00
8. 212 45E -8
.74 999 99
ETHAN- 01
.25 000 00
1. 787 55E -8
.25 000 00
CHL OR- 01
.75 000 00
.82 124 47
.75 000 00
ETHAN- 01
.25 000 00
.17 875 53
.25 000 00
M ole Fra c
To tal Flow
km ol/ hr
1.0 000 00
1. 000 00E -7
.99 999 99
To tal Flow
kg /hr
101 .05 00
1. 062 73E -5
101 .05 00
To tal Flow
l/m in
1.2 915 49
5. 182 81E -5
1.2 915 49
Te mp era tur e
C
55. 000 00
55. 000 00
55. 000 00
Pr ess ure
ba r
1.0 000 00
.85 957 76
.85 957 76
0 .0
1.0 000 00
0 .0
1.0 000 00
0 .0
1.0 000 00
0 .0
0 .0
0 .0
Va por Fr ac
Liq uid Fra c
So lid F rac
En tha lpy
ca l/m ol
- 396 67. 70
- 297 68. 77
- 396 67. 85
En tha lpy
ca l/gm
- 392 .55 50
- 280 .11 65
- 392 .55 65
En tha lpy
ca l/se c
- 110 18. 81
-8 .26 91E -4
- 110 18. 85
En tro py
ca l/m ol-K
- 53. 519 25
- 28. 457 63
- 53. 518 89
En tro py
ca l/gm -K
- .52 963 12
- .26 777 90
- .52 962 76
De nsit y
m ol/c c
.01 290 44
3. 215 76E -5
.01 290 44
De nsit y
gm /c c
1.3 039 90
3. 417 48E -3
1.3 039 90
101 .05 00
106 .27 28
101 .05 00
1.2 486 96
1. 275 21E -7
1.2 486 96
Av era ge MW
Liq Vo l 60 F
l/m in
Heat and Material Balanc e Table
Stream ID
SRK
chro:0.25
ETHAN: 0.75
1
From
To
B1
Phase
LIQUID
2
3
B1
B1
VAPOR
LIQUID
Substream: MIXED
Mole Flow
kmol/hr
CHLOR-01
.2500000 4.35658E-8
.2500000
ETHAN-01
.7500000 5.64342E-8
.7499999
CHLOR-01
.2500000
.4356579
.2500000
ETHAN-01
.7500000
.5643421
.7500000
Mole Frac
Total Flow
kmol/hr
1.000000 1.00000E-7
.9999999
Total Flow
kg/hr
64.39604 7.80063E-6
64.39603
Total Flow
l/min
1.083227 9.08467E-5
1.083309
Temperature
C
55.00000
55.00000
55.00000
Pressure
bar
1.000000
.4939871
.4939871
Vapor Frac
0.0
1.000000
0.0
Liquid Frac
1.000000
0.0
1.000000
0.0
0.0
0.0
Solid Frac
Enthalpy
cal/mol
-57044.84
-41918.30
-57045.36
Enthalpy
cal/gm
-885.8440
-537.3710
-885.8519
Enthalpy
cal/sec
-15845.79
-1.1644E-3
-15845.93
Entropy
cal/mol-K
-70.95519
-37.50323
-70.95392
Entropy
cal/gm-K
-1.101856
-.4807721
-1.101837
Density
mol/cc
.0153861 1.83459E-5
.0153849
Density
gm/c c
.9908053 1.43110E-3
.9907306
64.39604
78.00625
64.39604
1.062595 1.13170E-7
1.062595
Average MW
Liq Vol 60F
l/min
Heat and Material Balance Table
SRK
chro:0.5
ETHAN: 0.5
Stream ID
1
From
To
B1
Phase
LIQUID
2
3
B1
B1
VAPOR
LIQUID
Substream: MIXED
Mole Flow
kmol/hr
CHLOR-01
.5000000
6.81915E-8
.4999999
ETHAN-01
.5000000
3.18085E-8
.5000000
CHLOR-01
.5000000
.6819152
.5000000
ETHAN-01
.5000000
.3180848
.5000000
Mole Frac
Total Flow
kmol/hr
1.000000
1.00000E-7
.9999999
Total Flow
kg/hr
82.72304
9.60589E-6
82.72303
Total Flow
l/min
1.176603
7.41643E-5
1.176681
Temperature
C
55.00000
55.00000
55.00000
Pressure
bar
1.000000
.6032633
.6032633
Vapor Frac
0.0
1.000000
0.0
Liquid Frac
1.000000
0.0
1.000000
0.0
0.0
0.0
Solid Frac
Enthalpy
cal/mol
-48434.30
-34156.96
-48434.72
Enthalpy
cal/gm
-585.4996
-355.5836
-585.5046
Enthalpy
cal/s ec
-13453.97
-9.4880E-4
-13454.09
Entropy
cal/mol-K
-62.01212
-31.26253
-62.01107
Entropy
cal/gm-K
-.7496354
-.3254518
-.7496228
Dens ity
mol/cc
.0141650
2.24726E-5
.0141641
Dens ity
gm/cc
1.171777
2.15869E-3
1.171700
82.72304
96.05888
82.72304
1.155646
1.22336E-7
1.155646
Average MW
Liq Vol 60F
l/min
Heat and Material Balance Table
SRK
chro:0.75
ETHAN: 0.25
Stream ID
1
From
To
B1
Phase
LIQUID
2
3
B1
B1
VAPOR
LIQUID
Substream: MIXED
Mole Flow
kmol/hr
CHLOR-01
.7500000
8.57297E-8
.7499999
ETHAN-01
.2500000
1.42703E-8
.2500000
CHLOR-01
.7500000
.8572968
.7500000
ETHAN-01
.2500000
.1427032
.2500000
Mole Frac
Total Flow
kmol/hr
1.000000
1.00000E-7
.9999999
Total Flow
kg/hr
101.0500
1.08916E-5
101.0500
Total Flow
l/min
1.271038
6.34109E-5
1.271107
Temperature
C
55.00000
55.00000
55.00000
Pressure
bar
1.000000
.7035779
.7035779
Vapor Frac
0.0
1.000000
0.0
Liquid Frac
1.000000
0.0
1.000000
0.0
0.0
0.0
Solid Frac
Enthalpy
cal/mol
-39880. 32
-28630. 37
-39880. 65
Enthalpy
cal/gm
-394. 6591
-262. 8671
-394. 6624
Enthalpy
cal/sec
-11077. 87
-7. 9529E-4
-11077. 96
Entropy
cal/mol-K
-53. 72487
-27. 18650
-53. 72405
Entropy
cal/gm-K
-. 5316660
-. 2496104
-. 5316579
Density
mol/cc
.0131126
2.62836E-5
.0131119
Density
gm/cc
1.325033
2.86270E-3
1.324961
101.0500
108.9158
101.0500
1.248696
1.28863E-7
1.248696
Average MW
Liq Vol 60F
l/min
Heat and Material Balance Table
Stream ID
PR
chro:0.25
ETHAN: 0.75
1
From
To
B1
Phase
LIQUID
2
3
B1
B1
VAPOR
LIQUID
Substream: MIXED
Mole Flow
kmol/hr
CHLOR-01
.2500000
4.25738E-8
.2500000
ETHAN-01
.7500000
5.74262E-8
.7499999
CHLOR-01
.2500000
.4257382
.2500000
ETHAN-01
.7500000
.5742618
.7500000
Mole Frac
Total Flow
kmol/hr
1.000000
1.00000E-7
.9999999
Total Flow
kg/hr
64.39604
7.72791E-6
64.39603
Total Flow
l/min
1.134094
8.72268E-5
1.134152
Temperature
C
55.00000
55.00000
55.00000
Pressure
bar
1.000000
.5140007
.5140007
Vapor Frac
0.0
1.000000
0.0
Liquid Frac
1.000000
0.0
1.000000
0.0
0.0
0.0
Solid Frac
Enthalpy
cal/mol
-56815.82
-42232.00
-56816.28
Enthalpy
cal/gm
-882.2875
-546.4870
-882.2946
Enthalpy
cal/sec
-15782.17
-1.1731E-3
-15782.30
Entropy
cal/mol-K
-70.34845
-37.86086
-70.34742
Entropy
cal/gm-K
-1.092434
-.4899240
-1.092418
Density
mol/cc
.0146960
1.91073E-5
.0146952
Density
gm/cc
.9463655
1.47659E-3
.9463171
64.39604
77.27906
64.39604
1.062595
1.12801E-7
1.062595
Average MW
Liq Vol 60F
l/min
Heat and Material Balance T able
Stream ID
PR
chro:0.5
ETHAN: 0.5
1
From
To
B1
Phase
LIQUID
2
3
B1
B1
V APOR
LIQUID
Substream: MIX ED
Mole Flow
km ol/hr
C HL OR-01
.5000000 6.73741E-5
.4999326
ET HAN-01
.5000000 3.26259E-5
.4999674
C HL OR-01
.5000000
.6737408
.4999826
ET HAN-01
.5000000
.3262592
.5000174
Mole Frac
T otal Flow
km ol/hr
1.000000 1.00000E-4
.9999000
T otal Flow
kg/hr
82.72304 9.54596E-3
82.71349
T otal Flow
l/min
1.189861
.0718496
1.189792
T emperature
C
55.00000
55.00000
55.00000
Pressure
bar
1.000000
.6220447
.6220447
V apor Frac
0.0
1.000000
0.0
Liquid Frac
1.000000
0.0
1.000000
0.0
0.0
0.0
Solid Frac
Enthalpy
cal/m ol
-48238.75
-34415.59
-48239.72
Enthalpy
cal/gm
-583.1357
-360.5251
-583.1563
Enthalpy
cal/s ec
-13399.65
-.9559886
-13398.58
Entropy
cal/m ol-K
-61.48797
-31.53637
-61.48772
Entropy
cal/gm-K
-.7432992
-.3303634
-.7433076
Dens ity
mol/c c
.0140072 2.31966E-5
.0140066
Dens ity
gm /cc
1.158722 2.21434E-3
1.158654
82.72304
95.45963
82.72177
1.155646 1.22031E-4
1.155524
A verage MW
Liq V ol 60F
l/min
Heat and Material Balance Table
PR
chro:0.75
ETHAN: 0.25
Stream ID
1
From
To
B1
Phase
LIQUID
2
3
B1
B1
VAPOR
LIQUID
Substream: MIXED
Mole Flow
kmol/hr
CHLOR-01
.7500000
8.53003E-5
.7499147
ETHAN-01
.2500000
1.46998E-5
.2499853
CHLOR-01
.7500000
.8530025
.7499897
ETHAN-01
.2500000
.1469975
.2500103
Mole Frac
Total Flow
kmol/hr
1.000000
1.00000E-4
.9999000
Total Flow
kg/hr
101.0500
.0108601
101.0392
Total Flow
l/min
1.246492
.0617934
1.246413
Temperature
C
55.00000
55.00000
55.00000
Pressure
bar
1.000000
.7211670
.7211670
Vapor Frac
0.0
1.000000
0.0
Liquid Frac
1.000000
0.0
1.000000
0.0
0.0
0.0
Solid Frac
Enthalpy
cal/mol
-39714.95
-28766.59
-39715.58
Enthalpy
cal/gm
-393.0226
-264.8834
-393.0318
Enthalpy
cal/sec
-11031.93
-.7990721
-11031.00
Entropy
cal/mol-K
-53.27470
-27.33855
-53.27437
Entropy
cal/gm-K
-.5272111
-.2517340
-.5272118
Density
mol/cc
.0133708
2.69716E-5
.0133703
Density
gm/cc
1.351125
2.92914E-3
1.351066
101.0500
108.6010
101.0493
1.248696
1.28703E-4
1.248568
Average MW
Liq Vol 60F
l/min
14.54
After selection of components, parameters are generated
1
2
3
Then, you will get results
(a)
P-xy diagram for BENZE-01/CARBO-01
1.955
1.950
x 100.0 C
y 100.0 C
1.945
1.940
1.935
1.930
1.925
1.920
1.915
1.910
1.905
1.900
1.895
1.890
P ress ure, bar
1.885
1.880
1.875
1.870
1.865
1.860
1.855
1.850
1.845
1.840
1.835
1.830
1.825
1.820
1.815
1.810
1.805
1.800
1.795
0.000 0.025 0.050 0.075
0.100 0.125 0.150 0.175 0.200 0.225 0.250
0.275 0.300 0.325 0.350 0.375 0.400
0.425 0.450 0.475 0.500 0.525 0.550 0.575
Liquid/vapor mole fraction, BENZE-01
0.600 0.625 0.650 0.675 0.700 0.725
0.750 0.775 0.800 0.825 0.850 0.875 0.900
0.925 0.950 0.975 1.000
(b)
P-xy diagram for BENZE-01/CYCLO-01
1.94
x 100.0 C
y 100.0 C
1.92
1.90
1.88
Press ure, bar
1.86
1.84
1.82
1.80
1.78
1.76
1.74
0.000
0.025
0.050
0.075
0.100
0.125
0.150
0.175
0.200
0.225
0.250
0.275
0.300
0.325
0.350
0.375
0.400
0.425
0.450 0.475 0.500 0.525 0.550
Liquid/vapor mole fraction, BENZE-01
0.575
0.600
0.625
0.650
0.675
0.700
0.725
0.750
0.775
0.800
0.825
0.850
0.875
0.900
0.925
0.950
0.975
1.000
(d)
P-xy diagram for BENZE-01/N-HEX-01
2.45
x 100.0 C
y 100.0 C
2.40
2.35
2.30
2.25
2.20
Press ure, bar
2.15
2.10
2.05
2.00
1.95
1.90
1.85
1.80
1.75
0.000
0.025
0.050
0.075
0.100
0.125
0.150
0.175
0.200
0.225
0.250
0.275
0.300
0.325
0.350
0.375
0.400
0.425
0.450 0.475 0.500 0.525 0.550
Liquid/vapor mole fraction, BENZE-01
0.575
0.600
0.625
0.650
0.675
0.700
0.725
0.750
0.775
0.800
0.825
0.850
0.875
0.900
0.925
0.950
0.975
1.000
(d)
P-xy diagram for BENZE-01/CYCLO-01
1.94
x 100.0 C
y 100.0 C
1.92
1.90
1.88
Press ure, bar
1.86
1.84
1.82
1.80
1.78
1.76
1.74
0.000
0.025
0.050
0.075
0.100
0.125
0.150
0.175
0.200
0.225
0.250
0.275
0.300
0.325
0.350
0.375
0.400
0.425
0.450 0.475 0.500 0.525 0.550
Liquid/vapor mole fraction, BENZE-01
0.575
0.600
0.625
0.650
0.675
0.700
0.725
0.750
0.775
0.800
0.825
0.850
0.875
0.900
0.925
0.950
0.975
1.000
Don’t input parameters
A is not ᴧ
If parameters added intestinally, you will get results on the next 4 slides
(a)
2.00
1.95
P-xy diagram for BENZE-01/CARBO-01
x 100.0 C
y 100.0 C
1.90
1.85
1.80
1.75
1.70
1.65
P ress ure, bar
1.60
1.55
1.50
1.45
1.40
1.35
1.30
1.25
1.20
1.15
1.10
1.05
1.00
0.000 0.025 0.050 0.075 0.100 0.125 0.150 0.175 0.200 0.225 0.250 0.275 0.300 0.325 0.350 0.375 0.400 0.425 0.450 0.475 0.500 0.525 0.550 0.575 0.600 0.625 0.650 0.675 0.700 0.725 0.750 0.775 0.800 0.825 0.850 0.875 0.900 0.925 0.950 0.975 1.000
Liquid/vapor mole fraction, BENZE-01
(b)
P-xy diagram for BENZE-01/CYCLO-01
1.80
x 100.0 C
y 100.0 C
1.75
1.70
1.65
1.60
1.55
1.50
P ress ure, bar
1.45
1.40
1.35
1.30
1.25
1.20
1.15
1.10
1.05
1.00
0.000 0.025
0.050 0.075 0.100
0.125 0.150 0.175 0.200
0.225 0.250 0.275
0.300 0.325 0.350
0.375 0.400 0.425 0.450 0.475 0.500 0.525 0.550 0.575 0.600
Liquid/vapor mole fraction, BENZE-01
0.625 0.650 0.675 0.700
0.725 0.750 0.775
0.800 0.825 0.850
0.875 0.900 0.925 0.950
0.975 1.000
(c)
P-xy diagram for BENZE-01/N-HEP-01
1.80
x 100.0 C
y 100.0 C
1.75
1.70
1.65
1.60
1.55
1.50
1.45
1.40
P ress ure, bar
1.35
1.30
1.25
1.20
1.15
1.10
1.05
1.00
0.95
0.90
0.85
0.80
0.75
0.000 0.025
0.050 0.075
0.100
0.125 0.150
0.175
0.200
0.225 0.250
0.275
0.300 0.325 0.350
0.375
0.400 0.425 0.450 0.475 0.500 0.525 0.550 0.575
Liquid/vapor mole fraction, BENZE-01
0.600
0.625
0.650 0.675
0.700
0.725
0.750
0.775
0.800 0.825
0.850
0.875 0.900 0.925
0.950
0.975 1.000
(d)
P-xy diagram for BENZE-01/N-HEX-01
2.45
2.40
x 100.0 C
y 100.0 C
2.35
2.30
2.25
2.20
2.15
2.10
2.05
2.00
1.95
1.90
Press ure, bar
1.85
1.80
1.75
1.70
1.65
1.60
1.55
1.50
1.45
1.40
1.35
1.30
1.25
1.20
1.15
1.10
0.000
0.025
0.050
0.075
0.100
0.125
0.150
0.175
0.200
0.225
0.250
0.275
0.300
0.325
0.350
0.375
0.400
0.425
0.450 0.475 0.500 0.525 0.550
Liquid/vapor mole fraction, BENZE-01
0.575
0.600
0.625
0.650
0.675
0.700
0.725
0.750
0.775
0.800
0.825
0.850
0.875
0.900
0.925
0.950
0.975
1.000