Transcript + I 2 + PO 4 3 - iannonechem.com

Electrochemistry
Lesson 6
Balancing
Redox
Reactions
Balancing Redox Full Reactions in Acid Solution
4.
3.
5.2.
1.
Simplify
Add
the two
half
reactions
Check
Separate
Balance
each
into
half
half
reaction
reactions
MnO4-
+
C2O42-
→
2( MnO4- + 4H+ + 3e- →
MnO2
MnO2
+ CO32+ 2H2O )
3(C2O42- + 2H2O → 2CO32- + 4H+ + 2e-)
2
4
2MnO4- + 3C2O42- + 6H2O + 8H+ → 2MnO2 + 6CO32- + 12H+ + 4H2O
-8
-8
2MnO4- + 3C2O42- + 2H2O → 2MnO2 + 6CO32- + 4H+
Balancing Redox Full Reactions in Basic Solution
1.
2.
- toacid
Balance
Add
OHin
neutralize
solutionthe H+
2MnO4- + 3C2O42- + 2H2O → 2MnO2 + 6CO32- +
4OH-
4H+
4OH2 4H2O
Balancing Redox Full Reactions in Basic Solution
2MnO4- + 3C2O42- + 4OH- → 2MnO2 + 6CO32- + 2H2O
-12
-12
Balancing Redox Full Reactions in Acid Solution
Fe
+
O2
4( Fe +
→
3H2O
3( 4e- + O2
+
H2O
→
4H+
+
3H+
Fe(OH)3
+ Fe(OH)3 + 3e -)
→ H20 + H2O)
6
4Fe + 12H2O + 3O2 +12H+ → 12H+ + 4Fe(OH)3 + 6H2O
4Fe + 6H2O + 3O2 → 4Fe(OH)3
0
0
Balance the redox reaction
As
→
H2AsO4+
AsH3
You must separate into two half reactions!
3(As +
5( 3H+
4H2O
+
As
→
H2AsO4-
+ 3e- →
(alkaline)
6H+ +
+
5e-)
AsH3 )
3As + 12H2O + 15H+ + 5As → 3H2AsO4-
3
+ 18H+ + 5AsH3
8As + 12H2O → 3H2AsO4- + 3H+ + 5AsH3
3OH3OH3OH- + 8As + 9H2O → 3H2AsO4- + 5AsH3
-3
-3
Balance the redox reaction
IPO4- →
IO3- +
I2
+
PO43-
You must separate into two half reactions!
(alkaline)
Balance the redox reaction
IPO4- →
IO3- +
I2
+
PO43-
You must separate into two half reactions!
IPO4-
→
+
PO43-
(alkaline)
Balance the redox reaction
IPO4- →
IO3- +
I2
+
PO43-
You must separate into two half reactions!
IPO4-
→
+
PO43-
IPO4-
→
+
PO43-
(alkaline)
Balance the redox reaction
IPO4- →
IO3- +
I2
+
PO43-
You must separate into two half reactions!
IPO4-
→
IO3-
+
PO43-
IPO4-
→
I2
+
PO43-
(alkaline)
Balance the redox reaction
IPO4- →
IO3- +
I2
+
PO43-
You must separate into two half reactions!
IPO4-
→
IO3-
+
PO43-
2IPO4-
→
I2
+
2PO43-
(alkaline)
Balance the redox reaction
IPO4- →
IO3- +
I2
+
PO43-
(alkaline)
You must separate into two half reactions!
IPO42IPO4-
+ 3H2O
→
IO3-
+
PO43-
→
I2
+
2PO43-
+
6H+
Balance the redox reaction
IPO4- →
IO3- +
I2
+
PO43-
(alkaline)
You must separate into two half reactions!
IPO4-
+ 3H2O
2IPO4- +
4e-
→
IO3-
+
PO43-
→
I2
+
2PO43-
+
6H+
+ 3e-
Balance the redox reaction
IPO4- →
IO3- +
I2
+
PO43-
(alkaline)
You must separate into two half reactions!
4(IPO4- + 3H2O
→
IO3-
+
PO43-
3(2IPO4- +
→
I2
+
2PO43-)
4e-
+
6H+
+ 3e-)
Balance the redox reaction
IPO4- →
IO3- +
I2
+
PO43-
(alkaline)
You must separate into two half reactions!
4(IPO4- + 3H2O
→
IO3-
+
PO43-
3(2IPO4- +
→
I2
+
2PO43-)
4e-
+
6H+
+ 3e-)
12H2O + 10IPO4- → 3I2 + 10PO43- + 24H+ + 4IO324OH24OH24OH- + 10IPO4- → 3I2 + 10PO43- + 4IO3- + 12H2O
-34
-34
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