Transcript Supplement of Online single particle analysis of ice particle

Supplement of Atmos. Chem. Phys., 17, 575–594, 2017
http://www.atmos-chem-phys.net/17/575/2017/
doi:10.5194/acp-17-575-2017-supplement
© Author(s) 2017. CC Attribution 3.0 License.
Supplement of
Online single particle analysis of ice particle residuals
from mountain-top mixed-phase clouds using
laboratory derived particle type assignment
Susan Schmidt et al.
Correspondence to: Johannes Schneider ([email protected])
The copyright of individual parts of the supplement might differ from the CC-BY 3.0 licence.
This supplement shows the laboratory mass reference mass spectra that were used to infer characteristic marker
peaks for a number of particle types.
Figures S1 through S12 show the data sampled at MPIC, Figures S13 though S20 those measured at the AIDA
facility of KIT. The mass spectra obtained from one particle type were clustered using the fuzzy c-means
algorithm as explained in the main text. Typically, the largest cluster (the most frequent spectrum type) is shown
and the percentage of spectra contained in this largest cluster is given. In certain cases, the two or three largest
clusters are shown, giving an indication on the variability of mass spectra from one particle type.
1)
191 spectra (51 %)
relative intensity
46
0.12
88
0.08
43
0.04
62
16 26
79
97
177
0.00
0
50
100
m/z
2)
150
40
0.25
0.20
0.15
0.10
0.05
0.00
0.16
200
44
57
56
23
12
0
50
184 spectra (55 %)
relative intensity
120
0.10
0.08
0.06
0.04
0.02
0.00
97
0
62
79
50
100
m/z
relative intensity
3)
43
26 42 46
97
0.00
50
100
m/z
150
50
200
23
130
42 46
79
0.00
0
50
100
m/z
150
200
100
m/z
150
200
39
56 63
0
50
150
43
200
63
40
0.10
0.08
0.06
0.04
0.02
0.00
62
0.04
100
m/z
40
126 spectra (26 %)
97
0.08
5)
relative intensity
0
43
0.12
200
23
0.25
0.20
0.15
0.10
0.05
0.00
79
0
86
12
23
27
39 44
56
30
18
0
132
65
50
100
m/z
150
200
150
200
150
200
40
91 spectra (25 %)
0.20
46
0.15
0.15
0.10
0.10
26
42
0.05
16
62
23
56 63
70
0.05
97 114
111
116
44
12
0.00
0.00
0
50
6)
relative intensity
200
0.12
0.04
150
56 63
122 spectra (41 %)
146
4)
relative intensity
150
0.16
0.08
100
m/z
40
0.25
0.20
0.15
0.10
0.05
0.00
46
26 33
43
63
100
m/z
150
200
46
0.20
0
50
100
m/z
153 spectra (27 %)
130
0.30
0.15
0.20
77
0.10
62
0.05
203
26
35
0.10
51
27
97
0.00
63
0.00
0
50
100
m/z
150
200
0
50
100
m/z
Figure S1: Average spectra of different amino acids from laboratory measurements at MPIC: 1) alanine;
2) cysteine; 3) glutamic acid; 4) leucine; 5) proline; 6) tryptophan.
relative intensity
7)
0.10
0.08
0.06
0.04
0.02
0.00
161 spectra (43 %)
79
43
97
72
0.08
116
46
63
23
27
0.04
189
50
100
m/z
150
200
50
0.20
0.15
0.15
0.05
62
27
0.05
97
0.00
150
200
100
m/z
150
200
100
m/z
150
200
100
m/z
150
200
100
m/z
150
200
100
m/z
150
200
39
40
0.10
26
100
m/z
23
0.20
0.10
56
0
93 spectra (72%)
42
118
12
18
0.00
0
relative intensity
40
62
8)
515766
82
0.00
0
50
100
m/z
9a)
97
relative intensity
39
0.12
150
200
0
55 spectra (40 %)
50
36
12
39
0.25
0.20
0.15
0.10
0.05
0.00
0.12
24
0.08
27
0.04
24
50
48
56
36
0.00
0
50
100
m/z
9b)
150
200
0
50
relative intensity
40
268 spectra (53 %; of all sampled spectra)
0.25
0.20
0.15
0.10
0.05
0.00
12
27
31
56 63
0
10a)
relative intensity
16 spectra (60 %)
42
0.12
79
46
62
97
0.00
0
10b)
50
100
m/z
56
0.25
0.20
0.15
0.10
0.05
0.00
26
0.08
0.04
50
150
200
27
12
54
40
0
50
281 spectra (53%; of all sampled spectra)
relative intensity
40
0.5
0.4
0.3
0.2
0.1
0.0
12 27
0
50
Figure S2: Average spectra of different substances biological origin from laboratory measurements at
MPIC: 7) valine; 8) riboflavin; 9) glucose; 10) sucrose.
relative intensity
11a)
71 spectra (40 %)
26
0.20
0.15
0.4
0.10
0.2
42
0.05
62
0.00
0
50
100
m/z
relative intensity
26
0.10
0.08
0.06
0.04
0.02
0.00
200
0
50
75
100
m/z
150
200
100
m/z
150
200
100
m/z
150
200
100
m/z
150
200
23
54 spectra (30 %)
0.3
40
43
24
0.2
42
36 46 62
79
94
0.1
97
12
27 46 56
72
0.0
0
50
100
m/z
12a)
97
relative intensity
150
72
46
0.0
11b)
150
200
0
50
39
0.15
0.15
42
0.05
0.05
26
0.00
12 27
15
0.00
0
50
56
0.10
79
0.10
81
40
23
150 spectra (60 %)
0.20
100
m/z
12b)
79
relative intensitiy
23
0.6
150
200
0
47
50
35 spectra (16 %)
56
0.12
0.30
0.08
0.20
26 42
0.04
97
0.10
59
0.00
0
50
27 4047
39
23 30 54
44
15
12
63
0.00
100
m/z
150
200
0
50
Figure S3: Average spectra of protein measurements from the laboratory measurements at MPIC: 11)
chlorophyll; 12) hemoglobin.
relative intensity
13a)
124 spectra (19 %)
97
0.30
12
0.20
0.10
36 48
0.00
relative intensity
40
23
56
45
138
0.00
50
100
m/z
150
200
0
50
100
m/z
173 spectra (27 %)
26
0.15
150
200
39
0.30
0.20
0.20
0.10
41
42
24
0.05
48
36
35
113
0.10
62
0.00
12
0.00
0
50
100
m/z
14a)
relative intensity
27
0.04
24
0
150
200
23
104 115
78
0
50
100
m/z
104 spectra (23 %)
26
0.25
0.20
213
150
200
39
0.4
0.3
0.15
0.10
0.05
24
36
35 48 62
71
0.00
0
41
0.2
42
50
0.1
62
12 2327
97
0.0
100
m/z
14b)
relative intensity
24
0.08
13b)
150
200
50
125
43
24
100
m/z
150
15)
200
200
86
0.00
50
150
58
195
0.00
200
36
27
0.04
160
150
18
12
0.08
0.04
100
3039
0.12
0.08
113
115
78
0
74 spectra (16 %)
97
0.12
0
0
50
100
m/z
173 Spektren (84 %)
97
relative Intensität
3639
0.12
81
23
0.12
0.15
96
0.08
99
24
0.04
95
45 60
158
50
100
m/z
150
39
56
0.00
200
83
24
0.05
135
0.00
0
40
46
0.10
0
50
97
100
m/z
139
150
200
Figure S4: Average spectra of different substances of biological/natural origin from the laboratory
measurements at MPIC: 13) fiber cellulose; 14) microcrystalline cellulose; 15) sea salt.
relative intensity
1)
178 spectra (42 %)
45
0.12
26
59
0.08
0.15
71
0.04
35
73
40
80
m/z
relative intensity
79
165 spectra (45 %)
0
63
97
50
100
m/z
79
0.25
0.20
0.15
0.10
0.05
0.00
150
80
m/z
115
120
39
0.25
0.20
0.15
0.10
0.05
0.00
0.2
26 42
75 85
40
0.4
0.0
44
12
120
0.6
3)
relative intensity
0.05
97
89
0.00
2)
41
47
27
56
200
70
40
136 spectra (38 %)
84
80
m/z
120
39
0.20
0.15
23
26
0.10
43
42
63
0
50
40
47
12
0.00
100
m/z
79
0.4
150
200
56
24
0.05
59 71
4)
relative Intensität
56
57
40
24
79
17
23
0.10
0.00
0
85
50
235 spectra (63 %)
113
100
m/z
150
200
39
0.20
0.3
0.15
0.2
0.1
39
0.20
43
26
42
0.0
40
40
41
0.10
43
0.05
5963 71
80
m/z
2324
15
47
59
58
56
63
113
0.00
120
40
80
m/z
120
Figure S5: Average spectra from the investigation of different types of pollen from the laboratory
measurements at MPIC: 1) birch; 2) hazel nut; 3) pine; 4) rye.
relative intensity
1a)
1863 spectra (13 %)
48
0.20
0.15
36
0.15
24
0.10
72
84 96
26
108
12
0.00
0
40
80
m/z
1b)
120 132144
120
relative intensity
relative intensity
12
72 84
120132
96 108
144156168180
0.00
160
0
50
100
m/z
5411 spectra (38 %)
0.20
1223
150
200
39
36
24
41
0.10
0.05
79
48 60
0.00
40
80
m/z
120
160
31 spectra (32 %)
48
50
120
100
150
200
250
150
200
250
150
200
250
150
200
250
23 39
0.06
36
0.15
0
85
m/z
24
0.20
36
41
0.04
0.10
48
60
26
0.05
72
0.02
97
84 96 108
132
0.00
0
40
80
m/z
2b)
120
63 84
60 72 96
12 27
120
132
0.00
160
0
50
100
m/z
22 spectra (22 %)
97
relative intensity
60
48
24
2a)
39
0.4
0.12
0.3
0.08
26
0.04
46 48
60 72
24
23
0.2
80
0.1
0.00
41
0.0
0
40
80
m/z
3a)
relative intensity
41
0.15
0
0.05
0.04
0.03
0.02
0.01
0.00
120
160
0
50
100
m/z
86 spectra (24 %)
48
25
39
0.6
24 26
0.4
60 72
36
46
0.2
84 96
108
97
35 42
41
23
0.0
0
40
80
m/z
3b)
48
relative intensity
36
0.05
97
0.25
0.20
0.15
0.10
0.05
0.00
23
60
0.10
0.05
39
120
160
0
100
m/z
155 spectra (44 %)
0.20
50
39
0.30
0.15
36
0.10
0.05
60
0.20
72
0.10
24
84 96
0.00
0
40
80
m/z
108 120
120
228
60
0.00
160
0
50
120 132
100
150
m/z
178
202
216 240
200
250
Figure S6: Average spectra of biomass burning particles from the laboratory measurements at MPIC: 1)
bangkirai; 2) brown coal; 3) beech.
4a)
504 spectra (18 %)
relative intensity
48
0.16
0.15
36
24
0.12
60
26
108
120 132
12
0.00
0.05
84 96
0
40
80
m/z
4b)
relative intensity
0.10
72
0.08
0.04
120
565 spectra (20 %)
60 72
36
26
35
96 108 120 132 144
80
m/z
120
80
m/z
120
39
23
0.2
84 96
46
108
97 120 132
0.00
40
80
m/z
0.1
144
120
0.0
41
12
40
160
3026 spectra (37 %)
24
relative intensity
72 84
0.4
5)
39
0.5
48
0.4
0.15
36
0.3
0.10
41
0.2
0.05
60
26
72
0.00
0.1
84 96 108
12
0
40
80
m/z
6a)
0.0
120
23
85
12
160
40
336 spectra (44 %)
48
relative intensity
40
0.3
24
60
48
12
160
25
0.08
0
80
m/z
120
39
0.30
0.12
24
0.08
60
36
72
0.20
84
0.04
41
96
0.10
108
26
23
120 132 144
0.00
48 60
0.00
0
40
80
m/z
6b)
120
160
0.06
0.05
0.04
0.03
0.02
0.01
0.00
0.20
0.15
24
36
60
0.10
72
0.05
84 96
0.00
0
40
80
m/z
40
169 spectra (22 %)
48
relative intensity
36
41
0.00
48
0.12
0.04
39
23
108
120 132
120
160
84
80
m/z
120 132
120
39
36
12 23 27
48
41
84
60
120 132
51 63 72
96
43
77
108
40
80
m/z
120
Figure S7: Average spectra of biomass burning particles from the laboratory measurements at MPIC: 4)
euro pallet; 5) spruce; 6) pine.
1)
99 spectra (29 %)
relativeintensity
24
0.12
25
36
48
0.08
0.04
35
60
0.00
0
40
69 7985 97
80
m/z
2)
120
relative intensity
0.4
0.3
0.2
26
42
0.0
0
relative intensity
97
63
40
3a)
159
80
m/z
120
97
0.12
0.08
79
0.00
0
40
80
m/z
120
97
0.20
116
91
50
100
m/z
150
200
56
0.10
0.08
0.06
0.04
0.02
0.00
47
40
27
30
3944
15
1218
54
6370
206
77
0
50
100
m/z
150
200
100
m/z
150
200
100
m/z
150
200
39
37 51
27 50
36
63
12
60
0
160
359 spectra (44 %)
50
12
0.15
0.15
120
63
60 77
15
0.10
0.08
0.06
0.04
0.02
0.00
80
25
26
50
36
344 spectra (43 %)
96
0.04
12
0
160
42
3b)
relative intensity
160
39
37
217 spectra (54 %)
79
0.1
27
0.10
0.08
0.06
0.04
0.02
0.00
77
91 104
115
36
24 37
0.10
0.10
0.05
27
0.05
79
40
56
0.00
0.00
0
40
80
m/z
120
160
0
50
Figure S8: Average spectra of different PAHs from the laboratory measurements at MPIC: 1)
benzo[ghi]perylene; 2) dibenzo(a,h)anthracene; 3) triphenylene.
relative intensity
4a)
265 spectra (31 %)
62
0.30
0.15
0.20
46
0.10
0.10
36
125
40
80
m/z
relative intensity
4b)
40
217 spectra (26 %)
12
91
80
m/z
120
80
m/z
120
36
24
0.15
0.10
79
26
12
62
36 46 60 63
48
80
27 40
0.05
0.00
80
m/z
120
40
241 spectra (74 %)
24
relative intensity
48 60
50
0.00
0.20
40
0.16
12 24 36
48
0.12
0.08
36
40
0.04
48
12
60
23
44
72
0.00
40
80
m/z
5b)
120
97
0.20
40
7 spectra (2 %)
79
0.05
16 24
46
120
80
m/z
120
24
39
0.10
0.10
80
m/z
23
0.15
0.15
0.05
36
12
2327
18
120
97
24
0.030
0.025
0.020
0.015
0.010
0.005
5a)
relative intensity
0.05
97
0.00
0.5
0.4
0.3
0.2
0.1
0.0
39
0.20
62
12
40
36
27
62
0.00
0.00
40
80
m/z
120
40
Figure S9: Average spectra of fuel exhaust particles from the laboratory measurements at MPIC: 4) fuel
exhaust; 5) incomplete combustion of fuel exhaust.
6a)
3464 spectra (19 %)
relative intensity
97
0.16
0.12
0.08
0.04
26
42
46
62
0.00
40
80
m/z
6b)
relative intensity
0.10
0.08
0.06
0.04
0.02
0.00
0.30
24
48 6063
15
120
40
0.10
0.08
0.06
0.04
0.02
0.00
0.20
42
0.10
77
115
80
m/z
2432 spectra (13 %)
50
0.00
62
80
m/z
120
27
12
36
41
24
50
15
63
91
120
40
80
m/z
4020 spectra (21 %)
26
relative intensity
50
51
39
40
115
120
39
0.30
0.12
0.08
0.20
42
0.04
36 46
97
0.10
113
27 36
78
115
80
m/z
120
0.00
40
80
m/z
120
97
40
5706 spectra (30 %)
26
39
27
0.08
46
0.08
0.06
62
42
36
12
51
0.04
0.04
63
24
0.02
0.00
15
48
60
77
115
0.00
40
8)
80
m/z
120
40
70 spectra (45 %)
26
0.10
0.08
0.06
0.04
0.02
0.00
12
62
0.00
0.12
41
24
7b)
relative intensity
36
12
26
7a)
relative intensity
39
27 37
80
m/z
39
0.4
0.3
42
0.2
24
0.1
36 48 59
41
12
113
104 115
27
0.0
40
120
80
m/z
120
40
80
m/z
120
Figure S10: Average spectra of particles from cigarette smoke from the laboratory measurements at
MPIC: 6) cigarettes with additives; 7) cigarettes without additives; 8) airborne measurement from
cigarette smoke without measurements.
1)
4903 spectra (54 %)
relative intensity
62
0.12
0.10
0.04
142
0.00
0
50
100
m/z
relative intensity
160
150
195
39
27 36
24
43
58
0.00
200
40
612 spectra (29 %)
46
80
m/z
120
72 84
96 108 120 132 144
80
m/z
120
39
36
0.15
48
0.10
24 36
60
26
72
0.05
84 97108
50
150
0.25
0.20
0.15
0.10
0.05
0.00
0.15
0.10
42
0.05
24 36 48
62
0.00
0
50
23
200
16 spectra (9 %)
26
0.20
48 60
12
0.00
100
m/z
100
m/z
3b)
150
40
39
41
27
36
12 23
43 55 63
200
40
70 spectra (38 %)
62
relative intensity
12
0.05
0.20
0
0.15
0.05
24 36
48
60
72
0.05
125
100
m/z
150
200
0.02
24 35
0.08
109 111
84
23
96 108 120 132
80
m/z
120
39
0.12
80
64
59 71
40
0.16
42
16
72 84
141 spectra (58 %)
97
26
23
0.00
96
93
0.06
46
48 60
12
50
0.04
120
39
0.10
97
0.00
0
80
m/z
0.15
46
0.10
113
91
36
0.20
4a)
relative intensity
18
62
0.12
0.10
0.08
0.06
0.04
0.02
0.00
3a)
relative intensity
0.15
97
0.08
2)
41
12
27 36
0.04
119 151 153
46
15
0.00
62
81
78
97
113
115
0.00
0
50
4b)
100
m/z
150
200
40
87 spectra (36 %)
26
relative intensity
30
125
120
39
0.16
0.15
80
m/z
23
0.12
0.10
24
0.05
0.08
48
42
36 50
97
46 60 72 84
36
12
27
41
0.04
15
0.00
48 60
81
97
113
0.00
0
50
100
m/z
150
200
40
80
m/z
120
Figure S11: Average spectra of particles from cook emissions/barbecue from the laboratory
measurements at MPIC: 1) background aerosol; 2) spilling of coal; 4) heating of the coal; 5) barbecuing of
cheese.
5a)
11 spectra (16 %)
relative intensity
42
39
0.12
0.12
0.08
0.08
26
27
62
0.04
35
23
46
97
0.04
0.00
43
36
12
15
120
0.00
0
50
100
m/z
5b)
150
200
40
relative intensity
24 36 48
0.10
42
5060
72 84 96
46
0.00
0
50
100
m/z
relative intensity
6)
23
36
40
26
35
64
46 59
80
71
84
97
111
119
0.00
104 113
88
80
m/z
120
23
0.10
0.05
151 153
72
39
0.20
0.15
16
48 56 60
0.25
0.04
41
12
200
63 spectra (93 %)
96
41
27
12
81 97 113
115
46 62
0.00
0
50
100
m/z
7)
26
relative intensity
150
93
0.06
0.02
120
39
0.25
0.20
0.15
0.10
0.05
0.00
0.20
0.05
80
m/z
6 spectra (9 %)
26
0.15
51 63
57 70 77
89
150
200
0
0.16
0.06
0.12
0.04
0.08
97
46
0.04
62
0.00
12
200
27
23
36
51
15
81
0.00
50
150
39
0.08
0
100
m/z
103 spectra (98 %)
42
0.02
50
100
m/z
150
200
40
80
m/z
97
113
120
Figure S12: Average spectra of particles from cook emissions/barbecue from the laboratory
measurements at MPIC: 5) barbecuing of sausages (smooth); 6) barbecuing of sausages (coarse); 7)
barbecuing of steak.
relative intensity
1a)
30 spectra (13 %)
26
0.20
23
42
0.15
0.15
0.10
0.05
45
71
80
m/z
120
81
40
97
113
104
0.3
0.12
80
m/z
120
39
74 spectra (32 %)
79
0.16
23
0.2
0.08
26
0.04
41
0.1
97
63
0.00
59
0.0
40
80
m/z
120
81
40
242 spectra (26 %)
79
relative intensity
56
59
0.00
2a)
97
80
m/z
113
120
39
0.4
0.15
0.3
23
0.10
0.2
42
0.05
26
63
0.1
89 97
0.00
40
80
m/z
120
310 spectra (33 %)
79
0.30
26
0.20
42
0.10
16
35
46
0.00
63 71
40
3a)
96
80
m/z
40
80
m/z
24
41
47
56
23
81
59
40
80
m/z
45 59 71
119
40
80
m/z
3b)
12
94
120
79
0.4
78
46
0.05
0.00
365 spectra (28 %)
0.3
120
41
0.10
96
113
62
0.15
42
97
39
0.20
16
120
39
642 spectra (49 %)
26
97
23
0.25
0.20
0.15
0.10
0.05
0.00
120
79
0.25
0.20
0.15
0.10
0.05
0.00
74
56
0.0
2b)
relative intensity
41
47
0.00
42
relative intensity
39
0.05
96
40
relative intensity
24
0.10
35
16
1b)
relative intensity
0.20
79
40
23
0.30
80
m/z
120
39
0.20
0.2
0.1
97
63
0.0
0.00
40
41
0.10
42
26
80
m/z
120
12
47
72
40
80
m/z
120
Figure S13: Average spectra of different bacteria types from the laboratory measurements at the AIDA:
1) PS-32b-74; 2) PF-CGina; 3) Snomax®.
1)
93 spectra (48 %)
relative intensity
97
0.4
39
0.20
0.15
0.3
12
0.10
0.2
0.1
30
2736
24
0.05
62
195
125
0.0
0
18
50
100
m/z
150
58
0.00
200
0
50
100
m/z
150
200
150
200
150
200
2)
122 spectra (50 %)
relative intensity
79
0.20
39
0.15
0.12
0.10
0.08
0.05
42 59 71
45 63
17
23
50
100
m/z
79
150
200
351 spectra (80 %)
0.16
26
45
0
100
m/z
39 58
0.20
74
71
89
35
0.00
50
0.10
59
0.04
0
0.15
97
0.08
85
59
42
0.12
56
15
0.00
0
47
0.04
97
0.00
3)
relative intensity
24
0.16
26
50
42
0.05
111
100
m/z
15
171
150
104
0.00
200
0
50
100
m/z
Figure S14: Average spectra of ground leaves and two different types of pollen from the laboratory
measurements at the AIDA: 1) maple leaves; 2) birch pollen; 3) sun flower pollen.
1a)
219 spectra (40 %)
relative intensity
76
0.15
79
0.10
0.05
42
0.08
40
relative intensity
0.10
0.05
115 spectra (21 %)
60
59
42
79
32
97
0.00
40
80
m/z
relative intensity
1c)
0.30
0.20
relative intensity
119
148
0.10
75
40
80
m/z
0.10
0.05
62
0.00
40
80
m/z
2b)
27
30
36
43
24
15
58
56
40
88
80
m/z
120
80
m/z
120
39
0.30
0.20
0.04
0.02
39
12
18
344 spectra (16%)
0.06
120
39 4854
7
120
97
0.08
80
m/z
27
23
891 spectra (42 %)
0.15
120
55
40
0.10
0.08
0.06
0.04
0.02
0.00
80
m/z
24
120
97
0.20
40
0.25
0.20
0.15
0.10
0.05
0.00
42
0.00
120
56
27
51 spectra (9 %)
16 24
80
m/z
39
0.5
0.4
0.3
0.2
0.1
0.0
120
26
2a)
relative intensity
40
16
26
83
120
76
64
70
0.00
0.20
0.15
54
43
23
7
119
80
m/z
1b)
48
0.04
5963
35
0.00
56
24
0.12
60
16 26
27 39
0.16
41
12
24
43
46
0.10
62
0.00
23 36
24
0.00
40
80
m/z
120
40
Figure S15: Average spectra of soil dusts with different origins from the laboratory measurements at the
AIDA: 1) Argentina; 2) Switzerland.
relative intensity
3a)
234 spectra (21 %)
26
0.4
0.3
0.2
24
16
0.1
42
75
0.0
0
50
100
m/z
relative intensity
3b)
150
0.10
0.08
0.06
0.04
0.02
0.00
relative intenisty
48
54
44
40
80
m/z
120
80
m/z
120
24
27
0.15
39
42
0.10
59
45
23
79
71
63
50
97
7
179
100
m/z
48 54
0.05
119
150
64
59
0.00
200
40
210 spectra (18 %)
79
39
0.6
0.06
76
0.4
60
0.04
42
63
26
0.02
0.2
45
17
71
0
50
100
m/z
150
200
104 spectra (29 %)
26
0.25
0.20
0.15
0.10
0.05
0.00
56
23 27
0.0
4a)
relative intensity
7
200
60
0
40
0
56
54
0.10
50
39
0.05
36 45
634879
16
150
200
42
16
0.04
24
79
71
97
0
50
100
m/z
79
0.12
0.10
0.08
0.06
0.04
0.02
0.00
24
150
0.00
200
47 spectra (13 %)
40
25 36
48
26
63
27
0.04
95
120
0.12
39
43
0.08
24
80
m/z
40 54
64
48 59
7
179
0.00
4c)
23
0.05
119
120
56
0.10
4559
80
m/z
27
0.15
60
7
12
37
36
15
55
51 63
67 77
0.00
0
50
100
m/z
150
200
96
39
0.20
26
64
59
40
25 spectra (10 %)
76
0.12
0.08
44
48
0.00
100
m/z
120
40
27
0.20
80
m/z
0.15
42
24
4b)
relative intensity
27
24
28
26
3c)
relative intensity
56
424 spectra (37 %)
76
16
39
0.25
0.20
0.15
0.10
0.05
0.00
40
80
m/z
91 105115
120
Figure S16: Average spectra of soil dusts with different origins from the laboratory measurements at the
AIDA: 3) China; 4) Germany.
relative intensity
5)
32 spectra (37 %)
97
0.4
0.3
0.2
0.1
24
36
0.0
0
50
100
m/z
relative intensity
36 39
24
23
27
40
28
0
56
48
44 50
138
73
40
80
m/z
120
160
120
160
74 spectra (25 %)
76
0.20
27 39
0.20
60
0.15
0.10
43 59
26 42
32
0.05
0.00
0
50
24
0.10
0.05
119
179
103
100
m/z
97
0.16
56
0.15
16
6b)
relative intensity
48
150
6a)
7
57 spectra (19 %)
23
48
54
0.00
150
0
6470 83 96
40
80
m/z
12
0.16
3639
0.12
0.12
24
0.08
0.08
24
0.04
23
96
0.04
36 48
0.00
40
27
56
138
0.00
0
50
6c)
100
m/z
16
relative intensity
12
0.12
0.10
0.08
0.06
0.04
0.02
0.00
150
0
40
120
160
80
m/z
120
160
24
51 spectra (17 %)
0.3
80
m/z
0.15
55
17
0.2
0.10
26
24
0.1
27
0.05
7
0.0
394048 57
23 28
54
69
0.00
0
50
100
m/z
150
0
40
Figure S17: Average spectra of different types of dust from the laboratory measurements at the AIDA: 5)
Ethiopian (volcanic dust); 6) Morocco (desert dust).
relative intensity
1a)
0.16
145 spectra (23 %)
16
54
56
35
0.3
0.12
0.2
0.08
37
88
0.04
0.00
40
80
m/z
120
12
40
0.04
80
m/z
120
relative intensity
80
m/z
42 spectra (5 %)
0.25
0.20
0.20
0.15
0.05
45
0.00
120
24
55
27
0.10
0.10
39 41 48
7
23
69
0.00
40
80
m/z
120
24
0.20
16
60
46
0.00
119
79
40
103
80
m/z
2c)
0.05
39
56
7
23
120
64
59 70
40
12
80
m/z
120
24
27
0.08
96
85
39
36
0.12
23
36 43 48
54
216 spectra (25 %)
24
0.08
48
0.00
97
0.04
120
0.10
59
0.05
80
m/z
27
0.15
43
0.10
40
251 spectra (29 %)
76
relative intensity
40
0.30
40 56
0.04
60
76
0.00
0.00
40
80
m/z
3)
50
4854
7
120
97
0.25
0.20
0.15
0.10
0.05
0.00
138
0.00
2b)
relative intensity
45 4856
23
36 48
17
0.12
27
24
40
0.15
24
0.08
0.05
0.00
120
36
39
0.12
0.10
80
m/z
117 spectra (18 %)
0.15
2a)
relative intensity
40
97
0.25
0.20
72
23
0.0
1b)
relative intensity
0.1
72
40
21 spectra (26 %)
12
0.12
138
70
80
m/z
120
36
24
39
0.08
27
0.04
24
36 48
40
96
23
62
40
56
4850
0.00
80
m/z
120
40
80
m/z
120
Figure S18: Average spectra of different types of minerals from the laboratory measurements at the
AIDA: 1) Hematite 2) Illite; 3) Kaolinite.
4a)
357 spectra (61 %)
relative intensity
76
23
0.16
0.20
0.12
0.15
39
40
60
0.08
16
56
0.10
0.04
0.05
59
43
119
35
70
0.00
0.00
0
50
100
m/z
4b)
150
200
40
66 spectra (11 %)
76
relaive intensity
27
80
m/z
120
39
27
0.15
0.12
83
56
60
0.10
16
0.08
59
26 45
79
42
71
32
0.04
0.05
119
50
100
m/z
7
179
0.00
0
23
150
48
43 54 64 70
85
0.00
200
40
80
m/z
120
Figure S19: Average spectra of Feldspar (FS05; Na-rich) from the laboratory measurements at the AIDA.
1a)
76 spectra (30 %)
relative intensity
46
0.30
0.08
0.04
0.10
35 48 62
24
60 72
2736
39
43
50 63
178
23
89
0.00
50
100
m/z
150
0.12
200
50
12
0.04
0.04
108
120132
46
0.00
50
100
m/z
2a)
24
0.15
0.02
156
150
200
73
50
202
100
m/z
150
200
60
12
100
m/z
24
28
0.05
84 96 108
120 132
0
132
120
96108
144
0.10
72
2b)
63 77
36
48
0.00
84
50
0.15
0.05
60
4550
0
0.20
36
0.10
200
0.00
60
0.20
48
39
24
23
89 spectra (49 %)
48
0.25
0.20
28
27
84 96
26
0
150
36
72
0.08
12
100
m/z
0.06
60
24 36
0
65 spectra (26 %)
48
relative intensity
12
0.02
0.00
0
relative intenisty
73
0.06
0.20
1b)
relative intensity
202
52
24
72 84
132
96 108120
144
0.00
150
200
0
37 spectra (20 %)
50
12
100
m/z
150
200
100
m/z
150
200
36
0.15
0.15
0.10
36
0.05
26
28
24
0.10
48
0.05
97
0.00
48
5260 73
84
0.00
0
50
100
m/z
150
200
0
50
Figure S20: Average spectra of two different types of soot from the laboratory measurements at the
AIDA: 1) CAST; 2) GSG.