Transcript Center for Nanoscale Materials Overview Eric D. Isaacs CNM Director

Center for Nanoscale Materials
Overview
Basic Energy Sciences Advisory Committee
Nanoscience Research Center Review
Eric D. Isaacs
CNM Director
February 23, 2004
Argonne National Laboratory
Pioneering
Science and
Technology
A U.S. Department of Energy
Office of Science Laboratory
Operated
The University
BESACbyNSRC
Review of Chicago
February, 23, 2003
Office of Science
U.S. Department
of Energy
Talk Overview
• Introduction to the Center for Nanoscale
Materials.
– Scientific themes.
– Technical capabilities.
– X-ray nanoprobe.
• Path to Operations
– User science and outreach programs
– Jumpstart
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Science and
Technology
BESAC NSRC Review
February, 23, 2003
Office of Science
U.S. Department
of Energy
Center for Nanoscale Materials
World-class research facility at
Argonne National Laboratory for
tackling the grand challenges of
nanoscience.
$ 72 M Federal/State Partnership
Pioneering
Science and
Technology
• $36 M DOE equipment funds.
• $36 M State-of-Illinois funds.
• Building completed in FY06.
• $18.5 M DOE operations funds
in FY07.
BESAC NSRC Review
February, 23, 2003
Office of Science
U.S. Department
of Energy
Global Nanoscience Challenges
To explore novel phenomena associated with the
interplay between spatial, physical and chemical
length scales and proximity effects.
To transform the art of nanomaterial and
nanodevice fabrication into a science.
To characterize the 3D structural, electronic,
magnetic and chemical properties of a single
nanoparticle.
To lay foundations for new technologies based on
the principles of nanoscience.
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of Energy
CNM Scientific Themes
Novel functional
nanocomposites
Self-assembled,
functionalized arrays
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Science and
Technology
bio-inorganic interface (D. Tiede, T. Rajh, CHM)
nanocarbon (D. Gruen, J. Carlisle, MSD)
nanomagnetism (S. Bader, A. Hoffman, MSD)
complex oxides (O. Auciello, S. Streiffer, MSD)
nanophotonics (G. Wiederrecht, CHM)
Virtual Fab Lab (S. Gray, CHM and P.
Zapol, MSD)
 X-ray Nanoprobe (B. Stephenson, MSD, J.
Maser)
Sub-wavelength photon confinement/propagation
BESAC NSRC Review
February, 23, 2003
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U.S. Department
of Energy
Center for Nanoscale Materials Principals
 World-class research facility for tackling the grand
challenges of nanoscience, transforming the art of
nanomaterials and nanodevices to a science.
 Open access for all users.
 best science via peer review (http://nano.anl.gov).
 Bringing new science and capabilities to ANL, the region
and the nation.
 Leveraging Argonne’s and regional strengths.
 One-stop access to BES facilities at Argonne: Advanced
Photon Source, Intense Pulsed Neutron Source, Electron
Microscopy Center.
 Complements four other BES NSRC’s.
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Technology
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February, 23, 2003
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U.S. Department
of Energy
Enabling Science through
Technical Capabilities
CNM experimental themes share
common technical activities:
Synthesis
– Self-assembly (chemical, electrochemical, sizeselected nanoparticles etc.)
– Thin film synthesis
Sculpting
– Nanolithography
– Milling and etching
Aligned
Polymer Scaffolds
Characterization
•
•
Investigate the synthetic process
Explore chemistry, physics, materials structure
& properties
Theory and Simulation
•
Leverage resources from ANL’s petaflop
initiatives and DOE/SC computing
infrastructure investment
Apertureless NSOM
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Technology
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of Energy
‘Assisted’ Self-Assembly Cross-Cuts Many
Themes in Nanoscience and the CNM
Stage 1: Substrate
with
lithographically
prepared trenches
Stage 2: Selfassembled diblock
copolymer aligning
within the trenches
Stage 3: 1-D
nanomag array
selectively adsorbs
on hydrophobic
polymer stripes
Darling, Lin, Bader (ANL)
Sibener, Jaeger (U of C)
Mirkin, Stupp (NU)
Example: Beyond GMR (> 5Mb/cm2)
1000 nm
Fe(CO)5 + Pt(acac)2 → FePt
100 nm
10 nm
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Science and
Technology
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February, 23, 2003
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U.S. Department
of Energy
Key Fabrication and Characterization Tools
Plasma-enhanced
CVD for carbon
LEO 1560XB CrossBeam
FIB/SEM
e-beam lithography
combined
SEM/SPM
Pioneering
Science and
Technology
BESAC NSRC Review
February, 23, 2003
Office of Science
U.S. Department
of Energy
The Center for Nanoscale Materials
Hard X-ray Nanoprobe
Hard X-ray Nanoprobe
Unique, versatile instrument to study individual
nanostructures (30 nm resolution).
Quantitative atomic-scale structure, strain, orientation
and imaging.
Sensitive trace element and chemical state analysis.
Operates in both scanning probe and full field.
Pioneering
Science and
Technology
Office of Science
combine hard/soft x-ray microscopy.
BESACFuture:
NSRC Review
U.S. Department
of Energy
February, 23, 2003
Grand Challenges for Nanoscience
with X-rays
• X-ray wavelength resolution.
• 3D structural, chemical, electronic and
magnetic properties at the nanoscale.
• Structure of single macromolecule.
• Dynamics of single nanoparticle.
• Coherent manipulation of nanoparticles
(LCLS).
• Nonlinear x-ray processes (LCLS).
Pioneering
Science and
Technology
BESAC NSRC Review
February, 23, 2003
Office of Science
U.S. Department
of Energy
Hard X-ray Imaging at the Nanoscale
Hard x-ray scanning probe
10 m
Coherent Diffraction
data
inversion
absolute electron density
Antiferromagnetic domains in
chromium
Evans, Isaacs, Aeppli, Lai & Cai,
Science 295, 1042 (2002).
e-coli bacteria
Miao, Hodgson, et al., Proc. Natl. Acad. Sci. USA, 100, 110 (2003).
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Technology
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of Energy
Facilities Beyond CNM….
• DOE BES User Facilities at
Argonne
– The Advanced Photon Source,
Intense Pulsed Neutron Source,
Electron Microscopy Center
– ‘one-stop’ user access to all four
• DOE’s other NSRCs
– The Center for Nanophase
Materials Sciences, The
Molecular Foundry, The Center
for Functional Nanomaterials,
The Center for Integrated
Nanotechnologies
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Technology
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of Energy
Center for Nanoscale Materials Building
•Adjacent to APS Sector 26
•Integrated with APS site design
•Utilize APS site utilities
Pioneering
Science and
Technology
BESAC NSRC Review
February, 23, 2003
Office of Science
U.S. Department
of Energy
Center for Nanoscale Materials Building
~85,000 gross square feet, including:
•13,000 sq ft Laboratories
•11,000 sq ft Cleanroom Facilities
•33,000 sq ft Offices & Public Spaces
Pioneering
Science and
Technology
BESAC NSRC Review
February, 23, 2003
Office of Science
U.S. Department
of Energy
Center for Nanoscale Materials Building
Public Space & Offices
Cleanrooms
Laboratories
Support
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Science and
Technology
BESAC NSRC Review
February, 23, 2003
X-ray
Nanoprobe
Beamline
Office of Science
U.S. Department
of Energy
CNM Operations
Mission: Supporting users in doing
outstanding science in a safe
environment.
Enabling world-class nanoscience
aligned with DOE’s scientific
mission.
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Science and
Technology
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February, 23, 2003
Office of Science
U.S. Department
of Energy
CNM Operations – Challenges
• Maintaining a balance between User
support and CNM science.
– Technical support for User science.
– Scientific leadership driving the future vision
for CNM.
• Staffing CNM with technical support to
provide our Users with the highest quality
support and to take full advantage of
phased operations schedule.
Pioneering
Science and
Technology
BESAC NSRC Review
February, 23, 2003
Office of Science
U.S. Department
of Energy
Equipment Cost/Schedule Phased Operations Plan
Dollars (cumulative to date)
phased ops (CD-4)
40,000,000
35,000,000
Project complete,
begin full ops
Funding
Commitments (BA)
30,000,000
Accept nanoprobe
Accept 10th piece
of tech. equipment
Accept building,
initial ops begin
25,000,000
20,000,000
Earliest install, Hoods
15,000,000
Accept 1st piece of tech. equipment
10,000,000
Start nanoprobe construction
Start building construction,
place HVEBL contract
5,000,000
Start equipment procurement
0
1
Oct 03
Pioneering
Science and
Technology
7
Apr 04
13
Oct 04
19
25
31
37
Apr 05 Oct 05toApr
06 Oct 06
Cumulative
Date
BESAC NSRC Review
February, 23, 2003
43
Apr 07 Oct 07
Office of Science
U.S. Department
of Energy
CNM Operations Funding Profile –
Phased Operations
CD-4b, full ops begin
CD-4a
20
Funding ($ M)
18
16
14
12
operations
jumpstart funding
10
8
6
4
2
0
FY03 FY04 FY05 FY06 FY07 FY08 FY09
Year
Pioneering
Science and
Technology
BESAC NSRC Review
February, 23, 2003
Office of Science
U.S. Department
of Energy
Projected CNM Staffing – Overview
80
visiting fellows
70
computing suppport
FTE
60
admin (direct)
nanoprobe
50
nanosynthesis
40
s
nanolithography
scientific themes
30
20
Includes 12 post docs
and six lead scientists
in FY08.
10
0
FY03 FY04 FY05 FY06 FY07 FY08 FY09
Year
Goal: full staffing by FY08 (2.5 years !)
Pioneering
Science and
Technology
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February, 23, 2003
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U.S. Department
of Energy
Estimated User Visits
(per month)
Estimated CNM User Visits
250
200
150
virtual fab lab
nanoprobe
nanosynth & charac.
100
nanolithography
50
0
FY03
FY04
FY05
FY06
FY07
FY08
FY09
Year
Pioneering
Science and
Technology
BESAC NSRC Review
February, 23, 2003
Office of Science
U.S. Department
of Energy
Example: Nanolithography User Activity
Projections
Lab
FY09
# users / # Tools / # users / # Tools /
month
Lab
month
Lab
LVEBL
HVEBL
FIB
Ebeam Resist
Opto Litho
Opto Resist
Metrology
Litho Chem
Wet Chem
RIE
Thermal
CVD/PVD
Bio
Chemical Storage
Gowning
28
16
16
60
28
28
88
88
12
60
0
32
20
70
139
1
1
1
12
2
14
4
7
6
3
1
4
7
Total
139
63
32
32
32
96
36
36
132
132
36
101
32
56
36
109
221
1
1
1
12
4
14
12
14
11
7
4
7
7
221
95
 CNM cleanroom user activities
 Lithography, Wet Chemistry,
Synthesis
 140 per month in FY06
 220 per month in FY09
 Tool increase by FY09 needed
to satisfy demand
60
 Existing low-voltage ebeam tool at
ANL has ~ 30 user visits/month
average.
Pioneering
Science and
Technology
BESAC NSRC Review
February, 23, 2003
Users / Month
FY06
50
40
30
20
10
0
Aug-03 Sep-03 Oct-03 Nov-03 Dec-03 Jan-04 Feb-04
Office of Science
U.S. Department
of Energy
Building the Foundations for a CNM User
Community
• Universities to play critical role in CNM.
– Nanoscience Workshops
• Northwestern (Oct.’03); Notre Dame (Jan.’04); U. of Mich.
(Spring ’04); EPSCoR States (June ’04),….
– Joint hires w/regional Universities – U of C, NU, UIC, …
– Consortium for Nanoscience Research.
• Joint ANL/U of C Institute – H. Jaeger, Dir., S. Bader, Deputy Dir.
• Scientific Theme/Technical Workshops.
• 1st CNM User Meeting, May 3 – 4, 2004.
• Developing a vision for the ‘Ultimate X-ray
Microscope’.
– Planning workshop at ANL in June ‘04.
Pioneering
Science and
Technology
BESAC NSRC Review
February, 23, 2003
Office of Science
U.S. Department
of Energy
Jumpstart Funding for CNM Science
• Jumpstart funds – $1.5M (FY03).
• CNM Post-doc fellow program (user outreach).
Alex Bouhelier – nanoplasmonics/photonics
Andrew Goshe – nanobiomaterials
Amanda Barnard – theory and modeling (Virtual Fab Lab)
Oliver Williams – nano-crystalline diamond
Yi Ji – nanomagnetism
Dolly Batra – bio-inorganic interfaces
Add three more post-docs in FY04
• High resolution e-beam lithography (ANL tool purchase).
Leo Ocola - Raith 150, 25 kV, JEOL, 100 kV (@ Bell Labs).
• User Program/Access.
Nena Moonier, User coordinator to start Feb. ’04 (50% APS).
Xiao-min Lin, website (50% MSD/CHM)
• Nanoscience Summer School 2003.
Pioneering
Science and
Technology
BESAC NSRC Review
February, 23, 2003
Office of Science
U.S. Department
of Energy
Nanoscience & Health
• Risk assessment
– Risk (cost) = Σ(severity of effects x probability of effects) + public
perception.
• Environmental & Workers Health Concerns.
– Physiology meets anatomy.
– Control technologies available (e.g., equipment & procedures for biohazards level 2).
• Public relations
– Following literature.
– Community forums (e.g., CNM building title II review).
• Opportunities
– Collaborating with other NSRC’s.
– Networking with researchers (e.g., A. Maynard, NIOSH).
– Support research.
Pioneering
Science and
Technology
BESAC NSRC Review
February, 23, 2003
Office of Science
U.S. Department
of Energy
Center for Nanoscale Materials Project Organization
DOE Associate Director, BES
P.M. Dehmer, Acquisition Executive for MIE
DOE NSRC Program Manager
K. Bennett
DOE CH – Argonne Area Office
R. Wunderlich,
Acquisition Executive for CNM building
CNM Federal Project Director
F. Gines
Scientific Advisory
Committee
E. Hu and R. Buhrman
CENTER FOR NANOSCALE MATERIALS
E. Isaacs, Director
Scientific Theme Leaders &
Stakeholders
Bionanocomposites, Nanomagnetism,
Nanophotonics, Nanocarbon,
Complex oxides, Virtual Fab Lab
WBS 1.1
Nanoprobe
B. Stephenson
Pioneering
Science and
Technology
WBS 1.2
Nanolithography and
Processing
L. Ocola
CNM Project
D. Mancini, Project Manager
WBS 1.3
Nanosynthesis and
Characterization
S. Streiffer
BESAC NSRC Review
February, 23, 2003
Project Advisory Committee
Dale Knutson, Chair
Exec. Secretary, S. Gunter-Harris
Assist. Division Director, J. Morgenthaler
User Coordinator, N. Moonier
ES&H Coordinator, B. Stockmeier
WBS 1.4
Project Management,
Integration & Infrastr.
D. Mancini
WBS 1.5
Conventional Facilities
K. Hellman
Office of Science
U.S. Department
of Energy
Center for Nanoscale Materials Participants
ANL Project Team Leaders
Derrick Mancini
Stephen Streiffer
Brian Stephenson
Leo Ocola
Karen Hellman
Sam Bader
(Bev Hartline)
DOE
Kristin Bennett
Tof Carim
Pat Dehmer
Frank Gines
Helen Kerch
Pedro Montano
Bill Oosterhuis
Robert Wunderlich
Pioneering
Science and
Technology
Scientific Theme Leaders
Orlando Auciello
Sam Bader
John Carlisle
Millie Firestone
Stephen Gray
Dieter Gruen
Axel Hoffman
Jorg Maser
Tijana Rajh
Brian Stephenson
Stephen Streiffer
David Tiede
Gary Wiederrecht
Peter Zapol
BESAC NSRC Review
February, 23, 2003
Other Key Participants
George Crabtree
Murray Gibson
Efim Gluskin
Heinrich Jaeger, U of C
Dale Knutson
Gabrielle Long
Lee Makowski
Bob Rosner
Steve Sibener, U of C
Al Wagner
Office of Science
U.S. Department
of Energy
CNM Scientific Advisory Committee
• Charter: Reports to Argonne Director, providing science and policy advice
at the highest level
• Reviews & advises on scientific themes & technical equipment plans
– First meeting May 2003
– Next meeting planned for Spring 2004.
• Membership
–
–
–
–
–
–
–
–
–
Robert Buhrman (Co-chair), Cornell University
Evelyn Hu (Co-chair), University of California Santa Barbara
Federico Capasso, Harvard University (previously with Lucent)
Daniel Chemla, Univ. Calif. Berkeley, Lawrence Berkeley National Lab
Vicki Colvin, Rice University
Heinrich Jaeger, University of Chicago
Barbara Jones, IBM Almaden Research Center
Janos Kirz, State University of New York, Stony Brook
Samuel Stupp, Northwestern University
Currently updating SAC to include biophysicist/chemist
Pioneering
Science and
Technology
BESAC NSRC Review
February, 23, 2003
Office of Science
U.S. Department
of Energy
Center for Nanoscale Materials
World-class research facility at
Argonne for tackling the
grand challenges of
nanoscience.
$ 72 M Federal/State Partnership
 transforming the art of
nanomaterials to a science.
 3D properties of a single
nanoparticle.
 laying the foundations for
future nanotechnologies.
Pioneering
Science and
Technology
BESAC NSRC Review
February, 23, 2003
Office of Science
U.S. Department
of Energy