Matter and Change Chapter 3 Diatomic Two atoms of the same element bonded together.
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Matter and Change Chapter 3 Diatomic Two atoms of the same element bonded together Phase A sample of matter that looks the same Substance A form of matter that has a uniform and unchanging composition…aka a pure substance The 3 Physical States of Matter Solid Liquid Gas Solid Definite shape and volume Atoms/molecules held rigidly in place Non-compressible Liquid No definite shape; takes the shape of its container; Non-compressible Definite volume Molecules are farther apart than those of a solid, allowing molecules to flow past one another Gas No definite shape nor volume Gases take the shape & volume of their container Gases are mostly empty space Compressible What is the physical state of each of the following at room temperature? gold gasoline helium bromine lithium nitrogen The 3 Chemical Classes of Matter Element Compound Mixture 1. Element A substance that can not be reduced to a simpler form The building blocks of all substances Made up of only one type of atom 3 Types of Elements Metals: to the left of the “stair-step.” They compose the majority of the elements Non-metals: are to the right of the “stairstep” Metalloids: are non-metals having some metallic characteristics 2. COMPOUNDS formed when 2 or more different elements join together chemically made of 2 or more different kinds of atoms joined in a definite pattern/arrangement are separated by chemical reactions into simpler substances 2 Types of Compounds ionic compounds: made up of a metal and a non-metal portion covalent compounds: composed of nonmetals Which of these are elements and which of these are compounds? Hg NaCl O2 H2O S8 3. Mixtures 2 or more distinct substances mixed together with variable composition may have distinct phases can be separated by physical methods Distillation Filtration chromotography 2 Types of Mixtures Homogeneous Heterogeneous Homogeneous Mixture: aka Solution (sol’n) Has a constant composition throughout always has a single phase can be any state of matter Give me some examples of solutions in each of the 3 states of matter. gas: Air nitrous oxide(dentist) liquid: salt water 7-up solid: gold ring, metal alloys Heterogeneous Mixture A mixture that does not blend smoothly throughout 2 or more distinct phases are visible What are some examples of a heterogeneous mixture? Which of the 3 are substances? Elements Compounds Mixtures Classify each of the following as elements, compounds, or mixtures. Silver pine tree orange juice oxygen iced tea air water Chemical Classes of Matter Separating Mixtures 1. 2. 3. 4. Filtration Distillation Crystallization Chromatography 1. Filtration Filtration: a technique that uses a porous barrier to separate a solid from a liquid. Separates heterogeneous mixtures of solids and liquids Filtration 2. Distillation A separation technique that is based on differences in the boiling points of the substances involved A mixture is heated until the substance with the lowest boiling point boils to a vapor that can then be condensed into a liquid and collected. Distillation 3. Crystallization A separation technique that results in the formation of pure solid particles of a substance from a solution containing the dissolved substance. ie. Rock candy Crystallization 4. Chromatography A technique that separates the components of a mixture based on the tendency of each to travel across the surface of another material. Chromatography Magnetic Attraction Using a magnet to remove magnetic substances Physical Properties of Matter Physical properties are characteristics that can be observed or measured without changing the sample’s composition intensive properties: are independent of sample size. ie. density, color, boiling point extensive properties are dependent on the amount of material present. ie. mass and volume Physical Changes of Matter Changes that alter a substance without changing its chemical composition ie. Changes in physical state Sublimation: solid to gas phase For example: Dry ice Boiling: liquid to gas How can you change the physical appearance without changing the state Chemical Properties of Matter Chemical properties are only observed in chemical reactions Reactivity: the tendency of a substance to undergo a particular chemical reaction when exposed to an agent. Examples 2H2O reactivity to electric current→ 2H2(g) + O2(g) H2O reactivity to alkali metals→ H2(g) [Cesium in water causes explosion] Fe reactivity to O2 + H2O (fog)→ Fe2O3(rust) Iron Oxide (you leave your bike out in the fog and it rusts) Reaction of Alkali Metals with water http://www.youtube.com/watch?feature=en dscreen&v=uixxJtJPVXk&NR=1 http://www.youtube.com/watch?v=jJGqC4v XBms Chemical Change A process that involves one or more substances changing into new substances Reactants: the starting materials in a chemical reaction Products: the newly formed substances from a chemical reaction 4 Indicators of Chemical Change: (often accompany chemical change) color change precipitate formation gas evolution heat evolution or heat absorption 2 Types of Reactions Exothermic: Heat is released/given off during a chemical reaction Endothermic: Heat is absorbed during the chemical reaction DEMOS: Examples of Chemical Change http://www.youtube.com/watch?v=wHqudw VOe9M http://www.youtube.com/watch?v=jJGqC4v XBms http://www.youtube.com/watch?feature=en dscreen&v=uixxJtJPVXk&NR=1 http://www.youtube.com/watch?v=REdFN7U91M&feature=player_detailpage Gas Formation Zn + 2 HCl → H2 (g) + ZnCl2 Color Change and Precipitate Formation 2 KI + Pb(NO3)2 → 2 KNO3 + PbI2 (s) http://www.youtube.com/watch?v=REdFN7U91M&feature=player_detailpage Conservation of Mass In a chemical reaction, matter is neither created nor destroyed, but it can change from one form to another. Mass of Reactants= Mass of Products → Material Balance Conservation of Mass From a lab experiment designed to separate water into hydrogen and oxygen, a student collected 10.0 g of hydrogen and 79.4 g of oxygen. How many grams of water were originally present? Chemistry is the study of the composition of substances and the changes they undergo. In chemistry, a specific language is used when referring to elements. What do you notice about the letters on the periodic table? Periodic Table of Elements Groups: (Families) the vertical columns on the periodic table. Periods: Horizontal Rows. Each element is represented by a symbol Symbols are one to three letters The first letter is always capitalized, 2nd & 3rd letters are always lower case. Often the chemical symbols coincide with the spelling of the element, but other times the symbols were derived from the Latin name for the element. Periodic Table of Elements, cont. Metals: Good conductors of heat and electricity. In general, they are malleable, ductile, lustrous, etc Non-Metals: Poor conductors of heat and electricity. Solids are brittle Metalloid: Having characteristics of both metals and non-metals Chemical symbols Can be used to represent chemical formulas. The numerical subscripts tell the proportion of each element in a compound or diatomic element. Tell me how many of each type of atom are in the following: NaCl CO2 HF H2 Mg3(PO4)2 IUPAC International Union (of) Pure & Applied Chemistry IUPAC-developed a systematic way of naming elements that are 1st synthesized One-syllable root word to represent numbers 0-nil 1-un 2-bi 3-tri 4-quad 5-pent 6-hex 7-sept 8-oct 9-enn To write the name for synthesized elements: Use the root word for each number in the element Add –ium to the ending Examples 110→… 124 →… 139 →.... To write the chemical symbol for the element: Take the 1st letter of each root word, capitalize it and lower case the 2nd and 3rd examples 113 → 156 → 213 → Law of Definite Proportions: States that regardless of the amount, a compound is always composed of the same elements in the same proportion, by mass. For example, water, is always H2O… Which is ~11% Hydrogen And ~89% oxygen Percent by mass (%): mass of element x 100 Mass of compound Mass of Compound: the sum of the masses of the individual elements that make up the compound. Example A sample of an unknown compound contains 5.3 g oxygen and 20.0 g of copper. What is the percent by mass of each element in the compound? Law of Multiple Proportions States that when different compounds are formed by a combination of the same elements, different masses of one element combine with the same relative mass of the other element in a ratio of small whole numbers Ratios: Compare the relative amounts of any items or substances Express the relationship of elements in a compound Mass Ratio 1. Mass of element in a compound = ratio Mass of other element in compound 2. Mass ratio compound I = small whole numbers Mass ratio compound II *find the mass ratio for each compound, then divide the two ratios to give a small whole # ratio Example: Analysis Data of Two Iron Compounds Are Compounds I and II the same compound? If not, use the law of multiple proportions to show the relationship between them. Compound I II Total Mass 75.00 56.00 Mass Mass O Fe (g) (g) 52.46 22.54 43.53 12.47 Mass % Fe 69.95 77.73 Mass %O 30.05 22.27 Example cont.