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Composites. An overview For CME/MSE 404G 7/18/2015 cme/mse 404g composite overview 1 Outline • Composite examples • Fiber-reinforced composites • Matrices and fibers • Effects of fiber orientation 7/18/2015 • Multiple lamellae structures • Fiber/matrix wetting • Composites manufacturing • Typical composite design challenges cme/mse 404g composite overview 2 Composite examples. Properties, performance, processing, structure Composite push rod Tires Brake shoes 7/18/2015 cme/mse 404g composite overview 3 Composite Push Rod For Automobiles •Properties Collin. MSE 556. Spring, 2006 High compressive and tensile strength along the axial direction; (secondary) stiff with respect to torsion, bending and shear; temperature resistance; chemical resistance to lubricants and fuel gases •Structure Composite push rods are lighter weight replacements for metallic push rods in use between a cam shaft and a valve rocker in internal combustion engines. These composite push rods are constructed of a bar that is made of carbon fiber. These composite push, bars generally have flat ends to which rounded metal end fittings are bonded, usually by some type of epoxy or adhesive. The composite push rod then attaches to the cam shaft and valve rocker via these rounded metal end fittings. 7/18/2015 •Performance Failure mechanisms: overloading (tensile/compressive), torsion, off axis loading, fatigue, crack growth/delamination less of a concern •Processing In order to construct the composite push rod, the bar is first constructed and then the ends are bonded. The bar is constructed of a plurality of layers of sheets of epoxy impregnated, longitudinally oriented fiber material that are wrapped around a removable mandrel. The sheets of longitudinally oriented fiber material form the inner portion of the push bar and a single outside sheet of epoxy impregnated, woven fiber material that is wrapped around the sheets of longitudinally oriented fiber material forms the outside portion of the bar. The sheets of fiber material are comprised on a fiber, such as carbon, Kevlar, or glass, and the fiber material is resin impregnated with a thermosetting, high temperature, toughened epoxy. Once all of the layers of fiber material are wrapped together, they are heated and compressed to thermo-set the layers into a single composite bar. The mandrel is then removed, leaving a central opening in the bar where the mandrel was located. The ends of the composite bar are then cut to the proper shape and the mating surfaces of the metal end fittings are bonded to the ends of the composite bar via epoxy, thereby completing construction of the composite push rod. cme/mse 404g composite overview 4 Performance Tires Optimal performance is achieved by proper use and maintenance. Understanding the labeling or sidewall markings is key. Example: P215/65R15 89H P: passenger, vs. LT that has higher ply ratings 215: width 65: aspect ratio R: radial, vs. belted construction or diagonal construction 15: diameter of wheel 89: load index--indicates the max weight each tire can support H: speed rating—measurement of top safe speed the tire can carry a load under specified conditions. (worst to best: Q,S,T,U,H,V,Z,W,Y) *a higher rated tire will give better traction and improved steering response at 50 mph. Also consider: -Max. cold inflation (in psi) see images below!**very important -Load limit (redundant to load index) -treadware grading--how long the tread will last -traction grading—indicates tires ability to stop in a straight line on wet pavement -temp grading—min speed a tire will not fail at high temp. 7/18/2015 Processing 1. The process begins with the mixing of basic rubbers with process oils, carbon black, pigments, antioxidants, accelerators and other additives, each of which contributes certain properties to the compound. These ingredients are mixed in giant blenders called Banbury machines operating under tremendous heat and pressure. They blend the many ingredients together into a hot, black gummy compound that will be milled again and again. 2. This compound is fed into mills which feed the rubber between massive pairs of rollers,feeding, mixing and blending to prepare the different compounds for the feed mills, where they are slit into strips and carried by conveyor belts to become sidewalls, treads or other parts of the tire. Still another kind of rubber coats the fabric that will be used to make up the tire's body. Many kinds of fabrics are used: polyester, rayon or nylon. 3. Another component, shaped like a hoop, is called a bead. It has high-tensile steel wire forming its backbone, which will fit against the vehicle's wheel rim. The strands are aligned into a ribbon coated with rubber for adhesion, then wound into loops that are then wrapped together to secure them until they are assembled with the rest of the tire. Radial tires are built on one or two tire machines. The tire starts with a double layer of synthetic gum rubber called an innerliner that will seal in air and make the tire tubeless. 4. Next come two layers of ply fabric, the cords. Two strips called apexes stiffen the area just above the bead. Next, a pair of chafer strips is added, so called because they resist chafing from the wheel rim when mounted on a car. The tire building machine pre-shapes radial tires into a form very close to their final dimension to make sure the many components are in proper position before the tire goes into the mold. 5. Now the tire builder adds the steel belts that resist punctures and hold the tread firmly against the road. The tread is the last part to go on the tire. After automatic rollers press all the parts firmly together, the radial tire, now called a green tire, is ready for inspection and curing. 6. The curing press is where tires get their final shape and tread pattern. Hot molds like giant waffle irons shape and vulcanize the tire. The molds are engraved with the tread pattern, the sidewall markings of the manufacturer and those required by law. Tires are cured at over 300 degrees for 12 to 25 minutes, depending on their size. As the press swings open, the tires are popped from their molds onto a long conveyor that carries them to final finish and inspection. **This is traditional technique by goodyear, new automated processes are used by 404g 5 pirelli. composite cme/mse overview References: 1010tires.com, goodyeartires.com, us.pirelli.com Properties Structure RUBBER PERCENT BY WEIGHT IN A NEW RADIAL PASSENGER TIRE Typical phsyical properties of a universal tire Physical Properties Universal Hardness (Shore A,D) 67A Compression Modulus (psi) 900 Deflection @ 100psi 11.56 Deflection @ 300psi 26.71 Tear Strength (pli) Tensile Strength (psi) Weight % for Passenger Tire Natural 14 % rubber Synthetic rubber 27% Carbon black 28% Steel 14 - 15% 249 2,950 Ultimate Elongation (%) 690 300% Modulus (psi) 990 Bayshore Rebound (%) 38 Compression Set (%) 13 Fabric, fillers, accelerators,a ntiozonants, etc. TREAD BASE 21.9% BEAD APEX 5.0% BEAD INSULATION 1.2% FABRIC INSULATION INNERLINER www.superiortire.com 11.8% 9.5% 12.4% 3.9 % UNDERCUSHION Hardness (Shore A,D) - measures resistance to indentation. A "soft" elastomer & D for "harder" materials. Compression Modulus (psi) - force required to achieve a specific deflection, typically 50% deflection, predicts a material's rigidity or toughness. Tear Strength (pli) - measures the resistance to growth of a nick or cut when tension is applied to a test specimen, critical in predicting work life Tensile Strength (psi) - ultimate strength of a material when enough force is applied to cause it to break, with elongation and modulus, tensile can predict a material's toughness. Ultimate Elongation (%) - percent of the original length of the sample measured at point of rupture. 300% Modulus (psi) - stress required to produce 300% elongation. Bayshore Rebound (%) - resilience of a material. ratio of returned energy to impressed energy. predicts rolling resistance. Compression Set (%) - measures the deformation remaining in an elastomer after removal of the deforming force. In combination withcme/mse rebound, set values predict an 7/18/2015 404g composite elastomer's success in a dynamic application. overview http://www.p2pays.org/ref/11/10504/html/intro/tire.htm 1.7% SIDEWALL INSULATION OF STEEL CORD 16 - 17% 32.6% 100.0% 6 Brake Shoes Properties Density (gm/cc) 1.80 - 2.00 Rockwell Hardness (HRL) 75 – 100 Busting Strength (rpm)> 12,000Max. Continuous Operating Temp.200°CMax. Transient Operating Temp. 300°C Structure Performance *Riveted linings provide superior performance, but good quality bonded linings are perfectly adequate. *Organic and non-metallic asbestos compound brakes are quiet, easy on rotors and provide good feel. But this comes at the expense of high temperature operation. *In most cases, these linings will wear somewhat faster than metallic compound pads, so you will usually replace them more often. But, when using these pads, rotors tend to last longer. *The higher the metallic content, the better the friction material will resist heat. Processing The pad or shoe is composed of a metal backing plate and a Casting metal backing plate friction lining. Electric Infrared ovens used Friction materials vary between manufacturers and type of Shoe Prep pad: asbestos, organic, semi-metallic, metallic. Washing, Delining ,Shot Blasting, return of shoes to OE Exotic materials are also used in brake linings, among which specs, relining, riveting are Kevlar® and carbon compounds. Phenolic polymer matrix composites are used as brake pad/shoe materials. As a new disc/drum materials, aluminimum metal matrix composites (Al MMCs) are attractive for their lightweight (three times lighter than cast iron) properties, higher thermal conductivity, specific heat, 7/18/2015 cme/mse 404g composite 7 superior mechanical properties and higher wear resistance over cast iron. overview Fiber-reinforced composites 7/18/2015 cme/mse 404g composite overview 8 Applications. Fiber-reinforced composites • Aircraft and military – F14 horizontal stabilizers, 1969. • Space – boron fiber-reinforced aluminum tubes, Kevlar/epoxy pressure vessels • Automotive – body (Class A finish, polyurethanes), chassis (Corvette rear leaf spring), engine • Sporting goods –weight redution • Marine – boat hulls, decks, bulkheads 7/18/2015 cme/mse 404g composite overview 9 Fiber alignment • • • • Unidirectional, continuous Bidirectional, continuous Unidirectional, discontinuous Random, discontinuous Fibers + matrix + coupling agents + fillers 7/18/2015 cme/mse 404g composite overview lamina 10 Matrix and fiber properties 7/18/2015 cme/mse 404g composite overview 11 Resin Properties 7/18/2015 cme/mse 404g composite overview 12 Common commercial matrices • Thermosets: epoxies, polyester, vinyl ester, phenolics, polyimides • Thermoplastics: nylons, linear polyesters, polycarbonate, polyacetals, polyamideimide, PEEK, PSul, PPS, PEI • Metallic – Al alloys, Ti alloys, Mg alloys, copper alloys, nickel alloys, SS • Ceramic – aluminum oxide, carbon silicon carbide, silicon nitride 7/18/2015 cme/mse 404g composite overview 13 Fiber properties • • • • • • Specific gravity Tensile strength, modulus Compressive strength, modulus Fatigue strength Electrical, thermal conductivity cost 7/18/2015 cme/mse 404g composite overview 14 Fiber Properties 7/18/2015 cme/mse 404g composite overview 15 Effect of fiber diameter on strength Fiber that are formed by spinning processes usually have increased strength at smaller diameters due to the high orientation that occurs during processing. 7/18/2015 cme/mse 404g composite overview 16 Common commercial fibers • • • • • • Glass Graphite Kevlar 49 PE (Spectra) Boron Ceramic – SiC, Al2O3 7/18/2015 cme/mse 404g composite overview 17 Effects of fiber orientation Continous, aligned fibers. Morphology and mechanical properties 7/18/2015 cme/mse 404g composite overview 18 Representative Element of an Aligned-Fiber Bundle 7/18/2015 cme/mse 404g composite overview 19 (a) Micrograph of a carbon epoxy composite (b) square packing array 7/18/2015 cme/mse 404g composite overview 20 Stiffness of a unidirectional carbon epoxy laminate as a function of test angle relative to fiber direction 7/18/2015 cme/mse 404g composite overview 21 Effect of average fiber volume Vf on the axial permeability of an aligned-fiber bundle 7/18/2015 cme/mse 404g composite overview 22 Fiber volume fraction (Vf) 7/18/2015 cme/mse 404g composite overview 23 Viscosity change and cure cycle for graphite/epoxy composite (Hercules AS4/3501-6) In general, matrix viscosity increases with temperature until the polymer cures to the gel state. Above this temperature, local chain motion is restrained by crosslinks, and additional curing for higher crosslinking can require long “post-cure” times. 7/18/2015 cme/mse 404g composite overview 24 Fiber volume fraction Vf versus processing viscosity, µ. common polymer matrix systems 7/18/2015 cme/mse 404g composite overview 25 Multiple lamellae structures Design issues 7/18/2015 cme/mse 404g composite overview 26 Linear Fiber Structure [0/90/0] 7/18/2015 cme/mse 404g composite overview 27 Top and side views of woven (interlaced) fibers 7/18/2015 cme/mse 404g composite overview 28 Combination fiber structure showing linear fibers and interlacing through the thickness 7/18/2015 cme/mse 404g composite overview 29 Illustration of idealized, linear 3D fiber structures 7/18/2015 cme/mse 404g composite overview 30 Stacking sequence of a (0/90±45)s quasi-isotropic layup Symmetric layups prevent warping under stress, thermal expansion 7/18/2015 cme/mse 404g composite overview 31 In-plane stiffnesses of various-ply geometries as a function of test angle, relative to the on-axis stiffness of a unidirectional laminate 7/18/2015 cme/mse 404g composite overview 32 Relative modulus vs. fiber volume fraction Range of obtainable elastic moduli for various composites normalized by the fiber modulus, Ef, versus the fiber volume fraction (configuration indicated) 7/18/2015 cme/mse 404g composite overview 33 Fiber/matrix wetting Wetting of the fibers by the matrix material 7/18/2015 cme/mse 404g composite overview 34 Illustration of spontaneous wetting (a) at t=t0 and (b) at t>t0 Matrix material is often added to fiber assemblies, and needs to wet the fibers in order to prevent void formation. 7/18/2015 cme/mse 404g composite overview 35 Surface Energies 7/18/2015 cme/mse 404g composite overview 36 Resin infiltration of unidirectional glass fibers in [0/90] layup showing the formation of voids Resin has wicked into several orthogonal lamellae, forming voids (bubbles). The slight refractive index difference between fiber and matrix allows the fiber directions to be observed. 7/18/2015 cme/mse 404g composite overview 37 Composites processing Hand lay-up,+/- molds, filament winding, pultrusion, resin transfer molding, vacuum forming 7/18/2015 cme/mse 404g composite overview 38 Schematics of (a) hand layup and (b) mechanically assisted hand layup 7/18/2015 cme/mse 404g composite overview 39 Several bagged composite parts being rolled into the autoclave for cure 7/18/2015 cme/mse 404g composite overview 40 Schematic of the filament winding process 7/18/2015 cme/mse 404g composite overview 41 Examples of unstable fiber paths in the filament winding process 7/18/2015 cme/mse 404g composite overview 42 Filament winding of a rocket motor tube e.g., booster rocket 7/18/2015 cme/mse 404g composite overview 43 Schematic of automatic tow placement process showing seven axes of motion 7/18/2015 cme/mse 404g composite overview 44 Automatic fiber placement of the V-22 aft fuselage section on the Cincinnati-Milacron seven-axis CNC fiber placement machine 7/18/2015 cme/mse 404g composite overview 45 Inside view of the fiber placed V-22 fuselage section secured with stiffeners 7/18/2015 cme/mse 404g composite overview 46 Schematic of the pultrusion process 7/18/2015 cme/mse 404g composite overview 47 Examples of pultruded part cross sections including airfoil shapes and structural skins and stiffeners 7/18/2015 cme/mse 404g composite overview 48 Examples of pultruded part cross sections including airfoil shapes and structural skins and stiffeners 7/18/2015 cme/mse 404g composite overview 49 Schematic of the resin transfer modeling process showing (a) fiber preform and (b) resin injection into fiber preform 7/18/2015 cme/mse 404g composite overview 50 The body panels for the Chrysler Viper are made by resin transfer molding (RTM) 7/18/2015 cme/mse 404g composite overview 51 Schematic of the double diaphram forming process 7/18/2015 cme/mse 404g composite overview 52 Double-diaphragm-formed parts produced from graphite/epoxy prepregs and then cured (upper-curved Cchannel; lower-radio-controlled car chassis) 7/18/2015 cme/mse 404g composite overview 53 Typical composite design challenges 7/18/2015 cme/mse 404g composite overview 54 Example of how microstructural details can lead to warping or shape changes in the composite along with the solutions for the problem 7/18/2015 cme/mse 404g composite overview 55 Alternate assembly methods illustrated for a curved C-channel 7/18/2015 cme/mse 404g composite overview 56