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Bentonite
Uses and Sources
Overview
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Made up mainly of montmorillinite,
(Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2·nH2O
Formed from the weathering of volcanic ash beds
Named for Fort Benton, WY, where it was first
described as part of a Cretaceous tuff sequence
Grades vary, but it is generally impure, with
inclusions of other smectite minerals, as well as
quartz, feldspar, calcite, and gypsum
Exhibits a number of unique properties
(IMA-NA 2007)
Properties & Applications
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Thixotropy
– Can be semi-solid at rest, but
will be liquid when agitated
– Used as a thickening and suspension agent in
paints, dyes, and varnishes
(KSGS 2002)
Properties & Applications
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Cohesion
– Binder and pelletizer
– Ironworks: ore pellets for
feeding into furnaces, and
as a binder in casting sand
molds
(MiningLife 2005)
Properties & Applications
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Absorption / Adsorption
– Can absorb several times it dry weight in water
– Pet litter, impermeable clay liners, wastewater
treatment, detergent purification, paper pulp
purification, de-inking
(IMA-NA 2007)
Properties & Applications
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Inertness
– Won’t kill you to eat it!
– Filler in pharmaceuticals, animal feed, and
cosmetics
– Purifier and clarifier in beer, wine, and honey
(WSGS 2007)
Properties & Applications
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Viscosity and Plasticity
– Drilling: vertical and horizontal
– Lubricates the bit, seals the walls of the borehole,
removes drill cuttings
– Additive in Portland cement,
mortars, and specialized plasters
(WSGS 2007)
Bentonite as a Value-Added Commodity
Bentonite is not often taken straight from the ground
to market.
 Much purification is often undergone to specialize
the product
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Sieving (for granular bentonite)
Milling (fine and superfine powdered bentonite)
Removal of associated gangue minerals
Treated with acids (“bleaching earths”)
Treated with organics (“organoclays”)
(IMA-NA 2007)
Bentonite Producers & Refiners
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AMCOL International (miner, refiner, large producer
of bentonite products)
Aqua Technologies (organoclay water treatment)
Black Hills Bentonite LLC (miner and 1st-stage
refiner)
BPM Minerals LLC (producer)
CETCO (special-purpose bentonite products)
Montana Bentonite LLC (producer and refiner)
…and MANY others
Production Methods
Drilling & Sampling
 Soil Profiling (to aid in
speedy recovery after
reclamation)
 Topsoil & Overburden
removal (usual with
scrapers)
 Quarrying with loader &
truck
 Only economic to mine
bentonite with no more than
50 feet of overburden
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(WMA-Minelife 2007)
Simplified Bentonite Mill Flow-Chart
(WMA Minelife, 2007)
World Reserves and Production Statistics
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Reserves of all clays used
by man are extremely large,
and are thought to be
inexhaustible on human
timescales
As a result, no concrete
measurements of world
reserves have been
performed
It is still a very lucrative
sector. US production in
2005 amounted to 42
million tons worth $1.7
(Numbers are in thousands of metric tons)
billion
(USGS 2007)
Worldwide Distribution
(Mindat 2007)
End Use Statistics
(USGS 2005)
Works Cited
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Industrial Minerals Association of North America, www.ima-na.org, (Accessed March 23, 2007).
Kansas State Geological Survey, http://vulcan.wr.usgs.gov/LivingWith/VolcanicPast/Notes/bentonite.html,
(Accessed March 27, 2007).
Mindat, http://www.mindat.org/min-9141.html, (Accessed March 27, 2007). MiningLife Media,
http://www.mininglife.com/commodities/Bentonite.asp, (Accessed March 25, 2007).
WMA-Minelife, http://www.wma-minelife.com/bent/bentmine/bentmine.htm, (Accessed March 27, 2007).
Wyoming State Geological Survey, http://www.wsgs.uwyo.edu/minerals/bentonite.aspx, (Accessed
March 27, 2007).
USGS, http://minerals.usgs.gov/minerals/pubs/commodity/clays/, (Accessed March 27, 2007).
USGS, 2005, Bentonite statistics, in Kelly, T.D., and Matos, G.R.,comps., Historical statistics
for mineral and material commodities in the United States: U.S. Geological Survey Data Series
140, available online at http://pubs.usgs.gov/ds/2005/140/ . (Accessed March 27, 2007.)