Proposed Agenda
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Transcript Proposed Agenda
Advancing the Science of Metal Finishing Technology
for Defense Applications
UltraCemTM
5th Generation Nickel Boron
To Replace Chromium Plating
Presented to HCAT by Chuck McComas
April 2003
Copyright UCT Defense LLC, 2003
Page 1
UCT Defense – A Joining of Forces
Metal Finishing Technologies for:
• Defense
• Armaments
• Aerospace
• Ground Vehicles
• Maritime
• Forestry
• Foundries
• Industrial Pumps
• Molds & Tooling
• Oil & Gas
Copyright UCT Defense LLC, 2003
• Special Operations
• Information Protection and
Assurance
• Digital Signal Processing
• Design and development
of process control and
instrumentation devices
• Radar design
• Environmental
technologies
• Technical analysis and
programmatic support
Page 2
Characteristics of UltraCemTM
•
Metallurgical bond
•
Dense nodular structure
•
Uniform deposition (99%) – sharp edges, bore holes,
complex part. No post grinding required
•
Provides lubricity – reduced coefficient of friction
•
Hardness values (1200-1400HK25)
•
Provides 3X wear resistance
•
Coating adheres to flexible substrates
•
Provides wear surface for ferrous, aluminum, titanium,
powdered metals
•
No hydrogen embrittlement
•
Heat tolerance to 1600 degrees F
Copyright UCT Defense LLC, 2003
Page 3
Structure of UltraCemTM
Nodular growth with true metallurgical bond.
Copyright UCT Defense LLC, 2003
Page 4
Uniformity of UltraCemTM
Due to the electroless plating
process, UltraCem plates at a
very high degree of Uniformity.
Complete Uniformity
Cross Cut Gear
Copyright UCT Defense LLC, 2003
Page 5
NiB Plate Composition
PWA 259
Type I
Type II
Nickel
Balance
Balance
Boron
2.5-8.5%
2.5-5.0%
Thallium
--
2.5-6.0%
Cobalt
--
0.0-2.0%
AMS 2433B
Type I
Type II
Nickel
Balance
Balance
Boron
2.5-5.0%
2.5-8.5%
2.5%-6.0%
--
0.0-2.0%
--
Thallium
Cobalt
Copyright UCT Defense LLC, 2003
Page 6
Evolution of Nickel-Boron
Earlier generations of Nickel-Boron
coatings had a high degree of voids,
leading to reduced corrosion
resistance and sheer strength.
(Magnification 500x)
Copyright UCT Defense LLC, 2003
UltraCemTM (5th generation)
provides increased hardness and
wear resistance while providing a
high level of lubricity. Cubic inch
density is greatly increased
resulting in higher shear strength.
(Magnification 500x)
Page 7
Bath Characteristics of UltraCemTM
Bath Characteristics
Repeatable – 10-14 metal turn-overs
Plating rate - .0006 to .0009 in./hr.
Closed loop system
Clean air environment
Chemically strippable without substrate
damage
Copyright UCT Defense LLC, 2003
Page 8
Environmentally-Friendly Process
Plating Characteristics
Operates in closed-loop water system
Operation temperature 194° to 200° F
Alkaline solution – Ph 12-14
Disposal/recovery system substantiated
No thallium, ammonium, arsenic, or cyanides
Copyright UCT Defense LLC, 2003
Page 9
NiB Plating Procedure
Operating Procedure
Receive directional and visual inspection
Develop operation sheets
Mask areas not to be coated
Chemically clean
Chemically activate
Plate to desired thickness
Air bake 425° to 700 ° F
Copyright UCT Defense LLC, 2003
Page 10
Superior Wear Resistance
Copyright UCT Defense LLC, 2003
Page 11
Low Coefficient of Friction
Copyright UCT Defense LLC, 2003
Page 12
UltraCem™ vs. Hard Chrome
Hardness: UltraCem: 1200-1400 HK, hard chrome: 950-1000 HK
Wear resistance: UltraCem provides significantly more abrasion and wear resistance
(3x) than hard chrome
Bond strength: UltraCem has a true metallurgical bond that exceeds all known pull tests:
>10,000 psi
Uniformity: coats uniformly 99.8%, including blind holes and recessed areas, large
internal diameters
Post treatment: requires no post-grinding and can be polished to low surface finish < 1
RMS
Lower energy costs: UltraCem has lower setup and operating costs, lower energy
consumption, no expense related to rectifiers and anodes, 3-4 times greater throughput
with same tank capacity
Ductility: UltraCem exceeds 180 degree bend test due to bond and unique columnar
structure
Coefficient of Friction: UltraCem .08, Hard Chrome: 1.3 - 1.35
Operating Temperature Tolerance: UltraCem can withstand operating temperatures to
+1,500o F, hard chrome starts to deteriorate at 800o.
Copyright UCT Defense LLC, 2003
Page 13
Pratt & Whitney Proposed NiB
for Chromium Replacement
PEWG – CIP – November 2003
Bath Analysis
Bath Chemistry, Including Heavy Metals
Deposit Chemistry
Basic Properties of Deposit
Bond Strength
Hardness Testing
Wear Resistance
Hydrogen Content
Comprehensive Laboratory Validation
Pratt & Whitney
General Electric
Rolls Royce
Estimated Cost $235K
Copyright UCT Defense LLC, 2003
Page 14
Current DoD Activities
Air Force Propulsion Lab (PEWG)/Pratt & Whitney
Air Force Research Lab – Preliminary Evaluation
Air Force Special Operations Command (AFSOC)
Greaseless GunTM
US Army Picatinny
US Army Industrial/Ecology Center
NAVAIR Naval – Aviation – Pax River
Naval Surface Warfare Center - Crane
Copyright UCT Defense LLC, 2003
Page 15