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17th Symposium of AER on VVER Reactor Physics and Reactor Safety Reduced leakage September 24-29, 2007, Yalta, Crimea, Ukraine ADVANCED FUEL CYCLES FOR VVER-1000 REACTORS Semchenkov Y.M., Pavlovichev A.M., Pavlov V.I., Spirkin E.I., Styrin Y.A. and Kosourov E.K. RRC “Kurchatov Institute” Moscow, Russia RRC KI 1 Introduction In the present report following themes are discussed: Reduced Stages of development of the Russian uranium fuel from the leakage point of view of increase of safety and profitability of fuel loadings operation Neutron-physical and economic characteristics of present-day and perspective uranium fuel cycles Potential of uranium-plutonium regenerate use in VVER-1000 reactors Potential of weapon-grade plutonium disposition in VVER1000 reactors RRC KI 2 3 Evolution of VVER-1000 fuel cycles Factor FA structural material Burnable absorber Factor score Yesterday Today Future steel zirconium Hf Boric rods U-Gd fuel Results Deleterious neutron absorption Radio-active waste Max Kr, Ql Stability of FA geometry Low High FA burnup limit Max Kr, Ql Fuel enrichment, % no more than 4.4 Pellet outside diameter, mm 7.57 Central hole diameter, mm 1.5/1.4 Fuel height, mm 3530 FA burnup limit, MWd/kgU Number of fresh FA on core periphery , % 49 100 55 ~ 60 4.95 7.6 7.8 1.2 0.0 3530 (3680) FA energy potential 60-68 0 - 30 Neutron leakage Neutron flux on reactor vessel RRC KI Average burnup versus number of loaded FAs, FA enrichment and cycle length Reduced leakage RRC KI 4 Natural uranium consumption versus number of loaded FAs, FA enrichment and cycle length 270 1 Natural uranium consumption, g/MWd Reduced 260 leakage 250 1 – 81 FA, steel 2 – 54 FA, steel 3 – 48 FA – 42 FA 240 2 5.0% 4.4% 4.6% 4.8% 4.2% 4.0% 78 3.6% 3.8% 230 72 66 220 60 54 210 48 3 200 42 36 190 200 250 300 350 400 450 500 550 Cycle length, EFPD RRC KI 5 Cost of electricity generation versus number of loaded FAs, FA enrichment and cycle length (cost of fuel-20%, reloading – 65 days) Reduced leakage RRC KI 6 Cost of electricity generation versus number of loaded FAs, FA enrichment and cycle length (cost of fuel-30%, reloading – 65 days) Reduced leakage RRC KI 7 Cost of electricity generation versus number of loaded FAs, FA enrichment and cycle length (cost of fuel-20%, reloading – 40 days) Reduced leakage RRC KI 8 Average burnup versus number of loaded FAs, FA enrichment and cycle length 70 Average burnup, MW*d/kgHM B1 – Fuel rod characteristics -7.57/ 1.4/ 353 cm, reduced leakage B2 – Fuel rod characteristics - 7.57/ 1.4/ 353 cm, low leakage Reduced 65 B3 – Fuel rod characteristics -7.60/ 1.2/ 368 cm, low leakage leakageB4 – Fuel rod characteristics -7.8/ 0/ 368 cm, low leakage 60 36 42 55 54 50 66 36 42 5.0% 54 45 66 В2 78 В1 40 В3 В4 В3 78 В2 В4 4.4% 35 250 300 350 400 450 500 550 600 650 Cycle length, EFPD RRC KI 9 Loading patterns of advanced equilibrium cycles Height of core – 3680 mm, fuel pellet diameter -7,6 mm, central hole - 1,2 mm 12-month cycle (36 FAs) Average enrichment – 4,83% Reduced Cycle length – 324 EFPD leakage time – 4 or 5 cycles FA operational 18-month cycle (60 FAs) Average enrichment – 4,88% Cycle length – 478 EFPD FA operational time – 2 or 3 cycles RRC KI 10 11 Main neutronic characteristics of advanced equilibrium cycles Today's Advanced cycles 12-month 12-month 18-month Core height, cm 353 368 368 Amount of loaded uranium FAs, pcs 42 36 60 Amount of UGBA rods in loaded uranium FAs, pcs 252 216 900 Average enrichment, % 4,33 4,83 4,88 8,1 8,4 9,5 Reactivity compensated by liquid boron, % k/k (BOC) Cycle length, EFPD 297 324 478 Burnup of unloaded uranium Average 49,2 58,5 52,0 FAs, MWd/kg HM 53 62 61 Maximum over FAs Boric acid critical concentration at BOC, HFP, (g/kgH2O) 6,3 7,2 8,7 Maximal relative power of fuel rods in the core, Krmax 1,46 1,59 1,56 Maximal value of fuel rods linear heat rate, W/cm 285 323 318 -4,4 -0,6 Moderator temperature reactivity coefficient at BOC, HZP ( pcm/C) -4,7 Boric acid concentration at BOC, CZP, no Xe, =-2% (g/kg H2O) 10,7 12,4 13,8 o Repeated criticality temperature at EOC, Xe и Sm, no boron ( С) 182 195 182 Effective fraction of delayed neutrons, % BOC 0,63 0,63 0,66 EOC 0,56 0,56 0,55 Natural uranium consumption, g/MWd 200 188 214 RRC KI 11 Uranium-plutonium regenerate in VVER-1000 It was proposed to use uranium-plutonium regenerate in Reduced thermal reactors by using spent fuel of these reactors cleaned from leakage other actinides and fission products, and by following mixing of cleaned fuel with enriched uranium Weight fraction of uranium-plutonium regenerate and highly enriched uranium at their mixing is 0,8 and 0,2 correspondingly Enrichment of highly enriched uranium has been defined from a set of calculations under condition that the equilibrium cycle of VVER-1000 with feed by 42 fresh FAs has the same cycle length as the design uranium cycle. The enrichment of highly enriched uranium for uranium-plutonium fuel was 17,1% RRC KI 12 Isotopic content of regenerated fuel (kg/tHM) Nuclide Reduced leakage 234 U U 236 U 238 U U 238 Pu 239 Pu 240 Pu 241 Pu 242 Pu Pu 235 U+239Pu+241Pu 235 Uranium fuel, Regenerated uranium fuel, kg/tHM 0 43,3 0 956,7 1000 0 0 0 0 0 0 43,3 kg/tHM 1,5E-3 44,98 4,77 950,25 1000 0 0 0 0 0 0 44,98 Regenerated uraniumplutonium fuel, kg/tHM 1,5E-3 41,40 4,71 943,90 990 0,25 5,37 2,55 1,14 0,69 10 47,91 RRC KI 13 Main neutronic characteristics of equilibrium cycles with regenerated uranium-plutonium fuel Reduced leakage Amount of loaded FAs, pcs Content of 235U, % Content of 235U+239Pu +241Pu, % Cycle length, EFPD Reactivity compensated by liquid boron, BOC, % k/k Boric acid critical concentration at BOC, HFP, g/kg H2O Maximal relative power of fuel rods in the core (Krmax) Maximal value of fuel rods linear heat rate, W/cm Moderator temperature reactivity coefficient at BOC, HZP, pcm/C Boric acid concentration at BOC, CZP,=-2%, g/kg H2O Repeated criticality temperature at EOC, Xe и Sm, no boron, oС Effective fraction of delayed neutrons, % BOC EOC -5 Effective lifetime of fission prompt neutrons, 10 s BOC EOC Natural uranium consumption, g/MWd Uranium Regenerated Regenerated fuel uranium uraniumfuel plutonium fuel 42 4,33 4,48 4,14 4,33 4,48 4,79 297 8,1 8,0 6,4 6,3 1,46 285 -4,7 10,7 182 0,63 0,56 2,0 2,3 200 6,3 1,47 293 -6,0 11,2 183 0,63 0,56 1,9 2,2 185 RRC KI 6,0 1,46 288 -11,6 12,3 185 0,58 0,55 1,6 1,9 168 14 Weapon Plutonium MOX FA in VVER-1000 core Preliminary researches with participation of US, French and German experts have shown possibility of use of W-МОХ fuel in existing VVER-1000. Reduced leakage Fuel rod with high plutonium content Fuel rod with medium plutonium content Fuel rod with low plutonium content Low leakage UGBA rod Guide tube Instrumental tube The pattern of the typical MOX FA RRC KI 15 Loading patterns of equilibrium cycles with MOX FAs Reduced leakage MOX FAs- 30, UOX FAs-24 307 EFPD 684 UGBA MOX FAs- 36, UOX FAs- 36 465 EFPD 1188 UGBA RRC KI 16 Main characteristics of equilibrium cycles with MOX fuel Amount of loaded uranium FAs, pcs Reduced Amount of loaded MOX FAs, pcs leakage MOX fuel rods part in core, % Cycle length, EFPD Annual plutonium consumption, kg Average burnup of unloaded uranium FAs, MWd/kg HM Average burnup of unloaded MOX FAs, MWd/kg HM Maximal relative power of fuel rods in the core (Krmax) Maximal value of fuel rods linear heat rate, W/cm Boric acid critical concentration at BOC, HFP, (g/kg H2O) Moderator temperature coefficient ( pcm/C) 1218month month 24 36 30 36 38.2 40.3 307 465 445 450 50.4 46.3 31.1 43.5 1.41 1.47 278 306 7.7 10.7 -6 -1 Boric acid concentration at BOC,CZP,=-2%,(g/kg H2O) 13.2 180* Repeated criticality temperature, oС Natural uranium consumption, g/MWd 200 16.2 177* 185 * CR CPS boron is enriched by the isotope boron-10 up to 80% RRC KI 17 Conclusion Advanced uranium fuel cycles for VVER-1000 ensure under meeting safety requirements: Reduced effective use of natural uranium; leakage possibility of cycle length variation in a wide interval and consequently possibility of NPP power production adaptation to demands of power net and to eventual changes in relations between components of electricity generation cost; reducing of neutron fluence on reactor vessel in view of its service life prolongation. Expanding of fuel raw material nomenclature is possible for VVER1000 by using regenerated uranium and uranium-plutonium fuel. VVER-1000 reactors could ensure a high rate of weapon-grade plutonium disposition at effective using of plutonium power potential. RRC KI 18