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Modelling Fiber Suspensions Flows Using Rheological Data M. Graça Rasteiro COSt Action FP1005 meeting Nancy, 13-14 October 2011 Portugal Overview UNIVERSITY of COIMBRA Objectives Overview of work being developed Rheological characterization Pilot rig CFD model Results Future work Objectives UNIVERSITY of COIMBRA Flow properties of pulp suspensions are important for the optimization of most unit operations in pulp and paper making. Therefore, it is necessary to understand the specific hydrodynamic features of fibre suspensions. Objectives UNIVERSITY of COIMBRA Pulp suspensions flowing in pipes exhibit three basic types of shear flow mechanisms: Plug Flow water P L Plug flow Mixed Flow Transition Turbulent flow flow Turbulent Flow Vmax VWT VW Vred Objectives UNIVERSITY of COIMBRA Construction of a flow model able to predict the flow behaviour of pulp fibre suspensions represents an important step in this area. Strategy: Pseudo-Homogeneous Model Knowledge of the rheological behaviour is essential for the construction of a realistic model. The k Turbulence Model is one of the simplest and most used turbulence models for industrial applications. Modifications to the k- ε model can lead to an efficient description of the flow of concentrated fiber suspensions. Overview of the research developed UNIVERSITY of COIMBRA Rheological characterization suspensions (different fiber consistencies). -new rotational developed at UCM rheometer of fiber types and (Searl effect) Development of models for the rheology of fiber suspensions. (Carla A.F. Ventura, A. Blanco, C. Negro, F.A.P. Garcia, P. Ferreira, M.G. Rasteiro, "Modelling Pulp Fibre Suspension Rheology", Tappi J, 6, 7, 17-23 (2007).) Identification of the main parameters with a stronger impact on the rheology of fiber suspensions. (Carla A.F. Ventura, A. Blanco, C. Negro, F.A.P. Garcia, P. Ferreira, M.G. Rasteiro, "Modelling Pulp Fibre Suspension Rheology", Tappi J, 6, 7, 17-23 (2007).) Overview of the research developed UNIVERSITY of COIMBRA Pilot rig for the study suspensions in pipes. of the flow of fiber -Flow tests varying fiber type, suspension consistency, temperature, pipe diameter and material. Identification of the main parameters stronger impact on the flow regimen. with a (Carla Ventura, Fernando Garcia, Paulo Ferreira, Maria Rasteiro; "Flow Dynamics of Pulp Fibre Suspensions", Tappi J, 7, 8, 20-26 (2008).) New set of design correlations for friction factor vs Reynolds number based on a statistical design, showing the dependence on consistency and pipe diameter for two flow regimes. (Carla A.F. Ventura, Fernando Garcia, Paulo Ferreira, Maria Rasteiro, "Modelling Pipe Friction Loss of Pulp Fibre Suspensions", CHERD (2011) – in revision.) Modelling of the pipesturbulent approach. flow of regime fiber suspensions in – pseudo-homegeneous (Carla A.F. Ventura, Fernando Garcia, Paulo Ferreira, Maria Rasteiro, "Modelling the Turbulent Flow of Pulp Suspensions”, I&ECR, 50,16, 9735–9742 (2011).) Rheological characterization UNIVERSITY of COIMBRA New plate rotational Rheometer – Searl effect 5 3 4 2 5 1-Analytical scales; 2-Arms to measure torque; 3-Rotor; 4-Vessel; 5-Computer connected to the scales; 6-device to control velocity. 6 1 6 Induces uniform fibre distribution 1 5 Measures shear in the rotor (mobile plate) and in the vessel (fixed plate) Calculates the difference between torque applied by the rotor and torque transmitted by the fluid to the vessel Rheological characterization UNIVERSITY of COIMBRA Suspensions tested: Fibre length (mm) Consistencies % Recycled pulp 1.14±0.04 1.4 – 4.23 Eucalypt bleached kraft pulp 0.71±0.03 1.45 – 3.5 Eucalypt (90%) + pine (10%) bleached pulp 0.61±0.06 0.9 – 3.2 Pine unbleached kraft pulp 2.56 ±0.14 0.8 – 3.6 Pulp Type (w/w) Rheological characterization UNIVERSITY of COIMBRA Typical Rheograms ap (Pa.s) (Nm-2) C=3.2% C=2.5 % C=2.2 % C=1.9 % C=1.6% C=1.2 % C=0.9 % pine + eucalyptus suspension Rheological characterization UNIVERSITY of COIMBRA Herschel-Bulkley model y - yield stress k – consistency coefficient n – flow index -Using an experimental design the influence of fibre characteristics (length), consistency and temperature on y were evaluated. - n an k are mainly influenced by consistency - Yield stress increases with consistency and fibre length - Temperature has got a negative effect on yield stress See: Ventura C, Blanco A, Negro C, Ferreira P, Garcia F, Rasteiro M, Tappi J, 6 (7) 17 (2007) Flow model UNIVERSITY of COIMBRA Pseudo-Homogeneous Model Objective: To model the turbulent flow of suspensions in pipes using CFD(FEM). pulp fibre Modified k-ε model. COMSOL Multiphysics Software, version 3.5 Pilot rig UNIVERSITY of COIMBRA Pilot Rig Pilot rig UNIVERSITY of COIMBRA Pilot Rig Experimental Results- pressure drop UNIVERSITY of COIMBRA Pipe -3”SS Pulp type effect 400 ∆P(mm H2O/m pipe) 350 300 250 200 150 100 50 0 0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 Velocity(m/s) recycled pulp suspension C=4.2% pulp suspension C=3.4% pine Pulp eucalypt pulp suspension C=3.5 % Details of Governing Equations UNIVERSITY of COIMBRA Equation for k k IT 2 Equation for ε 3 k 2 LT Equations for the turbulence intensity and length scales I T I Re 1 8 Dh LT l Dh I – turbulence intensity scaling parameter l - turbulence length scaling parameter Turbulence damping assumed – I and l were adjusted depending on fiber type and consistency. Viscosity was supplied as a function of local shear rate in the pipe cross-section (data extracted from the rheograms). Results - Modelling UNIVERSITY of COIMBRA Experimental data Consistencies % Pulp Type SS Pipes and PE Pipes 3” and 4” Recycled pulp Eucalypt bleached kraft pulp 1.4 – 4.23 1.45 – 3.5 Eucalypt (90%) + pine (10%) bleached pulp 0.9 – 3.2 Pine unbleached kraft pulp 0.8 – 3.6 Results - Modelling UNIVERSITY of COIMBRA Turbulence parameters values Pulp type Recycled Eucalypt Eucalypt + pine Pine Turbulence Parameters very low consistencies low consistencies Consistency (%) 0.72 0.60 0.61 1.40 1.80 2.30 2.70 I 0.01 0.01 0.01 0.009 0.008 0.007 0.005 l 0.005 0.005 0.005 0.005 0.005 0.005 0.005 Consistency (%) 0.77 0.91 1.4 1.5 I 0.09 0.09 0.007 0.003 l 0.005 0.005 0.005 0.005 Consistency (%) 0.71 0.77 0.9 1.2 1.3 I 0.07 0.05 0.01 0.005 0.003 l 0.005 0.005 0.005 0.005 0.005 Consistency (%) 0.66 0.76 0.8 1 I 0.01 0.01 0.0005 0.0003 l 0.005 0.005 0.005 0.005 UNIVERSITY of COIMBRA Results - Modelling Comparison between predicted and experimental pressure drop (Pa/m) for the turbulent regime 1800 2000 1500 1600 Recycled 0.61% Recycled 0.76% 600 Recycled 1.4% Recycled 1.8% 300 Recycled 2.3% Recycled 2.7% Predicted 900 1200 Eucalypt 0.77% 800 Eucalypt 0.91% Eucalypt 1.4% 400 Eucalypt 1.5% 0 0 0 300 600 900 1200 Experimental 1500 1800 0 400 a) recycled 1800 1800 1500 1500 1200 1200 900 eucalypt+pine 0.71% eucalypt+pine 0.90% 600 1200 eucalypt+pine 1.20% 1600 2000 Experimental 900 pine 0.66% 600 eucalypt+pine 0.77% 300 800 b) eucalypt Predicted Predicted Predicted 1200 pine o.76% pine 0.8% 300 pine 1% eucalypt+pine 1.30% 0 0 0 300 600 900 1200 1500 1800 0 300 Experimental c) eucalypt+pine d) pine 600 900 Experimental 1200 1500 1800 UNIVERSITY of COIMBRA Results - Modelling Turbulence intensity scaling parameter versus suspension consistency 1 Recycled Pulp Low Consistencies Eucalypt Pulp 0.1 Eucalypt/Pine Pulp I Pine Pulp 0.01 0.001 High Consistencies 0.0001 0.00 0.50 1.00 1.50 Consistency (%) 2.00 2.50 3.00 UNIVERSITY of COIMBRA Future work ▪ Introduce in the model experimental information on the turbulence damping. ▪ Modify the transport equations include mechanistic damping terms. for k and ε to Establish quantitative correlations for the turbulence intensity and length scales, as a function of fiber characteristics and consistency. ▪ Model the intermediate regime (plug of fibers + water annulus). Acquire experimental information on the fiber plug evolution with Reynolds number (different fiber types and consistencies), using tomographic techniques. UNIVERSITY of COIMBRA Acknowledgments: European Project NODESZELOSS; FCT Project FIBERFLOW; UCM; RAIZ – Instituto Investigação da Floresta e Papel; Gopaca, S.A.; Prado Karton, S.A.; Soporcel - Grupo Portucel Soporcel; CELTEJO - Empresa de Celulose do Tejo, S.A.; Carla Ventura Carla Cotas Joy Iglesias F. Garcia Paulo Ferreira UNIVERSITY of COIMBRA Thank you for your attention UNIVERSITY of COIMBRA Conclusions ▪ The pressure drop profiles obtained using COMSOL Multiphysics Software agree very well with the experimental results obtained. ▪ The use of the k-ε Turbulence Model, associated with the rheological data acquired in a specially built viscometer, revealed to be a good strategy for the prediction of pressure drop values for fibre suspension flow. ▪ For very low consistencies the I value influenced by the consistency increase. is minimally ▪ For relatively high values of consistency, as consistency increases, the I values decrease for all the pulps tested. This boundary is dependent on the fibre type. The turbulence damping is higher in the case of the pine suspensions (longer and stiffer fibres), being lower for the recycled fibres suspension. Results - Modelling UNIVERSITY of COIMBRA Comparison with experimental data Pressure Drop (Pa/m) 2000 1800 Pine 0.76% - experimental 1600 Pine 0.76% - predicted 1400 Pine 1.0% - experimental 1200 C 0.76% Pine 1.0% - predicted 1000 800 600 C 1% 400 200 0 0 1 2 3 4 Velocity (m/s) 5 6 7 I 0.01 l 0.005 I 0.0003 l 0.005 Numerical Implementation UNIVERSITY of COIMBRA Results and Discussion First, the numerical implementation was validated with water. Then, the pulp’s physical characteristics were introduced in the model. Simulated pressure drop for the flow of the recycled pulp suspension with 2.7% (w/w) consistency, at a velocity of 4.8 m/s. Numerical Implementation UNIVERSITY of COIMBRA Results and Discussion Kinetic energy profile for the recycled fibre suspension 0.72% consistency Numerical Implementation UNIVERSITY of COIMBRA Results and Discussion Kinetic energy profile for the recycled fibre suspension 2.7% consistency Governing Equations UNIVERSITY of COIMBRA u 0 Continuity equation Conservation of momentum u T u u p u u F t Standard k-ε model T C k2 Transport Equation for k k T t k 1 k U k T U U T 2 2 Transport Equation for ε T t model constants: 1 U C 1 T U U T 2 k Constant Value C 0.09 C 1 1.44 2 C 2 1.92 C 2 2 k k 1.0 1.3 Numerical Implementation UNIVERSITY of COIMBRA For the CFD modelling the Chemical Engineering module of COMSOL Multiphysics Software version 3.5 was used. Geometry 4m The system to be modelled is basically a linear pipe (3 in diameter and 1 m long) where a pulp fibre suspension is flowing. 2D axial symmetry. Numerical Implementation UNIVERSITY of COIMBRA 2D axial symmetry: mesh mode In order to reach accurate results for the pressure drop, the mesh selected was a mapped mesh consisting of quadrilateral elements. The mesh is more refined near the wall to resolve the viscous sublayer. Numerical Implementation UNIVERSITY of COIMBRA Physics and Boundaries Inlet Boundary Outlet Boundary Wall Symmetry Boundary Plug type cross section velocity profile; The existence of particles, such as fibres, in a fluid flow induces a turbulence damping, thus the L and I values should be smaller then usually assumed for homogeneous fluids Since the turbulent length scale is mentioned to be mainly dependent on the system geometry, it’s value was assumed to be constant for all the fibre types and all the consistencies. The intensity scale parameter was adjusted according to the pulp fibre type and concentration. “Normal Stress, Normal Flow” function Logarithm wall function, Axial Symmetry Friction Factor H u2 2 Cf L D uD Re . C f vs Re Friction factor results Friction Factor: Eucalypt pulp 1.00000 3.50% 3.20% 2.90% 2.50% 0.10000 1.80% 1.50% Cf 0.77% 0.01000 0.00100 100.00 1000.00 10000.00 Re 100000.00 1000000.00 Friction factor results Friction Factor: distinct pulps 10.000 Cf 1.000 0.100 0.010 0.001 10 100 1000 Re recycled pulp suspension C=4.2% eucalypt/pine pulp suspension C=3.2% water line 10000 100000 eucalypt pulp suspension C=3.5% pine pulp suspension C=3.4% Friction Factor Correlations for C f not only as a function of Reynolds number, but also showing the dependence on consistency and pipe diameter for a range of pulp suspensions and for two different flow regimes were obtained; Rheological characterization UNIVERSITY of COIMBRA Shear stress, δ Typical rheogram for a pulp fibre suspension τY τD Newtonian fluid Rate of shear, γ Rheological characterization UNIVERSITY of COIMBRA Typical Rheograms 10 1 Ψ (Pa.s) (Nm-2) ap (Pa.s) 0.1 0.01 0 2000 4000 6000 dV/dx (1/s) C=3.6% C=3.3 % C=2.9 % C=2.3 % C=1.9% C=1.5 % C=1.0 % Pine suspension 8000 10000 1200