Transcript FOOD COLOURS

FOOD COLOURS
CLASSIFICATION
BY ORIGIN
NATURAL
vegetal
E-100, E-101, E-120
E-140, E-141, E-150,
E-160, E-161, E-162,
E-163
animal
E-120
SYNTHETIC
mineral
No special
labeling
E-171, E-172
E-131, E-132,
E-133, E-151
E-155
Special
labeling
E-102, E-104, E-110,
E-122, E-124, E-129
DOUE Reg 1333/2008/UE
Highly
restricted
E-127, E-123
Classification by
application form
Watersoluble
Oleosoluble
Pigments
Synthetic colours,
Curcuma OR, Carmine WS,
Chlorophyllins, Caramel,
Carotenes WD,
Annatto, Paprika WD, Lutein WD,
Beetroot Red, Anthocyanins
Chlorophylls, Betacarotene,
Annatto, Paprika OR.,Lutein,
Lycopene
Lakes of synthetic colours
Curcumin, Riboflavin, Carmine lake
Vegetable carbon, Titanium Dioxide,
Iron oxides
Natural colours
PRODUCT
MAIN DYE
RIBOFLAVINE
E-101
RIBOFLAVINE
PHOSPHATE
TURMERIC
CURCUMINE
ANNATTO
NORBIXIN
BIXIN
ß-CAROTENE
PAPRIKA
XANTHOPHYLLS
P
PG
P
WS
P/L
WS/OS/PG
L
WS
L
OS
P/L
WS/OS
E-160c
L
WS/OS
LUTEIN
E-161
P/L
WS/OS
E-150
P/L
WS
CHLOROPHYLL
75810
E.140
75815
E-140
L
OS
Mg
CHLOROPHYLLIN
Mg
P
WS
75815
E-141
L
OS
Cu
75815
E-141
P
WS
RED BEET
BETANIN
E-162
P/L
WS
COCHINEAL
CARMINE
75470
E-120
P/L
WS/PG
CARMINIC ACID
75470
E-120
P
WS
ENOCYANIN
E-163
P
WS
CARROT
ANTHOCYANIN
E-163
P
WS
E-153
P
PG
CHLOROPHYLL
CHLOROPHYLLS - Cu
Cu
CHLOROPHYLLIN
ANTHOCYANINS
VEGETABLE CARBON
PRODUCT
TITANIUM WHITE
P: Powder
E-101
75300
E-100
75120
E-160b
75120
E-160b
40800
E-160a
ASPECT AND
SOLUBILITY
CAPSANTHIN
CARAMEL
CHLOROPHYLLS - Mg
CI
Nº EEC
MAIN DYE
TITANIUM
DIOXIDE
YELLOW CONINOR E-172
IRON OXIDE
RED CONINOR E-172
IRON OXIDE
RED CONINOR R/E-172
IRON OXIDE
BLACK CONINOR E-172
IRON OXIDE
L: Liquid
WS: Watersoluble
OS: Oilsoluble
CI
Nº EC
77891
E-171
77492
E-172
77491
E-172
77491
E-172
77499
E-172
ASPECT AND
SOLUBILITY
P
PG
P
PG
P
PG
P
PG
P
PG
PG: Pigment
CONACERT : Synthetic dyes for food, cosmetic and
pharmaceutical products
CI /NºEEC
DYE RANGE
QUINOLINE YELLOW
47005
E-104
70%
TARTRAZINE
TARTRAZINE 233A
19140
E-102
85%
30%
SUNSET YELLOW
SUNSET YELLOW 41
15985
E-110
85%
41%
BROWN HT
20285
E-155
70%
PONCEAU 4R
PONCEAU 4R 33
16255
E-124
80%
33%
ALLURA RED (RED 40)
16035
E-129
85%
ERYTHROSINE
45430
E-127
87%
CARMOISINE
14720
E-122
85%
AMARANTH
16185
E-123
85%
INDIGO CARMINE
73015
E-132
85%
PATENT BLUE V
42051
E-131
85%
BRILLIANT BLUE FCF
42090
E-133
85%
GREEN S
44090
E-142
80%
BLACK PN
28440
E-151
80%
TYPE
COLOUR INDEX
a multi-volume reference work about colorants issued by the British Society of Dyers and
Colourists and the American Association of Textile Chemists and Colorists; continually
updated
TARTRAZINE
Trisodium 1-(4-sulfonatophenyl)-4-(4-sulfonatophenylazo)-5-pyrazolone-3carboxylate
COLOUR INDEX: CI 19140, FOOD YELLOW 4, ACID YELLOW 23
E NUMBER: E-102
CAS: 1934-21-0; EINECS 217-699-5
SO3Na
NaO3S
HO
N
N
NaO
N
N
O
SYNTHETIC FOOD COLOURS
CI
FOOD DYE
STABILITY
FDC
EEC
S(H20)
g/l
FDC Y5
102
140
6
4
5
5
5
5
5
104
150
5
2
4
3
5
2
5
110
120
4
4
5
5
5
4
3
Light
Alkali
100º
200º
Fruit
Acids
Benzoic
Acid
SO2
TARTRAZINE
19140
FY4
QUINOLINE YELLOW
47005
FY13
SUNSET YELLOW
15985
FY3
PONCEAU 4R
16255
FR7
124
140
4
3
5
5
5
5
3
CARMOISINE
14720
FR3
122
75
5
4
4
3
5
4
4
AMARANTH
16185
FR9
123
100
5
3
5
3
4
4
4
ERYTHROSINE
45430
FR14
FDC R3
127
75
3
3
4
3
1
1
5
ALLURA RED
16035
FR17
FDC R40
129
250
5
4
5
5
5
4
4
INDIGO CARMINE
73015
FB1
FDC B2
132
10
3
1
1
1
1
1
1
PATENT BLUE V
42051
FB5
131
50
4
4
5
4
1
2
1
BRILLIANT BLUE FCF
42090
FB2
133
160
5
5
5
5
5
5
5
GREEN S
44090
FG4
142
80
3
3
5
5
4
4
4
BLACK PN
28440
FBLACK1
151
130
4
4
4
4
4
4
3
BROWN HT
20285
FBrown 3
155
150
5
4
5
5
4
5
4
FDC Y6
FDC B1
FOOD SYNTHETIC DYES
PERMITTED IN EUROPEAN UNION AND IN U.S.A.
DYE
FDA (*)
E-102
Tartrazine
FD&C YELLOW 5
E-104
Quinoline Yellow
E-110
Sunset Yellow
E-122
Carmoisine
E-123
Amaranth
E-124
Ponceau 4R
E-127
E-131
Erythrosine
Allura red (Red
40)
Patent Blue V
E-132
Indigo Carmine
FD&C BLUE 2
E-133
Brilliant Blue FCF
FD&C BLUE 1
E-142
Green S
E-151
Black PN
E-155
Brown HT
Nº EEC
E-129
FDA: FOOD DRUG ADMINISTRATION
FD&C YELLOW 6
PONCEAU SX
FD&C RED 4
FD&C RED 3
FD&C RED 40
CONACERT : Blends of synthetic dyes for food, cosmetic
and pharmaceutical products
DYES
DYE RANGE
LEMON YELLOW
E-102+E-132
24%
EGG YELLOW
E-102+E-110
16% y 25%
MIMOSA YELLOW
E-102+E-110
25%
ORANGE 1787
E-110+E-124
40%
ORANGE 2000
E-110+E-124
85%
SHELLFISH COLOUR
E-110+E-122
85%
E-102+E-124+E-132
28%
BROWN 4004
E-110+E-151
40%
GREEN 519
E-102+E-133
71%
MINT GREEN 1869
E-102+E-131
81%
GREEN BB2228
E-102+E-133
60%
MINT GREEN 20
E-102+E-132
19.5%
MINT GREEN 23
E-102+E-131
20%
MINT GREEN TV66
E-102+E-131
66%
MINT GREEN 839
E-102+E-131
19%
VIOLET 952
E-122+E-151
16%
VIOLET 1027/1
E-124+E-131+E-151
74%
BLACK 952
E-102+E-110+E-124+
E-131+E-151
25%
TYPE
E-104
E-102
E-110
E-155
CHOCOLATE BROWN 648
E-142
E-151
SYNTHETIC COLOURS VS
LAKES
CH3
H3C
CH2CH3
N
CH3CH2
N
N
CH3
N
CH3
CH2CH3
CH3CH2
SO3
.x (Al2O3)
SO3
HO
SO3Na
HO
SO3 Al1/3
PATENT BLUE V
water soluble dye
PATENT BLUE V LAKE
pigment
CONALAKE : Aluminium lakes for food, cosmetic and
pharmaceutical products
C.I./nºEEC
DYE RANGE
CONALAKE QUINOLINE
YELLOW
47005
E-104
12-14%
18-22%
CONALAKE TARTRAZINE
19140
E-102
CONALAKE SUNSET
YELLOW
15985
E-110
CONALAKE PONCEAU 4R
16255
E-124
20-26%
CONALAKE ALLURA RED
(RED 40)
16035
E-129
22-26%
CONALAKE
ERYTHROSINE
45430
E-127
17-20%
35-40%
CONALAKE CARMOISINE
14720
E-122
19-23%
CONALAKE AMARANTH
16185
E-123
18-21%
CONALAKE INDIGO
CARMINE
73015
E-132
9-11%
13-16%
CONALAKE PATENT
BLUE V
42051
E-131
21-25%
CONALAKE BRILLIANT
BLUE FCF
42090
E-133
12.5-14.5%
CONALAKE BLACK PN
28440
E-151
32-37%
CONALAKE GREEN 778
19140+44090
E-102+E-142
9-11%
CONALAKE GREEN 3076
19140+42090
E-102+E-133
12-16%
CONALAKE GREEN K
47005+73015
E-104+E-132
TIPO
CONALAKE BROWN 2002
15985+16255+73015
E-110+E-124+E-132
CONALAKE MARRON 2424
15985+14720+28440
E-110+E-122+E-151
15-18%
23-27%
35-40%
10,5-12,5%
21-25%
35-40%
6-10%
20-24%
35-40%
MAIN APPLICATIONS
• Food:
beverage,sugar confectionery, ice
cream, dairy products, baked goods,
preserves, candied fruits, decorations
and coatings, sauces,
cheese, meat preparations, fish pastes
and crustaceans, snacks, dietary food
supplements, edible inks.
• Pharmaceuticals
Compressed pills, granulates,
solutions, coated tablets
• Pet food
Cats and dogs, ornamental fish,
ornamental birds, small rodents
• Cosmetics
Lotions, creams, soaps , lipsticks,
make ups, powders,
Food colours legislation
In force:
•
•
•
Labelling: REGULATION (EC) No 1333/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on food additives. (Annex V list of colours with special
labeling: name or E number of the colour(s)’: may have an adverse effect on activity and attention in children.)
Application: Directive 94/36/EC of 30 June 1994 on colours for use in foodstuffs.
Purity :COMMISSION DIRECTIVE 2008/128/EC of 22 December 2008 laying down specific
purity criteria concerning colours for use in foodstuffs.
Applying 1 june 2013
•
Application: COMMISSION REGULATION (EU) No 1129/2011 of 11 November 2011
amending Annex II to Regulation (EC) No 1333/2008 of the European Parliament and of the
Council by establishing a Union list of food additives.
General labelling legislation
•
•
•
GMO: REG 1829/2003 and REG 1830/2003
Allergens: Directive 2006/142
Food information-labelling: Regulation 1169/2011 (food additives exempt of nutritional
information) Applying December 2014
Feed legislation
•
•
2004 Commission List of the authorised additives in feedingstuffs (1) published in application of
Article 9t (b) of Council Directive 70/524/EEC concerning additives in feedingstuffs (2004/C
50/01). (poultry, salmon, trout, cats, dogs, ornamental fish).
2005 COMMISSION REGULATION (EC) No 358/2005 of 2 March 2005 concerning the
authorisations without a time limit of certain additives and the authorisation of new uses of
additives already authorised in feedingstuffs (grain eating birds and small rodents).
Pharmaceutical products
•
DIRECTIVE 2009/35/EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 23 April
2009 on the colouring matters which may be added to medicinal products
HOW TO USE APPLICATION DIRECTIVE 94/36/EC
• Annex I: List of permitted food colours
• Annex II: Foods which may not content added colours except where
specifically provided for in Annex III, IV or V
• Annex III: Food to which only certain permitted colours may be
added
• Annex IV : colours permitted for certain uses only
• Annex V. Colours permitted in foodstuffs other than those mentioned
in annexes II and III.
– Part I: Colours that can be added “quantum satis “ to the foods in
the table
– Part II: Colours with combined maximum level specified in the
table
Directiva 94/36 Annex V
HOW TO USE APPLICATION REGULATION 1129/2011
•
•
•
Annex II
Part A Table 2: Foods which may not content added colours
Part B: List of all additives.
1.
2.
3.
•
Part C: Definitions of groups of additives


•
•
colours
Sweteners
Additives other than colours and sweeteners
Group II: Food colours authorised at quantum satis
Group III: Food colours with combined maximum limit
Part D: Food categories
Part E: Authorised food additives and conditions of use in food
categories