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Mechanical Stress Effect on Gate Tunneling Leakage of Ge MOS Capacitor Younsung Choi Electrical Engineering University of Florida 1 Outline 1. 2. 3. 4. Background Ge MOS Device Gate Tunneling Current Summary 2 Background What is strain? Strain is differential deformation in response to an applied stress. – – – – Uniaxial: one directional (1D) deformation Biaxial: two directional (2D) deformation Hydrostatic: volume deformation of a solid (average energy level shift in the conduction and valence bands) Shear: twisted deformation of a solid (subband splitting in the conduction and valence bands without changing the average energy level) Hydrostatic strain Shear strain 3 Background Why is strain important? - Strain increases carrier mobility in MOSFETs, resulting in faster speed of a MOSFET operation. Thompson et al., Uniaxial-Process-Induced Strained-Si: Extending the CMOS Roadmap, IEEE Trans. On Electron Devices, 53, 1010, 2006 - Strain affects a MOSFET operation characteristics such as its threshold voltage, gate tunneling current. Lim et al., Comparison of threshold voltage shifts for Uniaxial and Biaxial Tensile-stressed n-MOSFETs, IEEE Elec. Device Letters, 25, 731,2004 Lim et al., Measurement of conduction band deformation potential constants using gate direct tunneling current in n MOSFET under mechanical stress, APL, 89, 073509,2006 4 Background Why do we need Ge? - Promising as an alternative channel material due to its high carrier mobility - Why have we used Si for a long time? => based on the synergy between the silicon itself and its thermal oxide, SiO2. For decades, thermal SiO2 has provided the best possible surface passivation and it is a superb gate insulator. - Non-SiO2 Gate Insulator with Ge MOSFET =>direct electron tunneling through very thin SiO2 5 Ge MOS Device • L valley of Ge Conduction Band • How to calculate Ge MOS Electrostatics • Ge MOS Electrostatics with solving self-consistently the Schrodinger and Poisson equations • Stress Effect on Ge Quantization 6 L valley of Ge Conduction Band For electrons in Ge, the conduction band minima are located at L valley [001] s[110] Uniaxial Tension along <110> direction [111] [111],[11-1] ∆EHydro [111] [111] ∆EShear [010] [1-11],[-111] Unstrained [111] [100] s[110] Hydrostatic Strain Shear Strain Four-fold degenerate L-valleys in the Ge conduction band. 7 How to calculate? 1-D Effective Mass Hamiltonian 2 d2 * 2 H strain qV ( x) n ( x) En n ( x), 2mn dx mn* : the effective mass associated the electron motion perpendicular to the interface H strain : the strain Hamiltonian Electron Concentration along quantum box n( x) n md* kBT 2 ln[1 exp( EF En / kBT )] n ( x) , 2 Electro static potential with Poisson equation d2 2 V ( x) q / Si [ N ( x) n( x) N D ( x)], dz 8 Ge MOS Electrostatics Conduction Band Edge vs Distance 18 HfO2 Ge Sub. 10 Vg = 1V electron density (/cm3) ---> 1.5 Energy (eV) ---> 1 0.5 0 -0.5 -1 0 5 10 z (nm)---> 15 4 2 12 electron density (/cm3) ---> Energy (eV) ---> 6 Vg = 0.5V 0.5 0 5 10 z (nm)---> 5 13 1 -0.5 0 Vg = 1V 8 0 0 20 2 1.5 x 10 15 20 10 z (nm) ---> 15 20 x 10 Vg = 0.5V 10 8 6 4 2 0 0 5 10 z (nm) ---> 15 20 9 Stress Effect on Ge Quantization EChydro ( d Electron Repopulation Lowest Energy Level (eV) ---> 3 x 10 ECshear 1 S 44 us x 10 6 3.615 12 Electron Density (/cm2) ---> Band Splitting -3 [111],[11-1] 2 1 0 [-111],[1-11] -1 -2 0 5 Uniaxial Tension (Pa) ---> 7 x 10 [111],[11-1] 0.136 0.134 0.132 0.13 [-111],[1-11] 0 5 Uniaxial Tension (Pa) ---> 10 7 x 10 [-111],[1-11] 3.605 10 0.14 0.138 3.61 relative change of electron density (%) ---> Conduction Band Edge Splitting (eV) ---> 1. Energy Band Splitting 2. Electron Repopulation 1 u )( xx yy zz ) 3 [111],[11-1] 3.6 0 5 10 7 Uniaxial Tension (Pa) ---> x 10 0.2 [-111],[1-11] 0.1 0 -0.1 [111],[11-1] -0.2 -0.3 0 5 10 7 Uniaxial Tension (Pa) ---> x 10 10 Gate Tunneling Current • What is Gate Tunneling Current? • Tunneling Probability Calculation with a modified Wentzel-Kramers-Brillouin (WKB) approximation • Stress Effect on Gate Tunneling Current 11 What is Gate Tunneling Current? Gate tunneling is a phenomenon in which channel charge carriers tunnel into the oxide layer when the gate bias is applied. Z (001) EL(σ) Direct Tunneling Current EC EV J N n / n ( En ) n 1 n (E) T (E) tox 0 Metal Gate HfO2 Ge Substrate 2mn /[ En EC ( z )]dz Y.T. Hou et al., Direct tunneling hole currents through ulrtathin gate oxides in MOS devices, JAP, 91, 258 12 Tunneling Probability Calculation with a modified WKB approximation T TRTWKB TWKB : the usual WKB tunneling probability valid for smoothly varying potentials TR : the correction factor for reflections from boundaries of the oxide tox TWKB exp(2 k ( E, z )dz) 0 K(E) : the imaginary wave number within the oxide gap energy 4vGe ( E )vOX ( EOXi ) 4vGe ( E qVOX )vOX ( EOXo ) TR 2 2 2 2 vGe ( E ) vOX ( EOXi ) vGe ( E qVOX ) vOX ( EOXo ) vGe(E) & vGe(E+qVOX) : the group velocities of carrier incident and leaving the Oxide layers vOX(EOXi) & vOX(EOXo) : the magnitude of the imaginary group velocities of Carriers tunneling in and out of the oxide layer 13 3 0.7 0.6 Line Model Symbol Exp.Data 2 ∆n/n & ∆τ/τ (%) ∆ФB(σ)<0 E(σ)[111],[11-1] 0.5 E(σ)[1-11],[-111] 0.4 Vg=0.6V 0.3 0.2 Vg=0.8V Vg=1V 0.1 VG=0.6V ∆n[-111],[1-11] 4 6 Uniaxial Tension (Pa) 8 10 x 10 7 Relative Change of Tunneling Current with Uniaxial Tension along (110) direction Barrier Lowering of [111],[11-1] valleys => Tunneling Current Enhancement ~-3% ∆n[111],[11-1] -1 ∆τ[111],[11-1] -2 -3 1 2 ~+2% 0 -1% 2 1.5 0 0 ∆τ[-111],[1-11] 1 -4 0 ∆n/n & ∆τ/τ (%) Tunneling Current Enhancement (%) Stress Effect on Gate Tunneling Current VG=1V 4 6 Uniaxial Tension (Pa) 8 10 x 10 7 ∆τ[-111],[1-11] ∆n[-111],[1-11] 0.5 ~+1.3% 0 ∆n[111],[11-1] -0.5 -1 -1.5 ~-2% ∆τ[111],[11-1] -2 -2.5 0 -0.7% 2 4 6 Uniaxial Tension (Pa) 8 10 x 10 7 14 Summary • Ge Electrostatics with solving self-consistently the Schrodinger and Poisson equations • Tunneling Probability with the modifeied WKB approximation • Gate Tunneling Leakage Current Change with Uniaxial Stress was obsereved. => Barrier Height Lowering leads to Enhancement of Tunneling Current 15 Thank You !!! 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