PowerPoint 演示文稿

Download Report

Transcript PowerPoint 演示文稿

Professional Flame Retardants
HangZhou JLS Flame Retardants Chemical Co.,Ltd.
Introduction
HangZhou JLS Flame Retardants Chemical Co.,Ltd. is a special
corporation for exploring and manufacturing non-halogenated
flame retardants. We have explored a series of products to meet
halogen free requirement.
We are world leader in range of ammonium polyphosphate, nonhalogenated flame retardants in polyolefine and melamine
derivates.
Our tenet : QUALITY, INNOVATION, SERVICE
姓名
职称
姓名
职称
姓名
职称
姓名
职称
Advantages of JLS

Lower smoke,no halogen, environment friendly

Varied series of products,broad Application

Excellent water-proof,aging stability and low migration

Excellent process property

More attractive price/performance
JLS Products Catalogue
JLS-MC Series—Melamine Cyanurate Flame Retardant
JLS-PNA—Non-Halogen Flame Retardant for Polyamide
JLS-MC
JLS-MC series
Melamine Cyanurate
JLS-MC15
JLS-MC25
JLS-MC50
JLS-MC810
JLS-MC Character
JLS-MC :Melamine Cyanurate
CAS No:37640-57-6
EINECS:2535757
MCA
content
Excess
melamine
Excess
Cyanurate
D50
D98
Treating
method
JLS-MC15
≥99.5 %
≤0.3 %
≤0.2 %
≈3μm
15 μm
No
JLS-MC25
≥99.5 %
≤0.3 %
≤0.2 %
≈4μm
25 μm
No
JLS-MC50
≥99.5 %
≤0.3 %
≤0.2 %
≈5μm
50 μm
No
25 μm
surface
coating
JLS-MC810
≥98.5 %
≤0.3 %
≤0.2 %
≈4μm
JLS-MC series Advantages
◆Higher bulk density to reduce floating dust and increase mix uniformity.
◆Excellent particle distributing to ensure Nylon with JLS-MC better
mechanism and a smoother surface.
◆Well mixing with Nylon resin,so is easier to disperse during processing.
◆JLS-MC810 has even higher disperse property,which ensure Nylon a
better mechanical property .
◆JLS-MC15, MC25 and MC50 is different diameter, which can suitable for
different need.
◆The Nylon which contain JLS-MC is better than Br/Sb system in
electricity isolation capability,it can be used widely in low
piezoelectricity applications.
JLS-MC TGA
JLS-MC laser diameter distribution Contrast
Volume
%
JLS-MC
DSMMC
Ordinary
MCA
Particle Diameter,µm
D10
0.232
0.277
0.217
D25
0.790
1.131
0.614
D50
3.981
3.976
1.962
D75
9.866
10.70
3.308
D90
17.47
19.54
4.632
Average
diameter
2.771
3.083
1.368
JLS-MC series laser diameter Contrast
Volume
JLSMC15
JLSMC25
JLSMC50
D10
0.472
0.490
0.458
D25
0.962
1.246
1.477
D50
2.083
3.506
5.564
D75
4.412
8.424
13.090
D90
7.311
14.660
20.860
D98
11.231
20.010
32.870
Average
diameter
1.851
2.989
4.031
JLS-MC and Melapur MC laser diameter Contrast
JLS-MC15 and Melapur MC15 laser diameter Contrast
Volume
JLS-MC15
Melapur
MC15
D10
0.472
0.429
D25
0.962
0.961
D50
2.083
2.345
D75
4.412
5.106
D90
7.311
8.028
D98
11.231
11.813
Average
diameter
1.851
2.059
JLS-MC series Applications
• JLS-MC series consists of JLS-MC15, MC25, MC50 and JLSMC810 based on JLS-MC, which is mostly used in Nylon.
• The series can also be used in a range of polyesters.
• PC,thermoplastic polyurethane
• Thermosets including epoxy resins, unsaturated polyesters and
polyurethane foams.
JLS-MC FR Mechanisms contrast
Melaminederivatives
Halogen /
Sb2O3
ATH/Mg(OH)2
Inert Gases
√
√
√
Heat sink
√
√
√
Char formation
√
√
√
Intumescence
√
Heat Insulation
√
Heat transfer(dripping)
√
FR - mechanism
JLS-MC FR Mechanism in PA Advantages
Salt
Degradation: T > 300oC
Heat
Sink: Endothermic decomposition to M and CA
Inert
Gas Source: (M): Dilution of oxygen and fuel gases
Non-burning
dripping (CA): Decrease of exposure to flame
JLS-MC for Nylon
PA6,
66 un-reinforced: UL 94 V-0 at 6~12 wt%, PA6 need more
addition than PA66
PA6,
66 mineral filled: UL 94 V-0 at 13~15 wt.%
PA6,
66 glass fiber reinforced: 10~15% glass fiber, 15% MC
Properties: UL 94 V-2, Glow wire 960oC, CTI > 500 Volt
JLS-MC Properties in Nylon66
Item
Units
Tensile Strength
Elongation at break
Flexural Strength
Flexural Modulus
MPa
%
MPa
GPa
Charpy Impact-Notched
Flame test (0.8mm)
KJ/m2
UL94
firing
No-firing
V
Smoke Density
CTI
Bromine
Antimony
75
5.0
100
3
4
V0
790
390
350
JLS-MC
Ordinary
MCA
80
5.2
125
3.9
82
4.0
115
4.5
8-10
V0
190
80
>550
4
V2
190
80
>550
JLS-MC used in Nylon contain of Glass fiber
Contain: 10% glass fiber, 10%~15%JLS-MC
Flame resistance PA6
Item
Unit
Fire test
0.8mm UL 94 V-2
Izod impact strength J/m
10.28
Flexural Strength
Flexural Modulus
Tensile Strength
Elongation at break
Mpa
Mpa
Mpa
%
68.4
2100
58.46
33.8~51
PA6 basis
Standard
no
8-10
UL 94-1996
69
1800
56.38
34.5
ISO 179-1982
ASTM D790-00
ASTM D638-99
JLS-MC processing instructions in Nylon
Item
1
2
3
4
5
6
7
NOZZLE
Temp, PA66
℃
PA6
250
260
265
265
270
270
265
255
230
240
250
245
240
240
240
235
Vacuum
≥-0.08Mpa(recommend)
JLS-PNA
JLS-PNA is a non-halogenated and phosphorus/nitrogen flame retardant.
It may be used in Nylon modified glass fiber. It is melamine polyphosphate.
JLS-PNA SPECIFICATIONS
JLS-PNA: Melamine Polyphosphate
CAS No:218768-84-4
Phosphorus
%(m/m)
16-18
Thermal
decomposition
℃
≥350
Water content
%
≤0.5
Average particle
size
µm
≤25
JLS-PNA Advantages
◆ Non-halogenated, lower smoke density and toxic
◆ Good processing capability,no need especial screw combination and
especial specs glass fiber
◆ Excellent thermal stability , thermal decomposition≥350℃,very
suitable for modified glass fiber Nylon
◆ White color,easy to make all kinds of colors
◆ Excellent electricity capability,CTI>450V,very suitable for E&E
applications ,no recycle problem
JLS -PNA APPLICATIONS
• Mostly used in glass fiber modified PA66 and PA6, which is suitable for
processing of sorts ,for example extrusion and injection moulding.
• The compound consisted of JLS-PNA, glass fiber and Nylon provided
with excellent flame resistance and mechanical performance
JLS-PNA Laser Diameter
Volume,
%
Particle
Diameter,µm
D10
0.412
D25
3.134
D50
6.758
D75
11.25
D90
15.47
Average
diameter
4.470
JLS-PNA Application in PA66
Item
PA66(A3K)
Additive percent(%wt)
50-55
Glassing fiber
25
JLS-PNA
20-25
fire test(UL 94)
UL94:V-0
Mechanical
properties
Tensile strength,Mpa
95.7
Flexural Strength,Mpa
175.0
Flexural Modulus,Mpa
8400
Notched impact strength,J/m
45.0
Charpy impact Strength,no notched,KJ/m2
15.4
Heat transition,℃(0.45Mpa)
220
Hardness, Rockwell
120
PNA processing instructions in Nylon66 modified glass fiber
Item
1
2
3
4
5
6
7
Nozzle
Temp℃
250
260
270
265
265
255
245
270
Vacuum
Screw
speed
<-0.06Mpa(recommend)
150-180rpm is suitable
Thanks for attention