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Nanocrystals MoS2 - crystalline Nanocrystals MoS2 - crystalline stuff w/ Li to get LiMoS2 Nanocrystals MoS2 - crystalline stuff w/ Li to get LiMoS2 Severely disrupts structure Local structure well-defined, poor long range order Nanocrystals MoS2 - crystalline stuff w/ Li to get LiMoS2 Severely disrupts structure Local structure well-defined, poor long range order Use PDF Nanocrystals Lots of structure, but broad peaks, overlap PDF oscillations die out Nanocrystals MoS2 Best structure model for LiMoS2 (Li not shown, Mo dark) Mo-S trigonal prisms ––> distorted octahedra Nanocrystals LiMoO2 similar to LiMoS2 except not nanocrystalline Std crystal structure detn carried out "successfully" "PDF test" applied (radial distrib fcn shown) Nanocrystals LiMoO2 similar to LiMoS2 except not nanocrystalline Std crystal structure detn carried out "successfully" "PDF test" applied (radial distrib fcn shown) Corrected structure Mo-Mo bonding similar to Li MoS2 Nanocrystals V2O5•nH2O xerogel ribbon-like particles - approx. 100 Å wide x 1 long No Bragg peaks - some sharp features + lots of diffuse scattering Nanocrystals V2O5•nH2O xerogel ribbon-like particles - approx. 100 Å wide x 1 long No Bragg peaks - some sharp features + lots of diffuse scattering V2O5•nH2O xerogel V2O5 Nanocrystals V2O5•nH2O xerogel ribbon-like particles - approx. 100 Å wide x 1 long No Bragg peaks - some sharp features + lots of diffuse scattering V2O5•nH2O xerogel - VO5 bilayers approx. 11.5 Å apart w/ H2Os in betwn Stacking disorder in VO5 bilayers Ribbons curled & tangled V2O5 - ordered single layers of VO5 units QCs QCs QCs QCs