CG St. C. Kendall CG St. C. Kendall

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GEOL 751: Carbonate Petrography University of South Carolina Spring 2005

Professor Chris Kendall EWS 304 [email protected] 777.2410

GEOL 751 Lecture 6: Cementation &

Diagnesis

Precipitated Cements & Diagenesis of Carbonates

Limestones & Dolomites Tango!

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Carbonate Cement Fabrics

 Crust or rims coat grains  Syntaxial overgrowth – optical continuity with skeletal fabric Echinoid single crystals Brachiopod multiple crystals  Blocky equant - final void fill GEOL 751 Lecture 6: Cementation &

Diagnesis

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

Carbonate Cement Fabrics

Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall after RL Folk

Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

GEOL 751 Lecture 6: Cementation &

Diagnesis

GEOL 751 Lecture 6: Cementation &

Diagnesis

After James

GEOL 751 Lecture 6: Cementation &

Diagnesis

After James

GEOL 751 Lecture 6: Cementation &

Diagnesis

After James

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Belize Reef - Cementation Botryoidal Aragonite Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

Belize Reef - Cementation Botryoidal Aragonite Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

Eniwetok Atoll – Pleistocene

Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Isopachus Marine Cement C. G. St. C. Kendall GEOL 751 Lecture 6: Cementation &

Diagnesis

Eniwetok Atoll – Pleistocene

Isopachus Marine Aragonite Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Marine Cement Fabrics Aragonite Needles & Magnesium Calcite Blades

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

After James

After James Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

Eniwetok – Marshal Islands GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Dry Canyon – Almagordo, NMx GEOL 751 Lecture 6: Cementation &

Diagnesis

Canning Basin – Winjana Gorge

GEOL 751 Lecture 6: Cementation &

Diagnesis

Canning Basin – Winjana Gorge

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Canning Basin – Winjana Gorge

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Canning Basin – Winjana Gorge

Renalcis Drape Internal Sediment GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Cement Fill Amphipora Core GEOL 751 Lecture 6: Cementation &

Diagnesis

Renalcis Drape

Canning Basin – Winjana Gorge

Cement Fill Renalcis Drape Amphipora Core GEOL 751 Lecture 6: Cementation &

Diagnesis

Eniwetok – Pleistocene

GEOL 751 Lecture 6: Cementation &

Diagnesis

Canning Basin – Winjana Gorge

Final Cement Fill Brchiopod Core Isopachus Marine Cement Renalcis Drape GEOL 751 Lecture 6: Cementation &

Diagnesis

Canning Basin – Winjana Gorge

Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

Canning Basin – Winjana Gorge

Isopachus Marine Cement Isopachus Marine Cement Renalcis Drape GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Renalcis Drape Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Canning Basin – Winjana Gorge - Pilara

GEOL 751 Lecture 6: Cementation &

Diagnesis

After Phil Playford GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Canning Basin – Winjana Gorge - Pilara

Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

Canning Basin – Winjana Gorge - Pilara

Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

GEOL 751 Lecture 6: Cementation &

Diagnesis

After Phil Playford

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

C. G. St. C. Kendall GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall GEOL 751 Lecture 6: Cementation &

Diagnesis

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Isopachus Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Meniscus Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Arab D – Jurassic

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Eniwetok Atoll – Pleistocene

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Seven Rivers Permian Marine Cavity Cements & Sediment GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Seven Rivers Permian Marine Cavity Cements & Sediment GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

After James

C. G. St. C. Kendall GEOL 751 Lecture 6: Cementation &

Diagnesis

Settings of Carbonate Diagenesis Flow Chart

GEOL 751 Lecture 6: Cementation &

Diagnesis

After James

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Ooids - Calcite Fresh Water Cement

Meniscus Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Ooids – Aragonite Dissolution GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Radial Ooids – Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

Gastropod – Test Preserved GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Gastropod – Aragonite Marine Cement GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Gastropod – Dissolution of Test Starts GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Gastropod – Solution Ghost of Test GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Gastropod – Cement Fill of Test GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Pleistocene – Eniwetok GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Tertiary – Fusilinids

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Guadalupian – West Texas

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

After James GEOL 751 Lecture 6: Cementation &

Diagnesis

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Influx of sea water Evaporation of mixed Waters 1. Aragonite 2. Gypsum 3. Anhydrite 4. Dolomite 5. Halite accumulate in this order GEOL 751 Lecture 6: Cementation &

Diagnesis

Influx of Magnesium Rich Continental Ground Waters

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Smackover Jurassic

C. G. St. C. Kendall GEOL 751 Lecture 6: Cementation &

Diagnesis

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Smackover – Alabama

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Carbonate Porosity After Choquette & Pray

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

Smackover – Alabama

GEOL 751 Lecture 6: Cementation &

Diagnesis

Ooid Dissolution with Burial

GEOL 751 Lecture 6: Cementation &

Diagnesis

Ooid Cortex Collapse with Burial

GEOL 751 Lecture 6: Cementation &

Diagnesis

GEOL 751 Lecture 6: Cementation &

Diagnesis

C. G. St. C. Kendall

After James GEOL 751 Lecture 6: Cementation &

Diagnesis

GEOL 751 Lecture 6: Cementation &

Diagnesis

GEOL 751 Lecture 6: Cementation &

Diagnesis

Stylolite s

Two-dimensional cross-sectonal views of

 Dissolution seam(A),  Stylolite (B),  Highly serrate stylolite (C)  Deformed stylolite (D). A few grains are shown schematically to emphasize the change in scale from the previous figure GEOL 751 Lecture 6: Cementation &

Diagnesis

(after Bruce Railsback)

Stylolite s

Intergranular contacts as seen in thin section  Tangential (A)  flattened (B)  concavo-convex (C)  sutured (D)

Diagnesis

(after Bruce Railsback)

Stylolites

GEOL 751 Lecture 6: Cementation &

Diagnesis

After Bruce Railsback

Stylolites

After Bruce Railsback

Lecture Conclusions

        Photosynthesis, warm temperatures & low pressures in shallow water enhance carbonate distribution Carbonate cementation takes place in the depositional setting Carbonate cementation takes place from water pumped by tides, waves and evaporation of sea water CCD controls dissolution of carbonate and its recirculation as a cement Most diagenesis, dolomitization, & cementation of carbonates takes place at the near surface & trace elements can be used in this determination Carbonate cementation and diagenesis can take place through the burial cycle Mineralogy & fabric of cements varies with setting and mineralogy of the substrate Stylolites develop through burial & solution/compaction GEOL 751 Lecture 6: Cementation &

Diagnesis

End of the Lecture

Lets go for lunch!!!