Transcript UV LED
高功率紫外光氮化鋁銦鎵發光 二極體之研製 100-2622-E-006-024-CC3 Reporter : 成大微電子所張守進 合作企業 : 新世紀光電 email: [email protected] 2000’s Illumination 70’s Indicators (DIM LED) 80’s Signs (Multi-Color LED) 90’s Displays (Full-Color HB LED) Color + White HB + HP LED 2nd half 2000’s General Lighting (“SUPER” LED ?) White Applications of high-brightness LEDs • Signaling Indicators (lamp, numeric,…) Automotive (interior, exterior) Traffic lights Display (indoor/outdoor) • Illumination Backlighting Sign & decorating lighting Specialty lighting (flashlight,...) General illumination (2-5 more years) Applications of high-brightness LEDs Colored light in sign LED Lighting in demo. room Large-area outdoor display Landscape lighting Colored light in display window 可見光LED:中國大陸大量擴產 供過於求,利潤低 (Lighting??) UV LED: 技術門檻相對高 (large leakage current, poor crystal quality) Niche Application of UV LEDs •UV Curing •Bio •Synthesis of Vitamin D •Free-Space Communications ……. Introduction : High Power UV LED Technology Nichia (385 nm) LedEngin (365 nm) Luminus Devices (390 nm) SETI (240 – 400 nm) Characteristically narrow, well-defined output Enfis (395 nm module) In0.05Ga0.95N/GaN MQW In0.05Ga0.95N/AlGaN MQW Ni/Au semi-transparent layer Mg:GaN Mg:Al0.15Ga0.85N InGaN/GaN MQW Mg:GaN Mg:Al0.15Ga0.85N n-electrode Ti/Al/Ti/Au InGaN/AlGaN MQW Si:GaN Al2O3 Ni/Au semi-transparent layer nucleation layer n-electrode Ti/Al/Ti/Au Si:GaN Al2O3 nucleation layer Poor quality for In0.05Ga0.95N/Al0.18Ga0.82N MQW In0.05Ga0.95N/Al0.1Ga0.9N MQW LED Intensity (a.u.) In0.05Ga0.95N/Al0.18Ga0.82N MQW LED -6000 InGaN/GaN MQW LED 15 nm -3 -4000 +1 -1 -2 -2000 0 2000 Relative Diffraction Angle (arcsec) 5 PL intensity (a.u.) InGaN/Al0.1Ga0.9N MQW LED 4 InGaN/Al0.18Ga0.82N MQW LED InGaN/GaN MQW LED 3 2 1 0 300 400 500 600 Wavelength (nm) 700 Output Power (mW) 10 8 6 4 InGaN/Al0.1Ga0.9N MQW LED 2 0 InGaN/Al0.18Ga0.82N MQW LED 0 50 InGaN/GaN MQW LED 100 150 200 250 Current (mA) 300 Energy band diagram ΔE1 ΔE2 Al0.1Ga0.9N= 3.781 eV In0.05Ga0.95N= 3.394 eV GaN=3.42 eV Experiment p-GaN MQW n-GaN Buffer layer: 1)MOCVD AlN buffer 2)Sputtering AlN buffer Sapphire Substrate Advantage for Sputtering AlN buffer: 1)Easy to Growth 2)Time Saved 3)Better quality 4)Better Uniformity (002) And (102) XRD spectra of GaN with high temperature PVD AlN and LT GaN buffer on flat sapphire substrate LT-G a N buffe r S putte r-A lN buffe r FWHM 76.3 104 233.8 103 102 LT-G a N buffe r FWHM 381.7 450.7 103 I n te n s ity ( c p s ) 105 I n te n s ity ( c p s ) S putte r-A lN buffe r 102 101 101 -2000 -1500 -1000 500 0 -500 O M EG A _R EL (a rc se c ) (002) 1000 1500 2000 -2000 -1500 -1000 -500 0 500 O M EG A _R EL (a rc se c ) (102) 1000 1500 2000 (002) And (102) XRD spectra of GaN with high temperature PVD AlN and MOCVD AlN buffer on patterned sapphire substrate 002 Rocking Curve 102 Rocking Curve MOCVD AlN buffer Sputtering AlN buffer Intensity (a.u.) Intensity (a.u.) MOCVD AlN buffer Sputtering AlN buffer 16.9 17.0 17.1 17.2 17.3 17.4 scan (degree) FWHM Sputter:239.9 MOCVD:349.9 17.5 17.6 23.8 24.0 24.2 24.4 scan (degree) FWHM Sputter:240.9 MOCVD:429.9 I-V characteristics of UV LEDs with sputtered AlN nucleation layer (a) forward I-V and (b) reverse I-V characteristics of GaNbased UV LEDs. Here the “ESAN” and “IGN” stand for the ex-situ sputtered AlN and the in-situ GaN nucleation LED, respectively. Relationship of emission wavelength and 20mA output power of UV LEDs with and without AlN nucleation layer Measured light output power as a function of the entire emission peak wavelength of UV LEDs. The Inset is the output power enhancement ratio of exsitu AlN nucleation to in-situ GaN nucleation at 20 mA. Reliability of the UV LEDs with AlN nucleation layer power output (a) and reverse leakage current (b) reliabilities of UV LEDs with in-situ GaN nucleation and ex-situ sputtered AlN nucleation. Summary •Use Al0.1Ga0.9N quantum barrier to replace conventional GaN barrier better crystal quality, lower leakage current, improve LED performances •Use sputter AlN nucleation layer high productivity, better crystal quality, improved LED performances 新世紀光電 http://www.gpiled.com/web/page s/products/gv-x Thank You Q&A?