Transcript Athens_ICL_WP1_ESG - Workspace

5th Progress Meeting
INASCO (22nd/23rd May 2012)
Emile S. Greenhalgh, Project Co-Ordinator
The Composites Centre, Imperial College, London
© The Composites Centre, Imperial College London
Agenda – 3rd Progress Meeting
Tuesday 22nd May (am)
09:30
Coffee, Welcome and Introductions
09:45
Minutes of the Last Meeting
10:00
10:15
WP1: Management/Overview of Project and Deliverables (Imperial/SICOMP)
WP1: Status of project extension (Imperial/SICOMP)
10:30
10:45
WP2: Reinforcement Development (Nanocyl) - overall status and management
WP2: Partner Presentations (max 20 minutes each)
WP2 - Nanocyl, Swerea Sicomp, BAM, ETC
11:30
11:45
WP3: Multifunctional Resin Development (Imperial) - overall status and management
Partner Presentations (max 20 minutes each)
WP3 - Imperial College London, Swerea Sicomp, Inasco, Chalmers, Umeco, BAM,
ETC
12:30
WP8: Project Demonstration and Exploitation (Inasco)
13:00
Lunch
© The Composites Centre, Imperial College London
Agenda – 3rd Progress Meeting
Tuesday 22nd May (pm)
14:00
14:15
WP6: Systems (SICOMP)
Partner Presentations (max 20 minutes each)
WP6 - Swerea Sicomp, Imperial College London, Inasco, Volvo, ETC
15:15
15:30
WP7: Demonstrator Development (SICOMP)
Partner Presentations (max 20 minutes each)
WP7 - Swerea Sicomp, Imperial College London, Inasco, Chalmers, Umeco, Nanocyl,
BAM, Volvo, ETC
16:00
WP6/7 Discussion – Design of Wheel Well
17:00
End of day one
19:00
Common dinner in Athens
© The Composites Centre, Imperial College London
Agenda – 3rd Progress Meeting
Wednesday 23rd May (am)
09:15
Coffee and Welcome
09:30
WP4: Composite Manufacture (Umeco) - overall status and management
09:45
WP4: Discussion regarding weave issues and suggested
mitigation (Imperial)
10:45
Partner Presentations (max 20 minutes each)
WP4 – Umeco, Imperial College London, Inasco, Swerea SICOMP, Nanocyl
11:15
11:30
WP5: Composite Characterisation (BAM)
Partner Presentations (max 20 minutes each)
WP5 – BAM, Imperial College London, Swerea Sicomp, INASCO, Chalmers, Umeco
12:30
AOB, Date of next meeting and close
13:00
Lunch
14:00
Optional tour of INASCO facilities
© The Composites Centre, Imperial College London
Agenda – 3rd Progress Meeting
Objectives of Meeting
• Report on Progress in all Work Package, and compare with
plan
• Progress the design of the wheel well (WP6/7)
• Resolve the issue of the influence of weave on electrical
performance (WP4/5)
© The Composites Centre, Imperial College London
Evening Plans
Dinner is at 8pm and the location is
Filistron restaurant.
23, Apostolou Pavlou str.
Thission
Athens
11851
[email protected]
+30 103422897
http://www.filistron.com/
© The Composites Centre, Imperial College London
6
Actions from Last Meeting
Action
Action 2.12 Approach to David Porter at
Oxford University to discuss GIM modelling
in the context of structural power is still open.
MRS happy to invite DP to Umeco to discuss
this. ESG will contact him to arrange a
visit.
Action 3.10 Student projects are underway
at Imperial. Please approach ESG if you are
interested in being involved in these.
On
ESG
ICL/ALL
Outcome (Grey = complete)
Complete – but awaiting response
from David Porter
Complete - Currently two UG projects
underway looking at influence of
curvature on structural power
performance. One is making the Usection arms of the quadcopter from
a baseline structural power material
(PEGDGE + 10% IL). The other is
making a model car body out of the
material (Device B) in conjunction
with Umeco and McLaren cars.
There are also two MSc projects
which have just started. One is
looking at alternative separator
materials (in conjunction with
McLaren) and the other is
characterising the acoustic
performance of our materials.
© The Composites Centre, Imperial College London
Actions from Last Meeting (Continued)
Action
Action 4.3 ESG and LA have met to collate
and formulate the amended document and
formalize changes. ESG is currently revising
the document, which will be issued to Mr Bird
in February to apply for an extension.
Action 4.5 JS and PJ have developed a
plan to determine the effect of moisture on
the electrical properties, including its
monitoring and methods to extract effects of
moisture from all data established on resins
and laminates to date and in the future. The
document will be included with the minutes
and partners should provide comments.
Action 4.10 ACG to send a specification of
the
screening
tests
at
ACG
for
crashworthiness to MW. The specification
has now been sent to ICL, who are
developing it further and will issue a revised
specification.
Action 4.11 BAM sorting out the revised
sample code
© The Composites Centre, Imperial College London
On
ICL/ALL
JS/PJ/ALL
Outcome (Grey = complete)
Complete - Document has been
issued to the EU with request for an
extension. Mr Bird has been positive
about the outcome, but no further
information yet.
Complete – document issued
ESG
Complete – Sang will elaborate on
this
MW
Complete – BAM will elaborate on
this
Actions from Last Meeting (Continued)
Action
Action 4.12 VE have sent ICL and NANOCYL
information on the size of materials needed to make
battery cells from CNT-coated and CAG-coated
fabrics. NANOCYL and ICL will then send materials to
VE and LA for tests in WP6. Also LA is to provide the
MWCNT coated CF-fabric to KTH for coin cell
tests. Sicomp and ETC have started to produce and
test some smaller cells for evaluation of electrical
properties, currently working with small cells using
sheets of 40x40 mm. For the electrical properties of
the materials in a battery this is sufficient. VE
mentioned that 150x150mm cells have been
suggested, and are currently focusing on improvement
of the production method and the electrical
performance of the battery cells. VE said ETC can use
40x40 mm for evaluating the materials from a battery
perspective. If successful ETC can investigate the
possibility to scale up for mechanical testing.
© The Composites Centre, Imperial College London
On
VE/LA/ESG/
MH
Outcome (Grey = complete)
Actions from Last Meeting (Continued)
Action
On
SC/TC/QF
Action 4.15 SICOMP/ACG to press forward
on
development
of
small-scale
demonstrators to be used by the partners at
future events such as JEC in April 2012. TC
and QF/SC should discuss to move this
forward quickly.
Action 5.2 ESG/SN/MW to investigate scope ESG/SN/MW
for characterising the acoustic response of
the STORAGE materials.
ESG/MM/MW
Action 5.3 Regarding electrical connection of
the laminates, there was discussion that
read-across from lightning strike protection
on conventional composites in aerospace
applications could be utilized.
Action 5.4 GW and PC will provide contacts
GW/PC
in the aerospace industry who have
knowledge of lightning strike protection in
aircraft.
Action 5.5 ESG will proceed with the
ESG
extension application.
© The Composites Centre, Imperial College London
Outcome (Grey = complete)
Complete – presented at JEC,
Swedish national exhibition and
Imperial Festival events.
Complete – MSc student will be
working on this at ICL
Still being explored – there are some
parallels but nature of the electrical
loading is different.
Complete
Complete
Model Demonstrator
•
Radio controlled car built by SICOMP &
Umeco
 Two cell Device B laminates
 No batteries in car, battery in controller
charges roof laminate which lights LEDs
 Raised cutting/grinding issues –
laminates need to be made to size
•
Demonstrated at a exhibitions, etc
 Umeco stand at JEC (Paris, 03/2012)
 Swedish Foundation for Strategic
Research’s (SSF) Materials Science
Programme Conference - Stockholm
(04/2012).
 Video for ‘Fully-Charged’ show http://www.youtube.com/watch?v=rMOxrDxq_do&lis
t=PL971B96323746C745&index=8&feature=plcp
 Imperial Festival (05/2012)
© The Composites Centre, Imperial College London
11
Actions from Last Meeting (Continued)
Action
Action 5.6 Formulate a small test plan to
investigate the effect of moisture on electrical
and mechanical properties of the laminates,
as an extension of Action 4.5. It is suggested
this will utilize Device B, and use in-plane
shear testing. It is recognized that electrical
testing after preparation for mechanical
testing can be challenging, so perhaps the
‘traveller’ approach could be utilised here.
Action 5.7 There is a need to consider
metalized film for bagging of laminates to
avoid moisture ingress. TC has information
on the supply of such a metalized film which
he will send to NS.
Action 5.8 There was discussion regarding
cutting of these materials (which will need to
be done dry), and GW suggested cryogenic
cutting could be a good approach, and would
send further details of this.
© The Composites Centre, Imperial College London
On
ESG/SN/NS/
JS
Outcome (Grey = complete)
Plan for controlling moisture, using
travellers, has been devised, but
TC
Complete – now being used
GW
Actions from Last Meeting (Continued)
Action
Action 5.9 During the meeting there was
some discussion regarding weave style of
the laminates, and it was identified that
Devices A and B will need to be remade
using 5HS fabric rather than plain weave
material.
Action 5.10 SICOMP will consider Device G
and advise as to the approach to be taken
towards manufacture for mechanical testing.
Action 5.11 The test plan for the partners
has been drawn up; this will be agreed with
the
appropriate
partners.
However,
INASCO’s testing work is unclear; a short
presentation was sent to MW by Tasia Gkika.
The issues of what can be measured by
INASCO will be established by discussion
with Tasia.
Action 5.12 The temperature range and
humidity range still needs to be established,
and therefore a specification will be
compiled.
© The Composites Centre, Imperial College London
On
QF/SC
Outcome (Grey = complete)
Complete, but maybe revised. 5HS
was confirmed. However, an
unexpected problem has arisen which
we will discuss during WP4.
LA/TC
Complete
ESG/MW/TG
ESG/LA/MW/
PS
Actions from Last Meeting (Continued)
Action
Action 5.13 MW will circulate the test plan
and establish delivery dates for each stage
so that the testing schedule can be finalized.
Some fractography may be done at SICOMP
and ICL.
Action 5.14 For manufacturing plenum cover
parts TC needs some MTM57 UD prepreg,
any carbon fibre, about 10 cm width about
20 lm. Umeco will look into this.
Action 5.15 TC will consider the Gantt and
work description to integrate the additional
intermediate demonstrators, and will send
this to ESG.
Action 5.16 MH will look into a cost analysis
(if these costings can be compared in
generic terms without revealing industrially
sensitive process costs information.)
Action 5.17 Scope for a student project on
separators to complement STORAGE, and
also scope to characterise the impact of
different separator thicknesses/stiffnesses on
the mechanical properties (both elastic and
delamination).
© The Composites Centre, Imperial College London
On
MW
QF/SC/TC
Outcome (Grey = complete)
Complete – a test plan has been
issued (D5.1)
Complete
LA/TC
MH
ESG/SN
Complete – student project currently
underway to characterise this
Actions from Last Meeting (Continued)
Action
Action 5.18 PJ will ask TG for an
explanation of what the presentation is
showing.
Action 5.19 QF will send TC some samples
of veils, (typically a square foot).
Action 5.20 TC has encountered issues with
curing of his resins. He will discuss this with
NS and SC.
Action 5.21 Regarding D4.1, QF to ask for
information from partners to clarify what is
required.
Action 5.22 MM to speak to TG about their
expertise in electrical connection to
composite laminates.
© The Composites Centre, Imperial College London
On
PJ
Outcome (Grey = complete)
Complete
QF
TC/NS/SC
QF
MM
Complete
Report being issued to PC, and will
reply with comments
Dates for Future Meetings
(Assuming Extension)
December 2012
Progress Meeting #6 – Imperial College London, UK
June 2013
Final Meeting – Volvo Car Corporation, Sweden,
© The Composites Centre, Imperial College London
Device Configurations
Device #
Type
Reinforce (i)
Reinforce (ii)
Insulator*
Matrix
Mechanical Test
Regime
A
Baseline
T300 fabric
T300 fabric
ACG Style 120
MTM57
Full
None
Baseline
Multifuncti T300 fabric
onal
T300 fabric
ACG Style 120
MTM57:IL:Li
conc1
Reduced
Reduced
B
C
D
E
F
G
H
Supercap
T300 CNT
T300 CNT
1a
Supercap
T300 CNT
T300 CNT
1b
Supercap T300/AquaCyl T300/AquaCyl
2a
3+
3+
Baseline
CNT
Reinforced
T300 CNT
T300 CNT
ACG Style 120
ACG Style 120
ACG Style 120
ACG Style 120
T800 cloth
Metalised Film ACG Style 120
(unsized)
Pseudo cap MnO2 loaded
CAG
ACG Style 120
1
CAG
Battery 1
Electrical Test
Regime
MTM57:IL:Li
conc1
MTM57:IL:Li
conc2
MTM57:IL:Li
conc1
Full
Full
Reduced
Reduced
Full
Full
MTM57
Reduced
None
Full
Full
Reduced
Reduced
MTM57:IL:Li
conc1
MTM57:IL:Li
conc1
I
Capacitor 1 T300 fabric
T300 fabric
PET Film 1
MTM57
Full
Full
J
Capacitor 2 T300 fabric
T300 fabric
PET Film 2
MTM57
Reduced
Reduced
MTM57:IL:Li
K Supercaps
Hybrid 13 ply
Bestlaminates
of above Best
of
above
ACG
Style
120
None /GF/CF
Individual
cells only
(CF/GF/CF); Batteries 7 ply laminates
(CFi/GF/CF
ii
ii/GF/CFi)
conc1
© The Composites Centre, Imperial College London
Laminates
Panel
Details
Dimensions
Layup
(i)
Shear
180mm x
180mm
[±CF/•
±GF]S
X
(ii)
Compression
180mm x
180mm
[CF4]S
X
(iii)
Fracture
Toughness /
ILSS
180mm x
180mm
[CF/•
GF2/CF2/GF2/PTFE/CF2/
GF2/CF2/GF2/CF]
X
© The Composites Centre, Imperial College London
Mec Ele A
X
X
B
C
D
E
F
G
H
I
J
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
K
Laminates
Panels (i) and (v)
[±CF/±GF]S
Panel (ii) [CF 4] S
180 x 180 mm
Panel (iii)
[CF/GF2/CF2/GF2/PTFE/CF2/GF2/CF2/GF2/CF ]
© The Composites Centre, Imperial College London
Mechanical Testing Regime
Laminate #
Stacking
Sequence
1mm (4ply)
(i)
[±CF/•
±GF]S
> 2 mm
(ii)
[CF4]S
3mm
(iii)
[CF/•
GF2/CF2/GF2/PT
FE/CF2/GF2/CF2/GF2
/CF]
3 mm
(iii)
[CF/•
GF2/CF2/GF2/PT
FE/CF2/GF2/CF2/GF2
/CF]
(i)
[±CF/•
±GF]S
Test
method
Standard
In-plane
shear
modulus &
strength
+/- 45° tensile
test
DIN EN ISO 14129
- ASTM
D3039/D3039M
150mm x
25mm
ICL/BAM reduced/full
(DIN EN ISO
14126) ICL
90mm x
10mm
ICL/BAM reduced/full A,C,E,G,I
ILSS
bending test
(short beam)
DIN EN ISO 14130
- ASTM
D2344/D2344M
25mm x
12mm
BAM/
SICOMP
full
A,C,E,G,I
Interlaminar
fracture
toughness
energy
DCB test
DIN EN 6033/6034
180mm x
20mm
SICOMP
full
A,C,E,G,I
Tg
DMTA
cantilever
beam test
?
10mm x 2mm
Chalmers
?
full
A,C,E,G,I 0.4-0.6 mm
compressive
compression
strength &
test
modulus
© The Composites Centre, Imperial College London
Specimen
Test
Partner
Device #
Size
Regime
t
Properties
A-J
Electrical Testing
•
Supercapacitors:
 Charge-discharge experiments: Voltage - 0.1 V (most likely we will increase
voltage); Charge time 10 s (can be varied); Discharge time 10 s (can be varied).
 Cyclic voltammetry: sweep rates of 5 mV/s to 50 mV/s, window of −0.5 to 0.5 V.
 Electrochemical impedance; frequency range from 106 Hz to 10-3 Hz, sinusoidal
voltage amplitude 5 mV.
 Effect of moisture/temperature; DiAMon monitoring
•
Batteries:
 Capacity and energy cycling, (Charge/Discharge)
 Self discharge
 Internal resistance - pulsed charge/discharge
 OCV characterisation, Life length
•
Capacitors:
 effect of moisture and temperature
DiAMon monitoring
 dielectric strength ?
 capacitance/ (specific energy) - 0.1-100Hz at 1V
© The Composites Centre, Imperial College London
Gantt
1
2
3
4
5
6
7
8
9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42
2010
Task
Details
Management
J
1
10.2
1_1
10.2
Project Management
Reinforcement Development
Work Package 2 Management
Carbon fibre activation and grafting
Separator layer development
Anode (Metal Electrode) Development
2
46.5
2_0
2_1
2_2
2_3
2.5
25.5
4.0
14.5
3
71.5
3_0
3_1
3_2
3.5
34.5
20.0
4
41.0
4_0
4_1
4_2
4_3
4_4
4_5
1.5
20.0
3.5
3.5
9.0
3.5
5
53.0
5_0
5_1
5_2
5_3
5_4
2.0
14.5
22.0
9.5
5.0
6
30.0
6_0
6_1
6_2
6_3
6_4
6_5
1.0
4.5
14.5
8.0
1.0
1.0
7
45.7
7_0
7_1
7_2
7_3
7_4
2.0
6.0
15.0
14.0
8.7
8
5.0
8_1
5.0
F M A M
J
J
2011
A S
O N D
J
F M A M
J
J
2012
A S
O N D
J
F M A M
J
J
2013
A S
O N D
J
F M A M
J
Multifunctional Resin Development
Work Package 3 Management
Structural Electrolyte Development
Structural Dielectic Development
Composite Manufacture
Work Package 4 Management
Composite Processing
Capacitor Concepts
Battery Concepts
Supercapacitor Concepts
Hybrid Capacitor Concepts
Composite Characterisation
Work Package 5 Management
Characterisation of electrical properties
Characterisation of mechanical properties
Crashworthiness
Ranking of Devices
Systems
Work Package 6 Management
Concept Design
Power Management and Connectivity
Packaging and Integration
Cost and Benefits Modelling and Analysis
Ownership Issues
Demonstrator Development
Work Package 7 Management
Demonstrator Design
Demonstrator Manufacture
Demonstrator Testing and Evaluation
Demonstrator Assessment
Dissemination and Exploitation
Project Dissemination and Exploitation
© The Composites Centre, Imperial College London
22
Deliverables Completed to date
#
1.1
2.1
3.1
8.1
2.2
3.2
4.2
6.1
2.3
6.2
1.2
5.1
Deliverable name
Project Management plan, Risk
Register and Quality Plan
Delivery of optimised separator layer
Delivery of dielectric matrix materials
for capacitor applications
Internal collaborative website set-up
Report on the mechanical
characterisation of the activated and
CNT grafted carbon-fibres
Report on the development and
characterisation of matrix materials
for structural supercapacitor
applications
Completed fabrication of composite
capacitor devices
Report on the cost/benefits analysis
of structural power source materials
Report on SICOMP connector
development
Report on the ownership issues
associated with structural power
source materials
1-18 Month Report
Testing Plan
© The Composites Centre, Imperial College London
WP
Lead
Original
New Date
Motivation
WP1
ICL
Mar-10
Mar-10
Complete
WP2.2
NCYL
Sep-10
Dec-10
Complete
WP3.2
SICOMP
Sep-10
Dec-10
Complete
WP8.1
ICL
Mar-10
Dec-10
Complete
WP2.1
NCYL
Nov-10
Mar-11
Complete
WP3.1
ICL
Feb-11
Mar-11
Complete
WP4.2
ACG
Mar-11
Mar-11
Complete
WP6.4
SICOMP
Apr-11
May-11
Complete
WP2.3
NCYL
Dec-10
Jun-11
Complete
WP6.5
SICOMP
Jul-11
Jul-11
Complete
WP1
WP5
ICL
BAM
Jun-11
Aug-11
Feb-12
Complete
New Deliverable
23
Deliverables due soon
#
4.1
2.4
3.3
Deliverable name
Report on the generic fabrication
issues regarding fabrication of
composite structural devices and
recommended processing
guidelines
Report on the development and
scale-up of activated and CNT
grafted carbon-fibres for structural
power applications at NCYL
Report on the development and
characterisation of matrix materials
for structural hybrid capacitor and
battery applications
Report on anode layer development
and characterisation
WP
Lead
Original New Date
WP4.1
ACG
Mar-11
Feb-12
About to be issued - currently with
ESG
WP2.2
NCYL
May-11
Feb-12
Knock-on delays with D2.2
WP3.1 SICOMP
Jun-11
Feb-12
WP2.3
NCYL
Dec-10
Mar-12
4.3
Completed fabrication of composite
WP4.4
supercapacitor devices
ACG
May-11
Mar-12
4.4
Completed fabrication of composite
WP4.3
batteries devices
ACG
May-11
Jun-12
Dec-11
Jun-12
2.5
Report on the connectivity and
6.4 packaging issues of structural power WP6.2 SICOMP
source materials
© The Composites Centre, Imperial College London
Motivation
Research will focus on tasks
associated with hybrids once
supercapacitor and battery
technologies have been frozen.
Covering SICOMP metalized film
and ICL CAG configurations
Delays in constituent development
have had a knock-on effect on the
supercapacitor fabrication.
Delays in constituent development
have had a knock-on effect on
battery fabrication.
Delay associated with delays in
other WPs regarding
characterisation of devices
24
Deliverables due before next meeting
#
Deliverable name
WP
Report on the electrical properties of
5.2
WP5.1
structural power source materials
Report on the mechanical properties
5.3
WP5.2
of structural power source materials
6.3
5.5
Lead
BAM
Oct-11
Aug-12
BAM
Nov-11
Aug-12
Oct-11
Aug-12
BAM
Feb-12
Sep-12
ICL
Jun-11
Sep-12
Dec-11
Oct-12
Mar-12
Dec-12
Report on the conceptual design of
WP6.3 SICOMP
structural power source materials
Report on the ranking of the
structural power source devices
WP5.4
Report on improved performance of
3.4 multifunctional resins for structural WP3.1
supercapacitor applications
Original New Date
Chosen configuration for design of
WP6.1 SICOMP
demonstrator
Design of the demonstrators
7.1
WP7.1 SICOMP
complete
6.5
Completed fabrication of composite
WP4.5
hybrid capacitor devices
ACG
Aug-11
Dec-12
Report on the crashworthiness of
the structural power source devices
5.4
WP5.3
and methodology to mitigate thermal
issues
ACG
Dec-11
Dec-12
4.5
© The Composites Centre, Imperial College London
Motivation
Knock on from delays in
constituent development
Knock on from delays in
constituent development
Delay associated with delays in
other WPs regarding
characterisation of devices
Knock on from delays in
constituent development
Change in research focus. The
approach is to move effort to
further develop the resin
formulation chosen in D3.2 to
improve its mechanical properties.
Knock on associated with delay in
earlier WPs
Knock on associated with delay in
earlier WPs
Shifting of hybrid development has
led to a shift in fabrication (and
characterisation) of final devices.
Knock on from delays in
constituent development
25