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Apparent heat release model The first work in this direction derived from the first law of thermodynamics was proposed in Krieger and Borman [1967] and was called the computation of apparent heat release. The method takes neither heat transfer nor crevice effects into account, thus dQht is lumped into dQ = dQch − dQht and dmc = dmi =0 The apparent heat release dQ can be expressed as: This model is the same Rassweiler-Withrow model, assuming that γ(T) = n The difference between two modal are: Rassweiler-Withrow model: Apparent heat release model Apparent heat release model: So: Results: Apparent heat release model Apparent heat release model: So: Results: Solid: Apparent heat release model Dash-dotted: R&W model Apparent heat release model The net heat release trace and mass fraction burned profile from the Krieger and Borman model are similar to those from the Rassweiler-Withrow method, the first being physically the more accurate one. For this particular case, the Rassweiler-Withrow method yields a higher burn rate compared to the apparent heat release method for the same data. This is also reflected in the heat release trace, and the difference is due to the assumptions on n and Vj+1/2 in the Rassweiler-Withrow method. The mass fraction burned profile is calculated assuming that the mass of burned mixture is proportional to the amount of released chemical energy.