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Nano Functional Ceramic Lab. 指導教授:王聖璋 博士 報告人: 林恩賢 No.13 2016/7/13 Outline •Conclusion •Future work 2 Conclusion • The hydrogen adsorption/desorption experiments reveal that the synthesized nanoporous PtIr electrodes possess extraordinarily high active surface area. • The further electrochemical studies show that the presence of Ir dramatically improves the electrocatlytic activity of Pt toward the electrochemical oxidation of CO and methanol and the electrochemical reduction of oxygen. • Among the four synthesized nanoporous PtIr electrodes, Pt85Ir15, Pt72Ir28, Pt60Ir40, and Pt50Ir50, the nanoporous Pt60Ir40 electrode exhibits the largest electroactive surface area, the lowest charge-transfer resistance, and the highest electrochemical activity. 前次未來工作 • 利用熱壓法以及直接塗佈法製備膜電極組。 • Cathode Side (熱壓法) • Pt/C 20% • 熱壓壓力 = 100kg/cm2 • 熱壓溫度 = 140oC • • • • Anode Side (直接塗佈法) Pt-Ir NP Area 9cm2 Loading 1 mg/cm2 • 遇到的問題 • 1.熱壓後碳布脫落。 • 2.熱壓後膜電極組難以剝除。 • 可能解決方案 • 1.熱壓板先預熱。 • 2.增加熱壓壓力。 未來工作 • 同製程中加入CNT • Pt-Ir奈米粒子水電解以及燃料電池測試 • Paper review 6