lecture CH19 chem131pikul

Download Report

Transcript lecture CH19 chem131pikul

CHAPTER 19: Lipids
General, Organic, & Biological Chemistry
Janice Gorzynski Smith
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
1
CHAPTER 19: Lipids
Learning Objectives:
 Identify basic structure & function of lipids:
 Hydrolyzable Lipids:
 Waxes
 Triglycerols
 Phospholipids (and phospholipid bilayers)
 Nonhydrolyzable Lipids
 Steroids
 Fat soluble vitamins (A, D, E, K)
 Eicosanoids
CH 19 Homework:
End of Chapter problems: 32, 34, 38, 40, 42, 46, 50, 54, 56, 58, 64, 70, 72, 76, 78,
81, 84, 90, 98, 100
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
2
Lipids
Definition
•Lipids are biomolecules that are soluble in
organic solvents and insoluble in water.
•They are not defined by a particular
functional group, thus they have a variety
of structures and functions.
•They contain many nonpolar C—C and C—H bonds
and few polar bonds resulting in their water insolubility.
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
3
Lipids
Fatty Acids
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
4
Lipids
Fatty Acids
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
5
Lipids
Hydrolyzable Lipids
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
6
Lipids
Waxes
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
7
Lipids
Waxes
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
8
Lipids
Waxes
Hydrolysis of a wax can occur with acids, bases, or
enzyme catalyzed, reforming the fatty acid and alcohol.
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
9
Lipids
Triglycerols
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
10
Lipids
Triglycerols
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
11
Lipids
Triglycerols
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
12
Lipids
Triglycerols
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
13
Lipids
Phospholipids
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
14
Lipids
Phospholipids
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
15
Lipids
Phospholipids
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
16
Lipids
Phospholipids
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
17
Lipids
Phospholipids
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
18
Lipids
Nonhydrolyzable Lipids
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
19
Lipids
Steroids
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
20
Lipids
Steroids
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
21
Lipids
Steroids
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
22
Lipids
Steroids
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
23
Lipids
Fat Soluble Vitamins
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
24
Lipids
Fat Soluble Vitamins
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
25
Lipids
Fat Soluble Vitamins
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
26
Lipids
Fat Soluble Vitamins
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
27
Lipids
Eicosanoids
Smith, Janice Gorzynski. General, Organic,
& Biological Chemistry 2nd Ed.
28