Document 7892858

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Transcript Document 7892858

NOW some for you to try!!!
K3[Fe(CN)6]
Potassium hexacyanoferrate(III)
K2[PtCl4]
Potassium tetrachloroplatinate(II)
Na2[Fe(CO)4]
Sodium Tetracarbonylferrate(II)
[Co(H2O)2(NH3)4]Cl3
Tetraammindiaquacobalt(III) chloride
[Ni(H2O)(NH3)4]SO4
Tetraaminediaquanickel(II) sulfate
Na2[OsCl5N]
Sodium pentachloronitridoosmate(VI)
[CoCl(NO2)(NH3)4]Cl
Tetraaminechloronitritocobalt(III) chloride
[CoCl(NH2)(en)2]NO3
Amidochlorobis(ethylenediamine)cobalt(III) chloride
[FeH(CO)3(NO)]
Tricarbonylhydridonitrosyliron(I) ?(II)??
[PtCl(NH2CH3)(NH3)]Cl
Amminchloro(methylamine) platinum(II) chloride
Ionization isomerism
Polymerization isomerism
[Pt(NH3)3Cl2]
H3N
H3N
Cl
Pt
cis-
Cl
Cl
vs.
H3N
Pt
NH3
Cl
trans-
How could you tell the difference between geometric
isomers?
If the propeller is "right-handed", that is, it would tend to pull away from you if
you rotated it clockwise, then the molecule is the D-isomer.
If the propeller tends to move towards you when rotated clockwise, then it is the
L-isomer.
http://www.people.carleton.edu/~mcass/TrisChelates/Index.html