Transcript FINGERPRINTS OF DETECTED HYDROCARBON SPECIES FOR ALL SESSIONS WINTER

FINGERPRINTS OF DETECTED
HYDROCARBON SPECIES FOR ALL
SESSIONS
WINTER
NOTES:
• All
concentrations in the graphs are ng/L.
• For every classification only the compounds detected at least one session in
the order of elution from gas chromatograph were used for clarification.
•The list of species for x-axis were given in the next page.
• Preliminary data (checked only with QC in the ERMD Laboratories, no
further data validation) were used to prepare the graphs.
List of Components for X-Axis
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44
STREET-WINTER IN-CAR-WINTER IN-BUS-WINTER ROOFTOP-WINTER STREET-SUMMER
IN-CAR-SUMMER
ethylene
ethylene
ethylene
ethylene
ethylene
ethylene
ethane
ethane
ethane
ethane
ethane
ethane
acetylene
acetylene
acetylene
acetylene
acetylene
acetylene
propylene
propylene
propylene
propylene
propylene
propylene
propane
propane
propane
propane
propane
propane
propyne
propyne
propyne
isobutene/1-butene
propyne
propyne
isobutane
isobutane
isobutane
n-butane
isobutene/1-butene
isobutene/1-butene
isobutene/1-butene
isobutene/1-butene
isobutene/1-butene
t2-butene
13-butadiene
13-butadiene
13-butadiene
n-butane
n-butane
c2-butene
n-butane
n-butane
n-butane
t2-butene
t2-butene
2m-butane
t2-butene
t2-butene
t2-butene
c2-butene
c2-butene
n-pentane
c2-butene
c2-butene
c2-butene
3m1-butene
3m1-butene
t2-pentene
3m1-butene
3m1-butene
3m1-butene
2m-butane
2m-butane
22-dm-butane
2m-butane
2m-butane
2m-butane
14-pentadiene
1-pentene
cyclopentane
14-pentadiene
14-pentadiene
14-pentadiene
1-pentene
2m1-butene
23-dm-butane
1-pentene
1-pentene
2-butyne
2m1-butene
n-pentane
2m-pentane
2m1-butene
2m1-butene
1-pentene
n-pentane
2m-13-butadiene
3m-pentane
n-pentane
n-pentane
2m1-butene
2m-13-butadiene
t2-pentene
n-hexane
2m-13-butadiene
2m-13-butadiene
n-pentane
t2-pentene
c2-pentene
m-cyclopentane
t2-pentene
t2-pentene
2m-13-butadiene
c2-pentene
2m2-butene
benzene
c2-pentene
c2-pentene
t2-pentene
2m2-butene
22-dm-butane
2m-hexane
2m2-butene
2m2-butene
c2-pentene
22-dm-butane
cyclopentene
23-dm-pentane
22-dm-butane
22-dm-butane
2m2-butene
cyclopentene
cyclopentane
11-dm-cyP
cyclopentene
cyclopentene
22-dm-butane
4m1-pentene
23-dm-butane
cyclohexene
cyclopentane
cyclopentane
cyclopentene
cyclopentane
2m-pentane
3m-hexane
23-dm-butane
23-dm-butane
cyclopentane
23-dm-butane
3m-pentane
224-tm-pentane
2m-pentane
MTBE
23-dm-butane
MTBE
2m1-pentene
n-heptane
3m-pentane
2m-pentane
2m-pentane
2m-pentane
1-hexene
234-tm-pentane
1-hexene
3m-pentane
3m-pentane
3m-pentane
n-hexane
toluene/233-tm-pentane
n-hexane
2m1-pentene
2m1-pentene
2m1-pentene
c/t-3-hexene
2m-heptane
t2-hexene
1-hexene
1-hexene
1-hexene
t2-hexene
3m-heptane/3e-hexane
2m2-pentene
n-hexane
n-hexane
n-hexane
2m2-pentene
cct-124-tm-cyP/c-13-dm-cyH
c-3m2-pentene
c/t-3-hexene
t2-hexene
c/t-3-hexene
c-3m2-pentene
n-octane/t12-dm-cyH
m-cyclopentane
t2-hexene
2m2-pentene
t2-hexene
22-dm-pentane
24-dm-heptane
24-dm-pentane
2m2-pentene
t-3m2-pentene
2m2-pentene
m-cyclopentane
e-benzene
benzene
t-3m2-pentene
c2-hexene
t-3m2-pentene
24-dm-pentane
m&p-xylene/34-dm-heptanecyclohexane
c2-hexene
c-3m2-pentene
c2-hexene
benzene
o-xylene
2m-hexane
c-3m2-pentene
22-dm-pentane
c-3m2-pentene
33-dm-pentane
n-nonane
23-dm-pentane
22-dm-pentane
m-cyclopentane
22-dm-pentane
cyclohexane
n-propylbenzene
3m-hexane
m-cyclopentane
24-dm-pentane
m-cyclopentane
2m-hexane
3e-toluene
c-13-dm-cyP
24-dm-pentane
benzene
24-dm-pentane
23-dm-pentane
124-tm-benzene/tb-benz/1-decene
3e-pentane/t-13-dm-cyP
benzene
33-dm-pentane
benzene
3m-hexane
ib-cyH
224-tm-pentane
33-dm-pentane
cyclohexane
33-dm-pentane
c-13-dm-cyP
n-decane
n-heptane
cyclohexane
2m-hexane
cyclohexane
3e-pentane/t-13-dm-cyP3-ip-toluene
m-cyclohexane/22-dm-hexane
2m-hexane
List of Components for X-Axis
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STREET-WINTER IN-CAR-WINTER IN-BUS-WINTER ROOFTOP-WINTER STREET-SUMMER
25-dm-hexane/e-cyP
IN-CAR-SUMMER
23-dm-pentane
2m-hexane
t-12-dm-cyP/1-heptene 3-np-toluene
23-dm-pentane
cyclohexene
23-dm-pentane
224-tm-pentane
n-undecane/12dm-3e-benzene
24-dm-hexane/223-tm-pentane
11-dm-cyP
3m-hexane
3m-hexane
n-heptane
naphthalene
c-13-dm-cyP
c-13-dm-cyP
m-cyclohexane/22-dm-hexane
n-dodecane
ctc123-tm-cyP
3m-hexane
234-tm-pentane
c-13-dm-cyP
3e-pentane/t-13-dm-cyP3e-pentane/t-13-dm-cyP
25-dm-hexane/e-cyP
toluene/233-tm-pentane
3e-pentane/t-13-dm-cyP
t-12-dm-cyP/1-heptene t-12-dm-cyP/1-heptene24-dm-hexane/223-tm-pentane
2m-heptane
224-tm-pentane
224-tm-pentane
224-tm-pentane
33-dm-hexane/ctc124-tm-cyP
4m-C7/3m3e-C5/1m-cyHexene
n-heptane
n-heptane
n-heptane
ctc123-tm-cyP
34-dm-hexane
m-cyclohexane/22-dm-hexane
m-cyclohexane/22-dm-hexane
c3-heptene
234-tm-pentane
3m-heptane/3e-hexane
12dm-cyH
25-dm-hexane/e-cyP
toluene/233-tm-pentane
cct-124-tm-cyP/c-13-dm-cyH
25-dm-hexane/e-cyP
c2-heptene
24-dm-hexane/223-tm-pentane
m-cyclohexane/22-dm-hexane
23-dm-hexane
n-octane/t12-dm-cyH
24-dm-hexane/223-tm-pentane
33-dm-hexane/ctc124-tm-cyP
25-dm-hexane/e-cyP 2m-heptane
ip-cyP
234-tm-pentane
234-tm-pentane
44&22-dm-heptane
toluene/233-tm-pentane
toluene/233-tm-pentane33-dm-hexane/ctc124-tm-cyP
34-dm-hexane
24-dm-heptane
23-dm-hexane
23-dm-hexane
234-tm-pentane
26-dm-heptane/c12-dm-cyH2m-heptane
2m-heptane
toluene/233-tm-pentane
t-13-dm-cyH
24-dm-hexane/223-tm-pentane
4m-C7/3m3e-C5/1m-cyHexene
3m-heptane/3e-hexane
e-benzene
4m-C7/3m3e-C5/1m-cyHexene
4m-C7/3m3e-C5/1m-cyHexene
23-dm-hexane
cct-124-tm-cyP/c-13-dm-cyH
m&p-xylene/34-dm-heptane34-dm-hexane
34-dm-hexane
t-14-dm-cyH
2m-octane
3m-heptane/3e-hexane
3m-heptane/3e-hexane 4m-C7/3m3e-C5/1m-cyHexene
11-dm-cyH/1-octene
2m-heptane
246-tm-hexane
t-13-dm-cyH
t-13-dm-cyH
ctc-124-tm-cyH
cct-124-tm-cyP/c-13-dm-cyH
cct-124-tm-cyP/c-13-dm-cyH
3m-heptane/3e-hexanen-octane/t12-dm-cyH
o-xylene
225-tm-hexane
225-tm-hexane
t-13-dm-cyH
n-nonane
11-dm-cyH/1-octene
11-dm-cyH/1-octene
cct-124-tm-cyP/c-13-dm-cyH
244-tm-hexane
33-dm-octane
1e1m-cyP
1e1m-cyP
t-14-dm-cyH
44&22-dm-heptane
n-propylbenzene
n-octane/t12-dm-cyH
224-tm-hexane
225-tm-hexane
24-dm-heptane
3e-toluene
44&22-dm-heptane
n-octane/t12-dm-cyH
11-dm-cyH/1-octene 26-dm-heptane/c12-dm-cyH
4e-toluene/23-dm-octane
26-dm-heptane/c12-dm-cyH
244-tm-hexane
n-octane/t12-dm-cyH ccc-135-tm-cyH
135-tm-benzene
e-benzene
44&22-dm-heptane
244-tm-hexane
25-dm-heptane/35-dm-heptane
124-tm-benzene/tb-benz/1-decene
m&p-xylene/34-dm-heptane
25-dm-heptane/35-dm-heptane
235-tm-hexane
33-dm-heptane
ib-cyH
2m-octane
e-benzene
114-tm-cyH
n-decane
246-tm-hexane
m&p-xylene/34-dm-heptane
26-dm-heptane/c12-dm-cyH
e-benzene
ib-benzene/t-1m-2p-CyH
3m-octane
2m-octane
np-cyP/e-cyH
ctt-124-tm-cyH
sb-benzene
ctc-124-tm-cyH
3m-octane
ccc-135-tm-cyH
23-dm-heptane
3-ip-toluene
o-xylene
o-xylene
25-dm-heptane/35-dm-heptane
m&p-xylene/34-dm-heptane
123-tm-benzene
1-nonene/112-tm-cyH
n-nonane
33-dm-heptane
2m-octane
indan
t3-nonene
nb-cyP
114-tm-cyH
246-tm-hexane
13-de-benzene
n-nonane
n-propylbenzene
e-benzene
3m-octane
3-np-toluene
33-dm-octane
3e-toluene
ctt-124-tm-cyH
ctc-124-tm-cyH
4-np-toluene/nb-benz/13dm5e-benzene
n-propylbenzene
o-xylene
34-dm-hexane
24-dm-heptane
4e-toluene/23-dm-octane
23-dm-heptane
1e1m-cyP
t2-octene
12de-benzene
3e-toluene
135-tm-benzene
m&p-xylene/34-dm-heptane
1-nonene/112-tm-cyH
2-np-toluene
4e-toluene/23-dm-octane
2m-nonane
2m-octane
t3-nonene
14dm-2e-benzene
135-tm-benzene
2e-toluene/3m-nonane 246-tm-hexane
n-nonane
13dm-4e-benzene
2m-nonane
124-tm-benzene/tb-benz/1-decene
3m-octane
c2-nonene
12dm-4e-benzene
3e-octane
List of Components for X-Axis
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100
101
102
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104
105
106
107
108
109
110
111
112
113
114
115
116
117
118
119
120
121
122
123
124
125
126
127
128
129
130
131
132
STREET-WINTER IN-CAR-WINTER IN-BUS-WINTER ROOFTOP-WINTER STREET-SUMMER
IN-CAR-SUMMER
ib-cyH
ctc-124-tm-cyH
ip-benzene
n-undecane/12dm-3e-benzene
3m-nonane
n-decane
o-xylene
22-dm-octane
1245-ttm-benzene
2e-toluene/3m-nonane
3-ip-toluene
1-nonene/112-tm-cyH ip-cyH
naphthalene
124-tm-benzene/tb-benz/1-decene
123-tm-benzene
t3-nonene
nb-cyP
n-dodecane
ib-cyH
3-np-toluene
n-nonane
33-dm-octane
n-decane
4-np-toluene/nb-benz/13dm5e-benzene
c2-nonene
n-propylbenzene
3-ip-toluene
n-undecane/12dm-3e-benzene
ip-benzene
3e-toluene
123-tm-benzene
2mb-benzene
4e-toluene/23-dm-octane
indan
npentyl-benzene/t-1m-2-(4mp)CyP
ip-cyH
135-tm-benzene
3-np-toluene
naphthalene
nb-cyP
2m-nonane
2-np-toluene
n-dodecane
33-dm-octane
3e-octane
14dm-2e-benzene
n-propylbenzene
3m-nonane
n-undecane/12dm-3e-benzene
3e-toluene
2e-toluene/3m-nonane
1245-ttm-benzene
22-dm-octane
4e-toluene/23-dm-octane
124-tm-benzene/tb-benz/1-decene
npentyl-benzene/t-1m-2-(4mp)CyP
135-tm-benzene
ib-cyH
tb-35dm-benzene
2m-nonane
n-decane
naphthalene
3e-octane
ib-benzene/t-1m-2p-CyH
n-dodecane
3m-nonane
sb-benzene
2e-toluene/3m-nonane3-ip-toluene
124-tm-benzene/tb-benz/1-decene
123-tm-benzene
ib-cyH
4-ip-toluene
n-decane
indan
ib-benzene/t-1m-2p-CyH
2-ip-toluene
sb-benzene
13-de-benzene
3-ip-toluene
14-de-benzene
123-tm-benzene
3-np-toluene
indan
4-np-toluene/nb-benz/13dm5e-benzene
2-ip-toluene
12de-benzene
13-de-benzene
2-np-toluene
3-np-toluene
14dm-2e-benzene
4-np-toluene/nb-benz/13dm5e-benzene
13dm-4e-benzene
12de-benzene
12dm-4e-benzene
2-np-toluene
13dm-2e-benzene
14dm-2e-benzene
n-undecane/12dm-3e-benzene
13dm-4e-benzene
2mb-benzene
12dm-4e-benzene
1234-ttm-benzene
13dm-2e-benzene
npentyl-benzene/t-1m-2-(4mp)CyP
n-undecane/12dm-3e-benzene
tb-35dm-benzene
1245-ttm-benzene
naphthalene
2mb-benzene
n-dodecane
tb-2m-benzene
1234-ttm-benzene
npentyl-benzene/t-1m-2-(4mp)CyP
naphthalene
n-dodecane
Slater Street (Winter) 1
40
w21Jan7.30
w21Jan11.30
90
40
w21Jan3.30
90
w22Jan7.30
toluene/233-tm-pentane
30
2m-butane
m&p-xylene/34-dm-heptane
10
w19Jan24hr
w20Jan7.30
w20Jan11.30
w20Jan3.30
30
ethylene
10
w17Jan3.30
30
w18Jan7.30
w18Jan11.30
w18Jan3.30
2m-butane
m&p-xylene/34-dm-heptane
10
40
90
40
90
Slater Street (Winter) 2
40
w25Jan24hr
w26Jan7.30
90
40
w26Jan11.30
90
w26Jan3.30
30
20
toluene/233-tm-pentane
10
0
w23Jan3.30
w24Jan7.30
w24Jan11.30
w24Jan3.30
30
m&p-xylene/34-dm-hepta
124-tm-benzene/tb-be
20
ethylene
10
0
w2Jan11.30
w22Jan3.30
w23Jan7.30
w23Jan11.30
30
20
10
0
40
90
40
90
Slater Street (Winter) 3
40
90
40
w29Jan3.30
w30Jan7.30
w30Jan11.30
w30Jan3.30
w28Jan11.30
w28Jan3.30
w29Jan7.30
w29Jan11.30
90
30
10
toluene/233-tm-pentane
propane
30
10
w27Jan7.30
w27Jan11.30
w27Jan3.30
w28Jan7.30
30
10
40
90
40
90
Slater Street (Winter) 4
40
90
40
w03Feb11.30
w03Feb3.30
w04Feb7.30
w04Feb11.30
w02Feb7.30
w02Feb11.30
w02Feb3.30
w03Feb7.30
90
30
10
30
10
w31Jan24hr
w01Feb7.30
w01Feb11.30
w01Feb3.30
30
10
40
90
40
90
Slater Street (Winter) 5
w06Feb24hr
30
10
w05Feb11.30
w05Feb3.30
30
toluene/233-tm-pentane
2m-butane
m&p-xylene/34-dm-heptane
124-tm-benzene/tb-benz/1-decene
w04Feb3.30
w05Feb7.30
30
10
0
20
40
60
80
100
10
In-Car (Winter) 1
40
w25JanAM
100
w25JanPM
40
w26JanAM
w26JanPM
isobutane
w26JanPM = 79.03
2m-butane
w26JanPM = 59.01
naphthalene
w25JanAM = 40.99
30
100
20
10
0
w20JanPM
w21JanAM
w24JanAM n-decane
w24JanPM
w24JanAM = 35.18
30
20
10
0
w18JanAM
w18JanPM
w19JanAM
n-decane
propane
w18JanAM = 145.07w18JanAM = 42.06
n-decane
w19JanAM = 44.29
30
20
10
0
40
100
40
100
w20JanAM
In-Car (Winter) 2
40
w10FebPM
100
w11FebAM
40
w11FebPM
100
w14FebAM
toluene/233-tm-pentane
30
20
10
0
w8FebPM
w9FebAM
w9FebPM
w10FebAM
30
n-undecane/12dm-3e-benzene
20
10
0
w27JanAM
30
w28JanAM
w7FebPM
m&p-xylene/34-dm-heptane
propane
w27JanAM = 53.50
20
10
0
40
100
w8FebAM
40
100
In-Car (Winter) 3
w17FebPM
ethylene
2m-butane
naphthalene
toluene/233-tm-pentane
w16FebPM
w17FebAM
w15FebPM
w16FebAM
30
10
n-butane
30
10
w14FebPM
w15FebAM
30
10
30
80
130
In-Bus (Winter) 1
40
30
w25Janam
100
40
100
w25Janpm
w26Janam
w26Janpm
w20Janpm
w24Janam
w24Janpm
ethylene
10
w20Janam
30
10
30
w18Janam
w18Janpm
w19Janam
w19Janpm
n-decane
naphthalene
10
40
100
40
100
In-Bus (Winter) 2
40
100
40
100
w14Febpm
w15Febam
w15Febpm
w16Febam
w10Febam
w10Febpm
w11Febam
w11Febpm
30
10
30
10
w27Janam
w28Janam
w8Febam
30
10
40
100
40
100
w8Febpm
In-Bus (Winter) 3
30
w21Febpm
80
130
w22Febam
30
naphthalene
toluene/233-tm-pentane
10
w18Febpm
n-butane
2m-butane
30
w21Febam
m&p-xylene/34-dm-heptane
10
w17Febpm
w18Febam
30
10
w16Febpm
w17Febam
30
ib-cyH
10
30
80
130
Rooftop (24Hr) (Winter)
10
w2.5.2000
30
50
w2.6.2000
30
10
acetylene
isobutene/1-butene
acetylene
w2.1.2000
w2.4.2000
naphthalene
30
10
2m-butane
10
ib-cyH
30
50
FINGERPRINTS OF DETECTED
HYDROCARBON SPECIES FOR ALL
SESSIONS
SUMMER
Slater Street (Summer) 1
40
90
40
90
w1Aug7.30
w1Aug11.30
w1Aug3.30
w2Aug7.30
w30Jul3.30
w31Jul7.30
w31Jul11.30
w31Jul3.30
50
20
50
propane
20
3-ip-toluene
w28Jul11.30
w29Jul24hr
w30Jul7.30
w30Jul11.30
ib-cyH
50
44&22-dm-heptane
20
3-ip-toluene
40
90
40
90
Slater Street (Summer) 2
w4Aug24hr
15
10
5
0
w3Aug3.30
15
10
5
0
w3Aug11.30
15
10
5
0
15
10
5
0
w3Aug7.30
propane
3-ip-toluene
m&p-xylene/34-dm-heptane
w2Aug3.30
15
10
5
0
15
10
5
0
w2Aug11.30
ethylene
10
2m-butane
toluene/233-tm-pentane
30
50
70
12dm-4e-benzene
naphthalene
3-np-toluene
90
In-Car (Summer) 1
30
80
30
80
w21JulAM
w21JulPM
w24JulAM
w24JulPM
w19JulAM
w19JulPM
w20JulAM
w20JulPM
30
10
30
10
w17JulAM
w17JulPM
w18JulAM
30
10
30
80
30
80
w18JulPM
In-Car (Summer) 2
30
80
30
80
w8AugAM
w8AugPM
w9AugAM
w9AugPM
w27JulAM
w27JulPM
w28JulAM
w28JulPM
30
10
30
10
w25JulAM
w25JulPM
w26JulAM
30
10
30
80
30
80
w26JulPM
In-Car (Summer) 3
w11AugPM
15
10
5
0
w11AugAM
15
10
5
0
3-ip-toluene
w10AugPM
15
10
5
0
propylene
m&p-xylene/34-dm-heptane
w10AugAM
15
10
5
0
ethane
0
toluene/233-tm-pentane
cct-124-tm-cyP/c-13-dm-cyH
2m-butane
20
40
60
80
naphthalene
100
In-Bus (Summer) 1
40
100
40
100
w21JulAM
w21JulPM
w24JulAM
w24JulPM
w19JulAM
w19JulPM
w20JulAM
w20JulPM
30
10
30
10
w17JulAM
w17JulPM
w18JulAM
30
10
40
100
40
100
w18JulPM
In-Bus (Summer) 2
40
100
40
100
w8AugAM
w8AugPM
w9AugAM
w9AugPM
w27JulAM
w27JulPM
w28JulAM
w28JulPM
30
10
30
10
w25JulAM
w25JulPM
w26JulAM
30
10
40
100
40
100
w26JulPM
In-Bus (Summer) 3
w11AugPM
15
10
5
0
propane
3e-toluene
2m-pentane
w11AugAM
15
10
5
0
3-ip-toluene
m&p-xylene/34-dm-heptane
n-undecane/12dm-3e-benzene
w10AugPM
15
10
5
0
w10AugAM
15
10
5
0
toluene/233-tm-pentane
2m-butane
npentyl-benzene/t-1m-2-(4mp
0
20
40
60
80
100
120
Rooftop (24Hr) (Summer)
w4Aug24rooftop
w2Aug24rooftop
15
10
5
0
w3Aug24rooftop
44&22-dm-heptane
ib-cyH naphthalene
w31Jul24rooftop
ib-cyH
w1Aug24rooftop
propane
toluene/233-tm-pentane
2m-butane
w29Jul24rooftop
44&22-dm-heptane
15
10
5
0
w30Jul24rooftop
15
10
5
0
3-ip-toluene
3e-toluene
10
30
50