Chapter 9 Notes Part III Limiting Reagents & Percent Yield What are limiting reagents? • Up until now, we have assumed that all reactants.
Download ReportTranscript Chapter 9 Notes Part III Limiting Reagents & Percent Yield What are limiting reagents? • Up until now, we have assumed that all reactants.
Chapter 9 Notes Part III Limiting Reagents & Percent Yield What are limiting reagents? • Up until now, we have assumed that all reactants are used up in a reaction. • In actuality, usually one chemical runs out first, stopping the reaction—that chemical is called the limiting reagent. The limiting reagent limits or determines the amount of product that can be formed in a reaction. On the flip side, the excess reagent is the one not completely used up. How do you find what the limiting reagent is? • To find the limiting reagent, use dimensional analysis to determine how much of the product will be formed by both reactants. • The smaller of the two results will indicate which reactant is the limiting reagent. Here’s an example: In the reaction: Mg + HCl a MgCl2 + H2 you combine 35.5 grams of magnesium with 28.1 grams of hydrochloric acid. Which one is the limiting reagent, and how much magnesium chloride is produced? Percent Yield • In the real world, you never form 100% of the products that you think you should based on theoretical calculations. • By comparing how much of a product forms to how much should form based on stoichiometry, you can find the percent yield. Percent Yield %Yield= actual yield theoretical yield Practice Problem • In the reaction of nitrogen gas and hydrogen gas producing ammonia (NH3), 250.2g H2 produces 1095.1g NH3. What is the % yield of this reaction? Rxn #1—A Precipitation Rxn K2CrO4 + Pb(NO3)2 a KNO3 + PbCrO4 • If 0.947g K2CrO4 are combined with 0.331g Pb(NO3)2 what will be the limiting reagent, and how much lead chromate is produced? Rxn #2—Whoosh! • C3H8O + O2 a CO2 + H2O • If 3.78 L of O2 are combined with 7.9 g of C3H8O, what is the limiting reagent, and how much water is produced? Rxn #3—No, it’s not blood... K2CrO4 + AgNO3 a KNO3 + Ag2CrO4 • If 1.17g K2CrO4 are combined with 1.23g AgNO3, what is the limiting reagent and how much Ag2CrO4 is produced? Rxn #4—Hindenburg, 2004 • Zn + HCl a ZnCl2 + H2 • What is the limiting reagent and how many liters of hydrogen are produced if 15.5 grams of zinc are combined with 26.3 grams of hydrochloric acid? Rxn #5—Kaboom! • Na + H2O a NaOH + H2 • If 2.1g of sodium is added to 3.8g of water, what is the limiting reagent, and how many grams of sodium hydroxide are produced? In Review: What is a limiting reagent? What is the excess reagent? How does a limiting reagent control the amount of product?