Overview of Principles, Concepts, and Key Issues of Fusion Nuclear Technology Mohamed Abdou Professor of Engineering and Director of Fusion Science and Technology Center University of.
Download ReportTranscript Overview of Principles, Concepts, and Key Issues of Fusion Nuclear Technology Mohamed Abdou Professor of Engineering and Director of Fusion Science and Technology Center University of.
Overview of Principles, Concepts, and Key Issues of Fusion Nuclear Technology Mohamed Abdou Professor of Engineering and Director of Fusion Science and Technology Center University of California Los Angeles Seminar Presented to KAERI and KBSI, Korea, April 2004 Overview of Fusion Nuclear Technology (FNT) Seminar Outline Principles, Concepts, and Key Issues (this presentation/handout) • FNT components and functions • Tritium Breeding • Solid Breeders - Design Concepts and Materials - Tritium Release, Extraction - Issues and R&D • Structural Materials • Liquid Breeders - Concepts: Materials, Configurations - Li/V - LiPb Dual Coolant - Issues • Tritium Supply and Need for Blanket Testing in ITER • Possible Areas for US-Korea Collaboration Other Presentations / Handouts - Fabrication Technology - ITER Test Blanket Module (TBM) - ITER Testing : Engineering Scaling - Molten Salts Incentives for Developing Fusion • Fusion powers the Sun and the stars – It is now within reach for use on Earth • In the fusion process lighter elements are “fused” together, making heavier elements and producing prodigious amounts of energy • Fusion offers very attractive features: – Sustainable energy source (for DT cycle; provided that Breeding Blankets are successfully developed) – No emission of Greenhouse or other polluting gases – No risk of a severe accident – No long-lived radioactive waste • Fusion energy can be used to produce electricity and hydrogen, and for desalination The Deuterium-Tritium (D-T) Cycle • World Program is focused on the D-T cycle (easiest to ignite): D + T → n + α + 17.58 MeV • The fusion energy (17.58 MeV per reaction) appears as Kinetic Energy of neutrons (14.06 MeV) and alphas (3.52 MeV) • Tritium does not exist in nature! Decay half-life is 12.3 years (Tritium must be generated inside the fusion system to have a sustainable fuel cycle) • The only possibility to adequately breed tritium is through neutron interactions with lithium – Lithium, in some form, must be used in the fusion system Fusion Nuclear Technology (FNT) Fusion Power & Fuel Cycle Technology FNT Components from the edge of the Plasma to TF Coils (Reactor “Core”) 1. Blanket Components 2. Plasma Interactive and High Heat Flux Components a. divertor, limiter b. rf antennas, launchers, wave guides, etc. 3. Vacuum Vessel & Shield Components Other Components affected by the Nuclear Environment 4. Tritium Processing Systems 5. Instrumentation and Control Systems 6. Remote Maintenance Components 7. Heat Transport and Power Conversion Systems ARIES-AT Shield Blanket Vacuum vessel Radiation Plasma Neutrons First Wall Tritium breeding zone Coolant for energy conversion Magnets Blanket (including first wall) • Blanket Functions: A. Power Extraction – Convert kinetic energy of neutrons and secondary gamma-rays into heat – Absorb plasma radiation on the first wall – Extract the heat (at high temperature, for energy conversion) B. Tritium Breeding – Tritium breeding, extraction, and control – Must have lithium in some form for tritium breeding C. Physical Boundary for the Plasma – Physical boundary surrounding the plasma, inside the vacuum vessel – Provide access for plasma heating, fueling – Must be compatible with plasma operation – Innovative blanket concepts can improve plasma stability and confinement D. Radiation Shielding of the Vacuum Vessel Blanket Materials 1. Tritium Breeding Material (Lithium in some form) Liquid: Li, LiPb (83Pb 17Li), lithium-containing molten salts Solid: Li2O, Li4SiO4, Li2TiO3, Li2ZrO3 2. Neutron Multiplier (for most blanket concepts) Beryllium (Be, Be12Ti) Lead (in LiPb) 3. Coolant – Li, LiPb 4. – Molten Salt – Helium – Water Structural Material – Ferritic Steel (accepted worldwide as the reference for DEMO) – Long-term: Vanadium alloy (compatible only with Li), and SiC/SiC 5. MHD insulators (for concepts with self-cooled liquid metals) 6. Thermal insulators (only in some concepts with dual coolants) 7. Tritium Permeation Barriers (in some concepts) 8. Neutron Attenuators and Reflectors Notes on FNT: • The Vacuum Vessel is outside the Blanket (/Shield). It is in a lowradiation field. • Vacuum Vessel Development for DEMO should be in good shape from ITER experience. • The Key Issues are for Blanket / PFC. • Note that the first wall is an integral part of the blanket (ideas for a separate first wall were discarded in the 1980’s). The term “Blanket” now implicitly includes first wall. • Since the Blanket is inside of the vacuum vessel, many failures (e.g. coolant leak from module) require immediate shutdown and repair/replacement. Adaptation from ARIES-AT Design Heat and Radiation Loads on First Wall • Neutron Wall Load ≡ Pnw Pnw = Fusion Neutron Power Incident on the First Wall per unit area = JwEo Jw = fusion neutron (uncollided) current on the first wall Eo = Energy per fusion neutron = 14.06 MeV • Typical Neutron Wall Load ≡ 1-5 MW/m2 At 1 MW/m2: Jw = 4.43 x 1017 n · m-2 · s-1 • Note the neutron flux at the first wall (0-14 MeV) is about an order of magnitude higher than Jw • Surface heat flux at the first wall This is the plasma radiation load. It is a fraction of the α-power qw = 0.25 Pnw · fα where f is the fraction of the α-power reaching the first wall (note that the balance, 1 – f, goes to the divertor) Poloidal Variation of Neutron Wall Load – Neutron wall load has profile along the poloidal direction (due to combination of toroidal and poloidal geometries) –Peak to average is typically about 1.4 Inboard (equatorial plane, outboard, in 0º) outboard Tritium Breeding Li-6(n,alpha)t and Li-7(n,n,alpha)t Cross-Section 1000 Natural lithium contains 7.42% 6Li and 92.58% 7Li. 100 6Li (n,a) t Li-6(n,a) t Li-7(n,na)t 10 1 (n;n’a) t 0.01 1 10 100 1000 10 4 10 Neutron Energy (eV) 5 10 6 Li n t a 4.78MeV 7 Li n t a n 2.47MeV The 7Li(n;n’a)t reaction is a threshold reaction and requires an incident neutron energy in excess of 2.8 MeV. 0.1 7Li 6 10 7 Tritium Self-Sufficiency • TBR ≡ Tritium Breeding Ratio = N / N N = Rate of tritium production (primarily in the blanket) N = Rate of tritium consumption (burnt in plasma) Tritium self-sufficiency condition: Λa > Λr Λr = Required tritium breeding ratio Λr is 1 + G, where G is the margin required to: a) compensate for losses and radioactive decay between production and use, b) supply inventory for start-up of other fusion systems, and c) provide a hold-up inventory, which accounts for the time delay between production and use as well as reserve storage. Λr is dependent on many system parameters and features such as plasma edge recycling, tritium fractional burnup in the plasma, tritium inventories, doubling time, efficiency/capacity/reliability of the tritium processing system, etc. Λa = Achievable breeding ratio Λa is a function of FW thickness, amount of structure in the blanket, presence of stabilizing shell materials, PFC coating/tile/materials, material and geometry for divertor, plasma heating, fueling and penetration. Neutron Multipliers Examples of Neutron Multipliers Beryllium, Lead • Almost all concepts need a neutron multiplier to achieve adequate tritium breeding. (Possible exceptions: concepts with Li and Li2O) Be-9 (n,2n) and Pb(n,2n) Cross-Sections- JENDL-3.2 Data 10 • Desired characteristics: – Large (n, 2n) cross-section with low threshold – Small absorption cross-sections 1 Be-9 (n,2n) Pb (n,2n) • Candidates: – Beryllium is the best (large n, 2n with low threshold, low absorption) – Be12Ti may have the advantage of less tritium retention – Pb is less effective except in LiPb – Beryllium results in large energy multiplication, but resources are limited. 0.1 9Be (n,2n) Pb (n,2n) 0.01 0.001 10 6 10 Neutron Energy (eV) 7 Fuel Cycle Dynamics The D-T fuel cycle includes many components whose operation parameters and their uncertainties impact the required TBR Fueling Plasma Fuel management Plasma exhaust processing Impurity separation FW coolant processing Plasma Facing Component Solid waste Breeder Blanket Fuel inline storage Impurity processing Coolant tritium recovery system PFC Coolant Blanket Coolant processing Tritium waste treatment (TWT) Tritium shipment/permanent storage •ß: Tritium fraction burn-up Isotope separation system •Ti: mean T residence time in each component •Tritium inventory in each component Water stream and air processing waste Blanket tritium recovery system Only for solid breeder or liquid breeder design using separate coolant Examples of key parameters: Only for liquid breeder as coolant design •Doubling time •Days of tritium reserves •Extraction inefficiency in plasma exhaust processing Achievable TBR is Very Sensitive to FW Thickness 1.25 ARIES-ST 7% FS, 7% He, 12% SiC inserts, 74% LiPb Overall TBR 1.20 1.15 Required TBR 1.10 1.05 0 0.5 1 1.5 Effective Thick. of FS in OB FW (cm) 2 ITER FW Panel Cross Section TBR drops by up to 15% with 2 cm thick FS FW [L. El-Guebaly, Fusion Engr & Design, 2003] TBR is Very Sensitive to Structure Content in Blanket 2.0 1.5 Li 2O Breeder 1.8 1.4 V TBR TBR 1.6 V FS 1.3 0 5 10 FS SiC 1.4 1.2 SiC 1.2 Li 17Pb 83 Breeder (90% Li-6) 15 20 1.0 0 5 10 15 20 Structure Content (%) Structure Content (%) 2.0 Impact of structure content on TBR depends on breeder and structural material used Li Breeder 1.8 TBR 1.6 V V has the least impact on breeding FS 1.4 SiC Up to 30% reduction in TBR could result from using 20% structure in the blanket 1.2 1.0 0 5 10 15 Structure Content (%) 20 Note: Net TBR is substantially lower (~30-40%) than local TBR Blanket Concepts (many concepts proposed worldwide) A. B. Solid Breeder Concepts – Always separately cooled – Solid Breeder: Lithium Ceramic (Li2O, Li4SiO4, Li2TiO3, Li2ZrO3) – Coolant: Helium or Water Liquid Breeder Concepts Liquid breeder can be: a) Liquid metal (high conductivity, low Pr): Li, or 83Pb 17Li b) Molten salt (low conductivity, high Pr): Flibe (LiF)n · (BeF2), Flinabe (LiF-BeF2-NaF) B.1. Self-Cooled – Liquid breeder is circulated at high enough speed to also serve as coolant B.2. Separately Cooled – A separate coolant is used (e.g., helium) – The breeder is circulated only at low speed for tritium extraction B.3. Dual Coolant – FW and structure are cooled with separate coolant (He) – Breeding zone is self-cooled A Helium-Cooled Li-Ceramic Breeder Concept: Example Material Functions • Beryllium (pebble bed) for neutron multiplication • Ceramic breeder (Li4SiO4, Li2TiO3, Li2O, etc.) for tritium breeding • Helium purge (low pressure) to remove tritium through the “interconnected porosity” in ceramic breeder • High pressure Helium cooling in structure (ferritic steel) Several configurations exist (e.g. wall parallel or “head on” breeder/Be arrangements) JA Water-Cooled Solid Breeder Blanket Neutron Multiplier Be, Be12Ti (<2mm) Tritium Breeder Li2TiO3, Li2O (<2mm) Optional W coating for FW protection Coolant water (25MPa, 280/510oC) MW/m2 Surface Heat Flux:1 Neutron Wall Load: 5 MW/m2(1.5×1015n/cm2s) First Wall (RAFS, F82H) Helium-Cooled Pebble Breeder Concept for EU Helium-cooled stiffening grid Breeder unit FW channel Stiffening plate provides the mechanical strength to the structural box Radial-poloidal plate Grooves for helium coolant Helium Radial-toroidal plate Cut view Breeder Unit for EU Helium-Cooled Pebble Bed Concept Mechanisms of tritium transport (for solid breeders) Li(n, 4He)T Breeder pebble (solid/gas interface where adsorption/desorption occurs) Mechanisms of tritium transport 1) 2) 3) 4) 5) Intragranular diffusion Grain boundary diffusion Surface Adsorption/desorption Pore diffusion Purge flow convection Purge gas composition: He + 0.1% H2 Tritium release composition: T2, HT, T2O, HTO Some mathematical formulas Diffusion model: Generation rate C (r , t ) 2 C (r , t ) C (r , t ) G(r , t ) D(T ) 2 t r r r 2 Activation D(T ) D0 exp(Ed / RT ) energy C (r ,0) 0 C ( a, t ) 0 C (r , t ) 0 r r 0 3 n G 2 2 Ga ( 1 ) nr 2 2 2 2 C (a r ) sin x exp Dn t / a 3 6D D r n3 a First -order tritium release rate estimated: Surface concentration (atoms/m2) R(t ) dCs / dt K des (t )C s (t ) K 0 C s (t ) exp( E des / RT (t )) t rate constant Desorption C s (t ) C s 0 exp K 0 exp( E des / RT (t ' ))dt' 0 Desorption energy MISTRAL (Model for Investigative Studies of Tritium Release in Lithium Ceramics)- a code developed at UCLA To understand and predict tritium release characteristics Gas phase Solid phase Phenomenological cartoon Transport mechanisms included: grain diffusion grain boundary diffusions adsorption from the bulk and from the pores to the surface desorption to the pores diffusion through the pores Features • includes details of the ceramic microstructure • includes coverage dependence of the activation energy of surface processes (adsorption/ desorption) “Temperature Window” for Solid Breeders • The operating temperature of the solid breeder is limited to an acceptable “temperature window”: Tmin– Tmax – Tmin, lower temperature limit, is based on acceptable tritium transport characteristics (typically bulk diffusion). Tritium diffusion is slow at lower temperatures and leads to unacceptable tritium inventory retained in the solid breeder – Tmax, maximum temperature limit, to avoid sintering (thermal and radiation-induced sintering) which could inhibit tritium release; also to avoid mass transfer (e.g., LiOT vaporization) • The limitations on allowable temperature window, combined with the low thermal conductivity, place limits on allowable power density and achievable TBR Effect of helium purge flow rate on pressure drop and tritium permeation P 175 (1 a ) 2 f NRTL a3 (d p )2 Ab ( P0 P / 2) a =Porosity, = pebble sphericity =1 for spherical pebble N = moles/s R = ideal gas constant T = temperature single size bed binary bed Porosity, a f = helium gas viscosity Ab= gas flow cross-sectional area P0= inlet pressure L = flow path dp = particle diameter Which solid breeder ceramic is better? Parameters: Lithium density Tritium residence time Thermal-physical properties Mechanical properties Temperature window Transmutation nuclides (activation products) Reactivity Fabrication Irradiation effects (e.g, swelling) Notes: • Li2O is highly hygroscopic: 2Li2O + H2O → 2LiOH (ΔH = 128.9 kJ/mole); LiOH is highly corrosive • Li2O has been observed to swell under irradiation • Li2O is the only ceramic that may achieve the desired TBR without a neutron multiplier (but not assured) Properties are for 100% TD Li2O Li4SiO4 Li2TiO3 Li2ZrO3 Lithium Density (g/cm3) 0.94 0.51 0.43 0.38 Diameter (mm) ~1.0 0.2~0.7 0.7~0.85 0.9~1.5 Thermal Expansion @ 500 ° C (L/L0%) 1.25 1.15 0.8 0.5 Thermal Conductivity 4.7 2.4 1.8 @ 500 ° C (W/m/ ° C) Higher design margin 0.75 Min.-Max. Temp. for Tritium Release (°C) 397795 325-925 Up to 900 400-1400 Relatively narrow T window Swelling @500 ° C 7.0 1.7 - < 0.7 Reactivity w/H20 High Little Less Less Grain Size (μm) 50 5-15 1-4 0.5-2 80-85 ~98 87~89 93~96 Crush Load (N) - ~ 10 24-33 68-79 Residence time @400 °C (h) 10 (V/V0%) Pore for Density (%TD) tritium release 2 2 1 Tritium Extraction for Solid Breeder Blankets 1% H2 Absorb impurities from tritium stream at ambient temperature Remove the remaining impurities and the hydrogen isotopes at a cryogenic temperature molecular sieve bed Tritium form: HT and HTO The “bleed” stream is sent to a shift catalyst bed where reactions such as steam reforming and water gas shift can be used to move hydrogen isotopes from impurities such as CQ4 and Q2O to the form of Q2 Legend AMSB CMSB CR ISS TWT Ambient Molecular Sieve Bed Cryogenic Molecular Sieve Bed Catalytic Reactor Isotope Separation System Tritium Waste Treatment When the CMSB is saturated with Q2 (hydrogen isotopes) it is taken off line for regeneration and its companion bed can be put into service. A CMSB is regenerated by warming. The Q2 desorbs and is sent to a Pd/Ag permeator. Solid Breeder Concepts: Key Advantages and Disadvantages Advantages • Non-mobile breeder permits, in principle, selection of a coolant that avoids problems related to safety, corrosion, MHD Disadvantages • Low thermal conductivity, k, of solid breeder ceramics – Intrinsically low even at 100% of theoretical density (~ 1-3 W · m-1 · c-1 for ternary ceramics) – k is lower at the 20-40% porosity required for effective tritium release – Further reduction in k under irradiation • Low k, combined with the allowable operating “temperature window” for solid breeders, results in: – Limitations on power density, especially behind first wall and next to the neutron multiplier (limits on wall load and surface heat flux) – Limits on achievable tritium breeding ratio (beryllium must always be used; still TBR is limited) because of increase in structure-to-breeder ratio • A number of key issues that are yet to be resolved (all liquid and solid breeder concepts have feasibility issues) Configurations and Interactions among breeder/Be/coolant/structure are very important and often represent the most critical feasibility issues. • Configuration (e.g. wall parallel or “head on” breeder/Be arrangements) affects TBR and performance • Tritium breeding and release - Max. allowable temp. (radiationinduced sintering in solid breeder inhibits tritium release; mass transfer, e.g. LiOT formation) - Min. allowable Temp. (tritium inventory, tritium diffusion - Temp. window (Tmax-Tmin) limits and ke for breeder determine breeder/structure ratio and TBR • Thermomechanics interactions of breeder/Be/coolant/structure involve many feasibility issues (cracking of breeder, formation of gaps leading to big reduction in interface conductance and excessive temperatures) Thermal creep trains of Li2TiO3 pebble bed at different stress levels and temperatures Solid Breeder Blanket Issues Tritium self-sufficiency Breeder/Multiplier/structure interactive effects under nuclear heating and irradiation Tritium inventory, recovery and control; development of tritium permeation barriers Effective thermal conductivity, interface thermal conductance, thermal control Allowable operating temperature window for breeder Failure modes, effects, and rates Mass transfer Temperature limits for structural materials and coolants Mechanical loads caused by major plasma disruption Response to off-normal conditions Major R&D Tasks for Solid Breeder Blanket • Solid breeder material development, characterization, and fabrication • Multiplier material development, characterization, and fabrication • Tritium inventory in beryllium; swelling in beryllium irradiated at temperature, including effects of form and porosity • Breeder and Multiplier Pebble Bed Characterization • Pebble bed thermo-physical and mechanical properties, thermomechanic interactions • Blanket Thermal Behavior • • • • • Neutronics and tritium breeding Tritium Permeation and Processing Nuclear Design and Analysis (Modeling Development) Advanced In-Situ Tritium Recovery (Fission Tests) Fusion Test Modules Design Fabrication and Testing • Material and Structural Response Structural Materials • Key issues include thermal stress capacity, coolant compatibility, waste disposal, and radiation damage effects • The 3 leading candidates are ferritic/martensitic steel, V alloys and SiC/SiC (based on safety, waste disposal, and performance considerations) • The ferritic/martensitic steel is the reference structural material for DEMO – Commercial alloys (Ti alloys, Ni base superalloys, refractory alloys, etc.) have been shown to be unacceptable for fusion for various technical reasons Structural Material Coolant/Tritium Breeding Material Li/Li Ferritic steel V alloy SiC/SiC He/PbLi H2O/PbLi He/Li ceramic H2O/Li ceramic FLiBe/FLiBe Comparison of fission and fusion structural materials requirements Fission (Gen. I) Fission (Gen. IV) Fusion (Demo) Structural alloy maximum temperature <300˚C 600-850˚C (~1000˚C for GFRs) 550-700˚C (1000˚C for SiC) Max dose for core internal structures ~1 dpa ~30-100 dpa ~150 dpa Max transmutation helium concentration ~0.1 appm ~3-10 appm ~1500 appm (~10000 appm for SiC) • Fusion has obtained enormous benefits from pioneering radiation effects research performed for fission reactors – Although the fusion materials environment is very hostile, there is confidence that satisfactory radiation-resistant reduced activation materials can be developed if a suitable fusion irradiation test facility is available Fission (PWR) Fusion structure Coal Tritium in fusion Liquid Breeders • Many liquid breeder concepts exist, all of which have key feasibility issues. Selection can not prudently be made before additional R&D results become available. • Type of Liquid Breeder: Two different classes of materials with markedly different issues. a) Liquid Metal: Li, 83Pb 17Li High conductivity, low Pr number Dominant issues: MHD, chemical reactivity for Li, tritium permeation for LiPb b) Molten Salt: Flibe (LiF)n · (BeF2), Flinabe (LiF-BeF2-NaF) Low conductivity, high Pr number Dominant Issues: Melting point, chemistry, tritium control Liquid Breeder Blanket Concepts 1. Self-Cooled – Liquid breeder circulated at high speed to serve as coolant – Concepts: Li/V, Flibe/advanced ferritic, flinabe/FS 2. Separately Cooled – A separate coolant, typically helium, is used. The breeder is circulated at low speed for tritium extraction. – Concepts: LiPb/He/FS, Li/He/FS 3. Dual Coolant – First Wall (highest heat flux region) and structure are cooled with a separate coolant (helium). The idea is to keep the temperature of the structure (ferritic steel) below 550ºC, and the interface temperature below 480ºC. – The liquid breeder is self-cooled; i.e., in the breeder region, the liquid serves as breeder and coolant. The temperature of the breeder can be kept higher than the structure temperature through design, leading to higher thermal efficiency. Physical Properties of Molten Natural Li (temperature in degrees Kelvin) Valid for T = 455-1500 K Melting Temperature: 454 K (181ºC) Density [1] r (kg/m3) = 278.5 - 0.04657 · T + 274.6 (1-T/3500)0.467 Specific heat [1; see also 2] CP (J/kg-K) = 4754 - 0.925 · T + 2.91 x 10-4 · T2 Thermal conductivity [1] Kth (W/m-K) = 22.28 + 0.0500 · T - 1.243 x 10-5 · T2 Electrical resistivity [1] re (nWm) = -64.9 + 1.064 · T - 1.035 x 10-3 T2 + 5.33 x 10-7 T3 - 9.23 x 10-12 T4 Surface tension [1] g (N/m) = 0.398 - 0.147 x 10-3 · T Dynamic viscosity [1] note: h = ru where u = kinematic viscosity (m2/s) ln h (Pa - s) = -4.164 - 0.6374 ln T + 292.1/T Vapor pressure [1] ln P (Pa) = 26.89 - 18880/T - 0.4942 ln T References: [1] R.W. Ohse (Ed.) Handbook of Thermodynamic and Transport Properties of Alkali Metals, Intern. Union of Pure and Applied Chemistry Chemical Data Series No. 30. Oxford: Blackwell Scientific Publ., 1985, pp. 987. [2] C.B. Alcock, M.W. Chase, V.P. Itkin, J. Phys. Chem. Ref. Data 23 (1994) 385. Physical Properties of Pb-17Li Melting Temperature: TM = 507 K (234ºC) Density [1] r (kg/m3) = 10.45 x 103 (1 - 161 x 10-6 T) 508-625 K Specific heat [1] CP [J/kg-K] = 195 - 9.116 x 10-3 T 508-800 K Thermal Conductivity [1] Kth (W/m-K) = 1.95 + 0.0195 T 508-625 K Electrical resistivity [1] re (nW-m) = 10.23 + 0.00426 T 508-933 K Surface tension [2,3] g(N/m) =0.52 - 0.11 x 10-3 T 520-1000 K Dynamic viscosity [1] h (Pa - s) = 0.187 x 10-3 exp [1400./T] 521-900 K Vapor pressure [2-4] P (Pa) = 1.5 x 1010 exp (-22900/T) 550-1000 K References: [1] B. Schulz, Fusion Eng. Design 14 (1991) 199. [2] H.E.J. Schins, Liquid Metals for Heat Pipes, Properties, Plots and Data Sheets, JRC-Ispra (1967) [3] R.E. Buxbaum, J. Less-Common Metals 97 (1984) 27. [4] H. Feuerstein et al., Fusion Eng. Design 17 (1991) 203. Physical Properties of Molten Flibe (LiF)n · (BeF2) Melting temperature [1] TM(K) = 636 K (363ºC) TM(K) = 732 K (459ºC) n=0.88 n=2 (TM=653 K for n=1) Density [2] r (kg/m3) =2349 – 0.424 · T r (kg/m3) =2413 – 0.488 · T n=1 n=2 930-1130 K 800-1080 K Specific heat [3] CP (J/kg-K) ≈ 2380 n=2 600-1200 K ? Thermal conductivity [3] Kth (W/m-K) = 1.0 n=2 600-1200 K ? Electrical resistivity [2] re (W-m) = 0.960 x 10-4 exp (3982/T) re (W-m) = 3.030 x 10-4 exp (2364/T) n=1 n-2 680-790 K 750-920 K Surface tension [2,4] g (N/m) = 0.2978 - 0.12 x 10-3 · T g (N/m) = 0.2958 - 0.12 x 10-3 · T n=1 n=2 830-1070 K 770-1070 K Dynamic viscosity [2] h(Pa - s) = 6.27 x 10-6 exp (7780/T) h(Pa - s) = 5.94 x 10-5 exp (4605/T) n=1 n=2 680-840 K 740-860 K Vapor pressure [3] P (Pa) = 1.5 x 1011 exp (-24200/T) n=2 770-970 K References: [1] K.A. Romberger, J. Braunstein, R.E. Thoma, J. Phys. Chem. 76 (1972) 1154. [2] G.J. Janz, Thermodynamic and Transport Properties for Molten Salts: Correlation equations for critically evaluated density, surface tension, electrical conductance, and viscosity data, J. Phys. Chem. Ref. Data 17, Supplement 2 (1988) 1. [3] S. Cantor et al., Physical Properties of Molten-Salt Reactor Fuel, Coolant and Flush-Salts, ORNL-TM-2316 (August 1968). [4] K. Yajima, H. Moriyama, J. Oishi, Y. Tominaga, J. Phys. Chem. 86 (1982) 4193. Liquid Breeders Summary of some physical property data • Some key physical property data for Flinabe are not yet available – (melting temperature measurements for promising compositions are in progress. Measurement at Sandia in early 2004 shows ~ 300ºC) • Physical property data for Flibe are available from the MSR over a limited temperature range Flows of electrically conducting coolants will experience complicated magnetohydrodynamic (MHD) effects What is magnetohydrodynamics (MHD)? – Motion of a conductor in a magnetic field produces an EMF that can induce current in the liquid. This must be added to Ohm’s law: j (E V B) – Any induced current in the liquid results in an additional body force in the liquid that usually opposes the motion. This body force must be included in the Navier-Stokes equation of motion: V 1 1 (V )V p 2 V g j B t r r – For liquid metal coolant, this body force can have dramatic impact on the flow: e.g. enormous MHD drag, highly distorted velocity profiles, non-uniform flow distribution, modified or suppressed turbulent fluctuations Large MHD drag results in large MHD pressure drop Conducting walls Insulated wall Lines of current enter the low resistance wall – leads to very high induced current and high pressure drop 1 0.8 0.6 0.4 1 0.8 0.6 0.4 0.2 0.2 0 0 -0.2 -0.2 All current must close in the liquid near the wall – net drag from jxB force is zero -0.4 -0.6 -0.8 -1 • • -0.6 -0.8 -1 -1 -1 • -0.4 -0.8 -0.6 -0.4 -0.2 0 0.2 0.4 0.6 0.8 -0.8 -0.6 -0.4 -0.2 0 0.2 0.4 0.6 0.8 1 1 Net JxB body force p = cVB2 where c = (tw w)/(a ) For high magnetic field and high speed (self-cooled LM concepts in inboard region) the pressure drop is large The resulting stresses on the wall exceed the allowable stress for candidate structural materials • • Perfect insulators make the net MHD body force zero But insulator coating crack tolerance is very low (~10-7). – • It appears impossible to develop practical insulators under fusion environment conditions with large temperature, stress, and radiation gradients Self-healing coatings have been proposed but none has yet been found (research is on-going) LM-MHD pressure drop window for inboard channels is closed! ( NWL ) L2 B 2 w S rc p T Lithium Inboard Base Case (Sze, 1992) - NWL = 5 MW/m2 - Blanket Thickness = 0.2 m - Blanket Length = 6.0 m ITER FW ARIES-RS FW - Coolant Bulk T rise = 200 K Pipe Stress (MPa) 300 250 Base Case 200 Blanket Thickness = .25 m 150 Flow Length = 4 m 100 Bulk T rise = 300 K 50 NWL = 2.5 MW/m2 0 1 2 U ~ .2-.3 m/s 3 4 5 6 7 8 9 10 11 12 13 14 15 Magnetic Field (T) So a strategy is needed to reduce MHD pressure drop for liquid metals PMHD KL lUB 2 “K” factor represents a measure of relative conductance of induced current closure paths • Lower K Main options considered: Break – Insulator coatings/Laminated walls electrical coupling to load bearing – Flow channel inserts walls so pipe walls can be made thick for more strength without – Elongated channels with anchor also increasing pressure drop! links or other design solutions • Lower Velocity: U – Heat transfer enhancement or dual/separate coolant to lower velocity required for first wall/breeder zone cooling – High temperature difference operation to lower mass flow • Lower Magnetic field and flow length: B,L – Outboard blanket only, with poloidal segmentation • Lower electrical conductivity: (molten salt) Li/Vanadium Blanket Concept Vanadium structure Li Lithium Secondary Shield Li Primary Shield Li Reflector Breeding Zone (Li flow) Primary shield (Tenelon) Secondary shield (B4C) Reflector Vanadium structure Lithium Issues with the Lithium/Vanadium Concept • Li/V was the U.S. choice for a long time, because of its perceived simplicity. But negative R&D results and lack of progress on serious feasibility issues have eliminated U.S. interest in this concept as a near-term option. Issues • Insulator Insulating layer Conducting wall – Insulator coating is required – Crack tolerance (10-7) appears too low to be achievable in the fusion environment – “Self-healing” coatings can solve the problem, but none has yet been found (research is ongoing) • Corrosion at high temperature (coupled to coating development) – Existing compatibility data are limited to maximum temperature of 550ºC and do not support the BCSS reported corrosion limit of 5m/year at 650ºC Leakage current • • Electric currents lines Crack Tritium recovery and control Vanadium alloy development is very costly and requires a very long time to complete EU – The Helium-Cooled Lead Lithium (HCLL) DEMO Blanket Concept Module box (container & surface heat flux extraction) Breeder cooling unit (heat extraction from PbLi) [18-54] mm/s [0.5-1.5] mm/s Stiffening structure (resistance to accidental in-box pressurization i.e He leakage) He collector system (back) HCLL PbLi flow scheme He-Cooled PbLi Flow Scheme • PbLi is fed at the top and collected at the back • Meandering PbLi flows in vertical columns delimited by vertical SPs • Alternative flow holes at front/back of horizontal SPs [18-54] mm/s PbLi inlet [0.5-1.5] mm/s pol rad PbLi outlet Key features of Dual Coolant Lead-Lithium Concept (One of the concepts considered by the U.S. for ITER TBM) • Cool the ferritic steel FW and structure with separate coolant – He (also used for FW/blanket preheating and possible tritium control) – The idea is to keep the structure temperature below 550ºC, the allowable temperature for ferritic steel, and the interface temperature below 480ºC • Breeding zone is self-cooled PbLi – PbLi can be moving at slow velocity, since the heat generation rate in the breeding zone is lower than the surface heat flux at the FW – PbLi can be operated at temperatures higher than the structure, for higher thermodynamic efficiency. – Some type of thermal/MHD insulator, e.g., FCIs, is required, but the requirements are more relaxed than for “all self-cooled” concepts • Use flow channel inserts (FCIs), wherever possible to: – Provide electrical insulation to reduce MHD pressure drop – Provide thermal insulation to decouple PbLi bulk flow temperature from wall temperature – Provide permeation barrier to reduce T permeation into the He system – Provide additional corrosion resistance since only stagnant PbLi is in contact with the ferritic steel structural walls Dual Coolant Concept Designs from EU and USA Cross section of the breeder region unit cell (ARIES) Flow Channel Insert Properties and Failures are Dominant Issues for PbLi Dual Coolant Blankets • Electrical and thermal conductivity of the SiC/SiC should be as low as possible to avoid velocity profiles with side-layer jets and excess heat transfer to the He-cooled structure. • The inserts have to be compatible with Pb-17Li at temperatures up to 700-800 °C • Liquid metal must not “soak” into pores of the composite in order to avoid increased electrical conductivity and high tritium retention. In general “sealing layers” are required on all surfaces of the inserts. – even if the change in conductivity is modest from pressure drop point of view it could also affect flow balance • There are minimum primary stresses in the inserts. However, secondary stresses caused by temperature gradients must not endanger the integrity under high neutron fluence. • The insert must be applicable and affordable Molten Salt Concepts: Advantages and Issues Advantages • Very low pressure operation • Very low tritium solubility • Low MHD interaction • Relatively inert with air and water • Pure material compatible with many structural materials • Relatively low thermal conductivity allows dual coolant concept (high thermal efficiency) without the use of flow-channel inserts Disadvantages • High melting temperature • Need additional Be for tritium breeding • Transmutation products may cause high corrosion • Low tritium solubility means high tritium partial pressure (tritium control problem) • Limited heat removal capability, unless operating at high Re (not an issue for dual-coolant concepts) Molten Salt Blanket Concepts (One of the concepts considered by U.S. for ITER TBM) • Lithium-containing molten salts are used as the coolant fot the Molten Salt Reactor Experiment (MSRE) • Examples of molten salt are: – Flibe: (LiF)n · (BeF2) – Flinabe: (LiF-BeF2-NaF) • The melting point for flibe is high (460ºC for n = 2, 380ºC for n = 1) • Flinabe has a lower melting point (recent measurement at SNL gives about 300ºC) • Flibe has low electrical conductivity, low thermal conductivity Concepts considered by US for ITER TBM: – Dual coolant (He-cooled ferritic structures, self-cooled molten salt) – Self-cooled (only with low-melting-point molten salt) Dual Coolant Molten Salt Blanket Concepts • He-cooled First Wall and structure • Self-cooled breeding region with flibe or flinabe • No flow-channel insert needed (because of lower conductivity) Example: Dual-Cooled FLiBe + Be Blanket Concept Helium Flows Poloidal cross-section Helium Flows Self-cooled – FLiNaBe Design Concept Radial Build and Flow Schematic FLINaBe Out 2/3 FLINaBe Out 1/3 FLINaBe In Tritium Extraction from Liquid Lithium The liquid lithium exits the torus and has protium added to it. This hydrogen-swamped stream is introduced into a cooler to reduce the temperature to 200 C. This will cause a portion of LiH and LiT to precipitate from the liquid lithium. This two-phase mixture is then sent to a cold trap where the LiQ (Q represents H, D and T) is collected. This process reduces the tritium concentration in the stream to 1 ppm. Lastly, the liquid lithium and some of the LiQ is sent to a heater before being reintroduced into the torus. Periodically the cold trap will require regeneration. This can be accomplished by heating the cold trap to 600 C. At this temperature the hydrogen isotopes will exert a 10 torr partial pressure which can be pumped away and recovered. Tritium Removal and Recovery from LiPb Technique includes the following steps: • tritium permeation into the NaK-filled gap of the doublewalled heat exchanger • tritium removal from the NaK by precipitation as potassium tritide in a cold trap • tritium recovery by thermal decomposition of the tritide and pumping off the tritium gas Two cold traps are operated in parallel: one for tritium removal by circulating the tritium dissolved in the NaK to the cold trap; the other for tritium recovery. For this purpose the cold trap is decoupled from the circulation loop, drained from NaK, heated up to temperatures of about 380oC and the released tritium gas is pumped off and stored in a getter bed. Tritium Consumption and Production Fusion Consumption 55.8 kg per 1000MW fusion power per year Production & Cost • CANDU Reactors: 27 kg over 40 years, $30M/kg (current) • Fission reactors: few kg per year, $200M/kg!! (projected cost after Canadian tritium is gone) It takes tens of fission reactors to supply one fusion reactor. Conclusions • ITER’s extended phase requires tritium breeding. • Large power DT facilities must breed their own tritium. World Tritium Supply Would be Exhausted by 2025 if ITER Were to Run at 1000MW at 10% Availability (OR at 500 MW at 20% availability) Projected Ontario (OPG) Tritium Inventory (kg) 30 25 CANDU Supply 20 w/o Fusion 15 1000 MW Fusion, 10% Avail, TBR 0.0 10 ITER-FEAT (2004 start) 5 0 1995 2000 2005 2010 2015 2020 Year 2025 2030 2035 2040 2045 Tritium supply and self-sufficiency are as critical to fusion energy as demonstrating a burning plasma. They are “Go-No Go” Issues for Fusion: – There is no practical external source of tritium for fusion energy development beyond a few months of DT plasma operation in an ITER-like device. – There is NOT a single experiment yet in the fusion environment to show that the DT fusion fuel cycle is viable. • Early development of tritium breeding blanket is critical to fusion now • Testing breeding blanket modules in ITER is REQUIRED Testing in a Fusion Facility is the fastest approach to Blanket and Fusion Development to Demo A fusion test facility allows SIMULTANEOUS testing of integrated (synergistic) effects, multiple effects, and single effects - Allows understanding through single and multiple effects tests under same conditions - Provides “direct” answer for synergistic effects Specimen (thousands) 100 cm 50 cm 9 cm 2.5 cm 10.8 cm Capsule test (100’s) * Figures are not to scale. Note Dimensions Submodule (>100) Test Module (>30) • Also Test Sectors (several) ITER Provides the First Integrated Experimental Conditions for Fusion Technology Testing • Simulation of all Environmental Conditions Neutrons Plasma Particles Electromagnetics Tritium Vacuum Synergistic Effects • Correct Neutron Spectrum (heating profile) • Large Volume of Test Vehicle • Large Total Volume, Surface Area of Test Matrix But ITER Operating Parameters pose a serious challenge to obtaining meaningful blanket testing results. Careful design of ITER test blanket module (TBM) must be based on detailed engineering scaling. Testing tritium breeding blankets has always been a principal objective of ITER • “The ITER should serve as a test facility for neutronics, blanket modules, tritium production and advanced plasma technologies. The important objectives will be the extraction of high-grade heat from reactor relevant blanket modules appropriate for generation of electricity.” —The ITER Quadripartite Initiative Committee (QIC), IEA Vienna 18–19 October 1987 • “ITER should test design concepts of tritium breeding blankets relevant to a reactor. The tests foreseen in modules include the demonstration of a breeding capability that would lead to tritium self sufficiency in a reactor, the extraction of high-grade heat and electricity generation.” —SWG1, reaffirmed by ITER Council, IC-7 Records (14–15 December 1994), and stated again in forming the Test Blanket Working Group (TBWG) What is the ITER Test Blanket Module Program? • The ITER Test Program is managed by the ITER Test Blanket Working Group (TBWG) with participants from the ITER Central Team and representatives of the Parties • Breeding Blankets will be tested in ITER, starting on Day One, by inserting Test Blanket Modules (TBM) in specially designed ports • Each TBM will have its own dedicated systems for tritium recovery and processing, heat extraction, etc. Each TBM will also need new diagnostics for the nuclearelectromagnetic environment • Each ITER Party is allocated limited space for testing two TBM’s. (No. of Ports reduced to 3. Number of Parties increased to 6) • ITER’s construction plan includes specifications for TBM’s because of impacts on space, vacuum vessel, remote maintenance, ancillary equipment, safety, availability, etc. Stages of FNT Testing in Fusion Facilities Fusion “Break-in” Stage: Required Fluence 2 (MW-y/m ) Size of Test Article I ~ 0.3 SubModules • Initial exploration of performance in a fusion environment • Calibrate non-fusion tests • Effects of rapid changes in properties in early life • Initial check of codes and data • Develop experimental techniques and test instrumentation Design Concept & Performance Verification Component Engineering Development & Reliability Growth II III 1-3 >4-6 Modules Modules / Sectors • Tests for basic functions and phenomena (tritium release / recovery, etc.), interactions of materials, configurations • Verify performance beyond beginning of life and until changes in properties become small (changes are substantial 2 up to ~ 1-2 MW · y/m ) • Data on initial failure modes and effects • Narrow material combination and design concepts • Establish engineering feasibility of blankets (satisfy basic functions & performance, 10 to 20% of lifetime) • 10-20 test campaigns, each is 12 weeks • Select 2 or 3 concepts for further development • Identify failure modes and effects • Iterative design / test / fail / analyze / improve programs aimed at improving reliability and safety • Failure rate data: Develop a data base sufficient to predict mean-timebetween-failure with sufficient confidence • Obtain data to predict mean-time-toreplace (MTTR) for both planned outage and random failure • Develop a data base to predict overall availability of FNT components in DEMO D E M O FNT Requirements for Major Parameters for Testing in Fusion Facilities with Emphasis on Testing Needs to Construct DEMO Blanket - These requirements have been extensively studied over the past 20 years, and they have been agreed to internationally (FINESSE, ITER Blanket Testing Working Group, IEA-VNS, etc.) - Many Journal Papers have been published (>35) - Below is the Table from the IEA-VNS Study Paper (Fusion Technology, Vol. 29, Jan 96) Parameter a Neutron wall load (MW/m2) Plasma mode of operation Minimum COT (periods with 100% availability) (weeks) Neutron fluence at test module (MW·y/m2) Stage I: initial fusion break-in Stage II: concept performance verification (engineering feasibility) c Stage III : component engineering development and reliability growth Total neutron fluence for test device (MW·y/m2) Total test area (m2) Total test volume (m3) Magnetic field strength (T) Value 1 to 2 b Steady State 1 to 2 0.3 1 to 3 c 4 to 6 >6 >10 >5 >4 a - Prototypical surface heat flux (exposure of first wall to plasma is critical) b - If steady state is unattainable, the alternative is long plasma burn with plasma duty cycle >80% c - Note that the fluence is not an accumulated fluence on “the same test article”; rather it is derived from testing “time” on “successive” test articles dictated by “reliability growth” requirements Key Fusion Environmental Conditions for Testing Fusion Nuclear Components Neutrons (fluence, spectrum, spatial and temporal gradients) - Radiation Effects (at relevant temperatures, stresses, loading conditions) Bulk Heating Tritium Production Activation Heat Sources (magnitude, gradient) - Bulk (from neutrons) Surface Particle Flux (energy and density, gradients) Magnetic Field (3-component with gradients) - Steady Field Time-Varying Field Mechanical Forces - Normal Off-Normal - Combined environmental loading conditions - Interactions among physical elements of components Thermal/Chemical/Mechanical/Electrical/Magnetic Interactions Synergistic Effects R&D Tasks to be Accomplished Prior to Demo 1) Plasma - Confinement/Burn - Disruption Control - Current Drive/Steady State - Edge Control 2) Plasma Support Systems - Superconducting Magnets - Fueling - Heating 3) Fusion Nuclear Technology Components and Materials [Blanket, First Wall, High Performance Divertors, rf Launchers] - Materials combination selection and configuration optimization - Performance verification and concept validation - Show that the fuel cycle can be closed (tritium self-sufficiency) - Failure modes and effects - Remote maintenance demonstration - Reliability growth - Component lifetime 4) Systems Integration Where Will These Tasks be Done?! • Burning Plasma Facility (ITER) and other plasma devices will address 1, 2, & much of 4 • Fusion Nuclear Technology (FNT) components and materials require dedicated fusion facility(ies) parallel to ITER (prior to DEMO) in addition to TBM testing in ITER. Summary of Critical R&D Issues for Fusion Nuclear Technology 1. D-T fuel cycle tritium self-sufficiency in a practical system depends on many physics and engineering parameters / details: e.g. fractional burn-up in plasma, tritium inventories, FW thickness, penetrations, passive coils, etc. 2. Tritium extraction and inventory in the solid/liquid breeders under actual operating conditions 3. Thermomechanical loadings and response of blanket and PFC components under normal and off-normal operation 4. Materials interactions and compatibility 5. Identification and characterization of failure modes, effects, and rates in blankets and PFC’s 6. Engineering feasibility and reliability of electric (MHD) insulators and tritium permeation barriers under thermal / mechanical / electrical / magnetic / nuclear loadings with high temperature and stress gradients 7. Tritium permeation, control and inventory in blanket and PFC 8. Lifetime of blanket, PFC, and other FNT components 9. Remote maintenance with acceptable machine shutdown time. Excellent opportunities exist for collaboration between US and Korea on fusion engineering • US has extensive experience in fusion blanket systems developed over 30 years • US has focused blanket R&D on key areas of blanket feasibility • Korea has strong background in fission and now fusion technology systems • Korea has strong industrial and manufacturing capabilities • Collaboration possibilities are numerous, especially on development and deployment of ITER TBMs of joint interest. Possibilities for US-Korea Collaboration on Helium-Cooled Ceramic Breeder Blankets • Development and characterisation of ceramic breeder and beryllium pebbles • Thermo-mechanics of pebble beds • Tritium release characteristics of ceramic breeders and beryllium • Beryllium behaviour under irradiation • Helium cooling technology • Prototypical mock-up testing in out-of-pile facility • In-pile testing of sub-modules • Development of instrumentation Utilization of Fission Reactors for Assessing Blanket Feasibility Issues (examples) Pebble bed assemblies for thermomechanical experiments at HFR in Petten Tritium release experiments in JMTR Feature: a stepping motor used in a fission capsule test to 50 cm Module 1 Li4SiO4 T= 650 oC simulate ITER pulsed operations f60 Stepping motor Hollow cylinder for neutron absorber(Hf) Li2TiO3 f65 pebbles f20 Aluminium(Al) Hollowcylinder (Hf) Fixedneutron absorber (Hf) Windowangle B C AandCsections 65 65 65 260 A Windowof Hf neutronabsorber Core f65 Opencondition Submodule Module 3 Li2TiO3 T= 650 oC B section A : Cross section A B : Cross section B C : Cross section C : Hot junction point of multi-paired thermocouple : Self powered neutron detector (SPND) Core 10.8 cm Module 2 Li4SiO4 T= 850 oC Closecondition Module 4 Li2TiO3 T= 850 oC Possibilities for US-Korea Collaboration on Liquid Metal* Breeder Blankets • Fabrication techniques for SiC Inserts • MHD and thermalhydraulic experiments on SiC flow channel inserts with Pb-Li alloy • Pb-Li and Helium loop technology and out-ofpile test facilities • MHD-Computational Fluid Dynamics simulation • Tritium permeation barriers • Corrosion experiments • Test modules design, fabrication with RAFS, preliminary testing • Instrumentation for nuclear environment *Similar possibilities exist also for molten-salt blankets