William C. Ehler, P.G., Project Manager Office of Surface Mining Appalachian Region, Federal Reclamation Program Pittsburgh, Pennsylvania 15220
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William C. Ehler, P.G., Project Manager Office of Surface Mining Appalachian Region, Federal Reclamation Program Pittsburgh, Pennsylvania 15220 “Blackdamp” Usually associated with communication of shallow abandoned mine atmosphere with surface structures via old shafts & entries 12 – 15 % CO2 in abandoned mine atmosphere CO2 & Methane are natural products of coal % CO2 in Air Increase in Respiration 0.03 ....................................... Normal Air & Respiration 0.05 ....................................... Slight Increase 0.5 ....................................... TLV-TWA (8-hr max by law) 2.0 ....................................... 50% more Respiration 3.0 ....................................... 100% more Respiration TLV-STEL (max by law) 5.0 ....................................... 300%, Laborious Breathing 10.0 ....................................... Cannot be endured, unconsciousness Concentrations over 0.5% CO2 produce relative decrease in O2. O2 - Percent Effect 21% ..........................Normal Breathing 19.5% .......................Minimum Required by Law 17% ..........................Breathing Becomes Faster & Deeper 16% ..........................Pilot Light Extinguishes 16-13% .....................Dizziness, Rapid Pulse, Headache, etc. 9% ............................Unconsciousness 6% ............................Convulsions and Death Data Set 1 Hudson Mine Gas Complaint Carbon Dioxide 5 4 Data Set 2 Data Set 1 Data Set 3 CO2 Peak 15.1% Average 5.5% over 18 hours 3.0% TLV-STEL % 3 2 1 0.5% TLV-TWA (action level) 0 Date Modifications to Hot Water Heater by Home Owner to address Blackdamp Problems Base of Tank Raised off of the Floor Fresh Air Inlet Box Fan to Exhaust Air Low barometer High CO2 Low O2 Isotopic ranges of natural gases are large in range, specific, predictable, and capable of providing diagnostic information on their source. Differences in isotopic mass lead to subtle but significant differences in the behavior of an element during natural processes (fractionation) 13CO2 = Rsample – Rstandard * 1000 (permil) Sample Brush Creek Shale Kanawha Black Flint Lower Kittanning Underclay Houchins Creek Shale Middle Kittanning Sandstone Wadesville Sandstone Valentine Limestone Coal Refuse (From processing Kittanning seams) Redstone Limestone State (Stratigraphy) Pennsylvania (Conemaugh) West Virginia (Kanawha) Pennsylvania (Allegheny) Indiana (Carbondale) Pennsylvania (Allegheny) Pennsylvania (Anthracite region) Pennsylvania Neutralization Potential (tons/1000 tons) % Sulfur 96.9 0.59 16.9 0.31 12.6 0.91 43.6 5.15 17.7 0.04 261 0.01 902 0.01 Pennsylvania (Allegheny) 0.9 1.68 West Virginia (Monongahela) 467 0.38 Bailey residence, Volant, Lawrence County 2006 CO2 ambient levels up to 3.0% measured inside the home Home was built on about 110 feet of mine spoil from a large surface mine operation of the Brookville and Kittanning seams of the Potsville Fm. Carbonate source identified as glacial till and the spoil augmented with scrubber sludge Bailey site Older project sites Un-mined land Bailey Property Cost: $23,000 Construction Period: 15 Days Power: 350watts & Long-term Maintenance Noise & Temperature differential in basement Reduce CO2 to 0.08% except very low Barometer Popson residence, Fairchance, Fayette County 2006 CO2 ambient levels up to 6.3%, exceeded 25% in foundation cracks The full basement, no windows and partially finished. Mine 40-60 deep in Redstone Coal, Spoil associated with a massive Limestone seam. Vents SSPP inlet location & restored floor Air inlets for SSPP & Air Exchanger Cost: $27,000 Construction Period: 20 Days Problems with working around the partially finished basement Mine abandoned in interim period, almost did not qualify for AML funds. Problem may be area wide. Hudson residence, Velpen, Pike County 2008 O2 levels depressed as low as 12% inside the home CO2 levels more than 25% measured in cracks and holes in the foundation around the home Resulted in death of two family cats Low barometric pressure and heavy rains Hudson Property Monitoring shows less severe in the summer Modifications or replacement of the basement floor would be required for mitigation. Sealing of the block walls would require replacing much of the basement already finished and or deep excavation around the perimeter of the home. USGS has been acquired by the INDNR to help study and recommend solutions. Problems are more extensive Mostly recently abandoned surface mines Must have carbonate materials and other conditions to harbor the CO2. Property owners, developers and local agencies are unaware of the problem. Sub-Slab Positive Pressure systems, Sealing foundation Foundation ventilation, French Drains may be required Air Exchangers may be required on worse case situations. Trenching and drainage around property Land Use / Building Code Mine regulation How does topography and compaction of the mine play to the problem? Do we need to reconsider augmentation of the mine spoil to neutralize AMD? Should we continue to burden the homeowner with mitigation systems? Regulation Changes? Is the problem hiding in your state?