Environmental Monitoring and Assessment Standing Committee (EM&A) Chemicals Management Forum San Antonio, Texas May 15-16, 2012 Commission for Environmental Cooperation.
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Environmental Monitoring and Assessment Standing Committee (EM&A) Chemicals Management Forum San Antonio, Texas May 15-16, 2012 Commission for Environmental Cooperation Background • 1999: North American Regional Action Plan (NARAP) on Environmental Monitoring and Assessment (EM&A) in support of the SMOC initiative that, among other things, promotes collaboration in acquiring environmental data and information to assess exposure to substances of concern and the risks they pose to human health and the environment • 2008: Develop and implement a sustainable regional approach to environmental and human biomonitoring and assessment to enhance North American monitoring capacity, with an early emphasis on supporting Mexico in the initial stages of implementation of its National Environmental Monitoring and Assessment Program (Programa Nacional de Monitoreo y Evaluación Ambiental—Proname) • 2010: The EMA SC supports the Sound Management of Chemicals Working Group in “…continental management of chemicals of concern.” 2 What it does • Serve as a trinational forum for promoting cooperation and sharing knowledge in monitoring and assessing persistent toxic substances in the North American environment • Work to improve the comparability, quality, relevance and availability of environmental information on the status, trends of persistent toxic substances • Direct beneficiaries are governments, academics and private laboratories in Mexico 3 Objectives and Goals of EM&A • Assist the Parties in increasing the comparability, reliability, relevance and availability of data and information on chemicals • Seek to improve the information needed to identify and assess trends and concerns related to contaminants and stressors that affect the environment and human health • In order to ensure an integrated North American data set, place continued emphasis on supporting Mexico’s monitoring and evaluation program (Programa Nacional de Monitoreo y Evaluación Ambiental— Proname) 4 Highlights of EM&A Work 1. Comparability/Reliability of Data • • • • • Training: e.g., POPs in environmental matrices Workshops: e.g., Chemical data analysis, modelling atmospheric fate and transport Intercalibration exercises: e.g., Atmospheric chemistry Lab validation exercises: e.g., Developed guidelines for interlaboratory validation Guidance documents: e.g., Biomonitoring initiatives 5 Highlights of EM&A Work (cont’d) 2. Information for assessing trends and concerns – – – Trinational blood biomonitoring project Compendium of trinational monitoring initiatives Supporting SMOC initiatives, including gathering information on: – – – – – PCBs Lindane DDT Mercury Dioxins and Furans 3. Mexico’s monitoring and evaluation program (Programa Nacional de Monitoreo y Evaluación Ambiental—Proname) 6 North American Trilateral Maternal Blood Study The purpose of this sampling was to obtain an initial profile of levels of persistent organic pollutants (POPs) and metals in pregnant women from Canada, Mexico and the United States. SAMPLING SITES Results: •As expected, mothers from Mexico had higher concentrations of p,p’-DDT and p,p’-DDE due to its more recent use in Mexico. Lower concentrations of PCBs were seen in Mexican mothers compared to those in Canada and the United States. •In Mexico, it was found that mothers of Coatzacoalcos, a center of the Mexican petrochemical industry, had the highest concentration of several POPs (p,p´-DDE p,p´DDT, PCDDs) •Merida, an urban area without major sources of contaminant exposure, had higher concentrations of several PCB congeners Conclusion This study provides an indication of the concentrations of POPs/metals in pregnant women in North America and Mexico, plus the need for an ongoing surveillance program among vulnerable populations to pinpoint sources of higher exposure. 7 Wet Deposition of Hg in North America (2003) First subcontinental Mercury Monitoring Network for the three countries: Canada, Mexico and the USA . 8 PART 2 Proname National PBT Environmental Monitoring and Assessment Program General Objective • Reduce and/or eliminate persistent bioaccumulative and toxic substances in Mexican ecosystems, through a long-term (more than 25 years) national environmental-biological monitoring program that contributes to ecosystem and human health. 10 Proname Sites in Operation 2009 2010 Cd Juárez 2012 Future sites Valle del Yaqui Mapimí Monterrey Sinaloa Zacatecas Huasteca Potosina Salamanca Manantlá n Valle de Bravo Celestún Coatzacalcos Pochutla Lacandon jungle 11 Substances and Environmental Compartments (Proname) Environmental media & components Persistent bioaccumulative toxic substances (PBTs) soil sediment water air biota Humans 2009 to date 10 initial POPs (organochlorine pesticides) Metals (Hg, Cd and Pb, among others) Polyaromatic hydrocarbons PCBs 2011-2012 12 initial POPs (organochlorine pesticides) Metals (Hg, Cd and Pb, among others) Polyaromatic hydrocarbons PCBs + 10 new POPs (selection) Implementation of biomonitoring program (2012) Institutional strategy to begin biomonitoring program - To be defined 12 Presence of Persistent Bioaccumulative Toxic Substances at Proname Sites, in Different Environmental Media & Components Valle del Yaqui, Son. WATER 2009 2010 BIOTA (Animal) 2011 2009 2010 2011 BIOTA (Plant) 2009 2010 2011 SOIL 2009 2010 SEDIMENT 2011 2009 2010 2011 Metals PAH PCB POP R.B. Ría Celestún, Yuc. WATER 2009 2010 BIOTA (Animal) 2011 2009 2010 BIOTA (Plant) 2011 2009 2010 SOIL 2011 2009 2010 SEDIMENT 2011 2009 2010 2011 Metals PAH PCB POP Coatzacoalcos, Ver.. Starting in 2012 R.B. Sierra de Manatlán, Jal. WATER 2010 BIOTA (Animal) 2011 2010 2011 BIOTA (Plant) 2010 2011 SOIL 2010 Valle de Bravo, Edo de Mex. SEDIMENT 2011 2010 2011 Metals PAH WATER PCB 2010 POP Metals PAH No sampling PCB POP BIOTA (Animal) 2011 2010 2011 BIOTA (Plant) 2010 2011 SOIL 2010 SEDIMENT 2011 2010 2011 Metals PRONAME ------- 6.6 mg/kg inorganic mercury Farm soil Canadian Soil Quality Guidelines for the Protection of Environmental and Human Health 25000 20000 15000 mg/kg 10000 5000 0 CELESTÚN 2009 CELESTÚN 2010 CELESTÚN 2011 MERCURIO (suelo) MANATLÁN MANATLÁN 2010 PLOMO (suelo) 2011 V-YAQUI 2010 V-YAQUI 2011 MERCURIO (sedimento) V-BRAVO 2010 V-BRAVO 2011 PLOMO (sedimento) 14 Organochlorine Pesticides PRONAME 0.7 mg/kg Total DDT Farm soil Canadian Soil Quality Guidelines for the Protection of Environmental and Human Health 35 30 25 15 10 5 V-YAQUI 2010 2011 2010 V-BRAVO 2011 V-BRAVO 2010 V-YAQUI CELESTÚN 2011 MANATLÁN 2010 MANATLÁN 2009 CELESTÚN 0 CELESTÚN mg/kg 20 2011 4,4'-DDE (agua) 4,4'-DDT (agua) 4,4'-DDE (músculo) 4,4'-DDT (músculo) 4,4'-DDE (hígado) 4,4'-DDT (hígado) 4,4'-DDE (B-vegetal) 4,4'-DDT (B-vegetal) 4,4'-DDE (suelo) 4,4'-DDT (suelo) 4,4'-DDE (sedimento) 4,4'-DDT (sedimento) 15 Polycyclic Aromatic Hydrocarbons PRONAME 101,500 140,000 85,000,000 80,000,000 ------- 0.1 mg/kg Naphthalene Farm soil Canadian Soil Quality Guidelines for the Protection of Environmental and Human Health 16 Polychlorinated Biphenyls PRONAME ------- 0.5 mg/kg PCBs Farm soil Canadian Soil Quality Guidelines for the Protection of Environmental and Human Health 80000 70000 ng/kg 60000 50000 40000 30000 20000 10000 2010 V-YAQUI 2011 2010 V-BRAVO 2011 V-BRAVO 2010 V-YAQUI CELESTÚN 2011 MANATLÁN 2010 MANATLÁN 2009 CELESTÚN CELESTÚN 0 2011 3,4,4'-TRICLOROBIFENILO (sedimento) OTROS HOMÓLOGOS DE TRICLOROBIFENILOS (sedimento) 2,2',3,4,4',5,5'-HEPTACLOROBIFENILO (sedimento) 2,2',3,4,4',5,6'-HEPTACLOROBIFENILO (sedimento) 3,4,4'-TRICLOROBIFENILO (hígado) OTROS HOMÓLOGOS DE TRICLOROBIFENILOS (hígado) 2,2',3,4,4',5,5'-HEPTACLOROBIFENILO (hígado) 2,2',3,4,4',5,6'-HEPTACLOROBIFENILO(hígado) 17 POPs Air Monitoring Program • The POPs Air Monitoring Program is being implemented under the Proname umbrella, which in turn: – Fulfills the commitments established within the CEC EM&A working group – Supplies POP data for the Global Monitoring Plan (GMP) under the Stockholm Convention – Includes five sites: • Two form part of the Global Atmospheric Passive Sampling Network (GAPS). 18 GAPS – Global Context Global Atmospheric Passive Sampling Network 2010 sampling sites Modified: October 15, 2010 • • • ~55 sites since 2005 Monitoring (reporting to GMP) Surveillance (new priority chemicals) GAPS Network: www.ec.gc.ca/rs-mn/default.asp?lang=En&n=22D58893-1 19 Proname Sites 20 POPs Monitoring Sites in Mexico • PRONAME/GAPS sites include the first 12 Stockholm Convention POP plus some of the 10 new POP: – Ría Celestún, Yucatán, beginning April 2009 (background site) – Valle del Yaqui, Sonora, beginning April 2009 (farm site) • PRONAME sites measuring organochlorine pesticides and PCBs: – Manantlán, Jalisco, beginning July 2010 (background site) – Valle de Bravo, Mexico State, beginning April 2011 (transitional pilot site) – Coatzacoalcos, Veracruz, beginning April 2011 (industrial site) 21 Proname Microsite 22 PRONAME 23 PART 3 Next Steps for EM&A Next Steps Contribute to advancing sound management of chemicals: - Support Proname at two new sites - Continue support of research needs on specific chemicals, such as mercury deposition and dioxin monitoring - Continue support to Mexico as it develops its biomonitoring programs - Generate a report on SMOC contributions to SAICM for ICCM3 25 Challenges • Consolidate a network of analytical laboratories in Mexico • Consolidate chemical specific monitoring into overall Proname • Share methodologies to identify communities and ecosystems at risk • Interpretation and evaluation of data, including data comparison at a regional level and how best use the current data available • Increase transparency by sharing results with stakeholders 26 For additional information • CEC website: http://www.cec.org/Page.asp?PageID=924&SiteN odeID=1019 • Proname website: 27 Thank you EM&A Co-chairs: • Canada: Nicole Davidson ([email protected]) • Mexico: Ana Patricia Martínez ([email protected]) • US: Ana Corado ([email protected]) 28