Lecture #9 OUTLINE • Continuity equations • Minority carrier diffusion equations • Minority carrier diffusion length • Quasi-Fermi levels Read: Sections 3.4, 3.5

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Transcript Lecture #9 OUTLINE • Continuity equations • Minority carrier diffusion equations • Minority carrier diffusion length • Quasi-Fermi levels Read: Sections 3.4, 3.5

Lecture #9

OUTLINE • Continuity equations • Minority carrier diffusion equations • Minority carrier diffusion length • Quasi-Fermi levels Read: Sections 3.4, 3.5

Derivation of Continuity Equation

• Consider carrier-flux into/out-of an infinitesimal volume: Area

A

, volume

Adx

J

N (

x

)

J

N (

x

+

dx

) 

Adx

 

n

t

dx

  1

q

J N

(

x

)

A

J N

(

x

dx

)

A

  

n

n Adx

Spring 2007 EE130 Lecture 9, Slide 2

Continuity Equations:

J N

(

x

  

n

t dx

)  1

q

J N

(

x

) 

J N

x

(

x

)   

J N

x

( 

n x

) 

n dx

n

t

p

t

  1

q

 1

q

J N

x

(

x

) 

J P

x

(

x

)   

n

n

p

p

G L

G L

Spring 2007 EE130 Lecture 9, Slide 3

Derivation of Minority Carrier Diffusion Equation

• •

The minority carrier diffusion equations are derived from the general continuity equations, and are applicable only for minority carriers.

Simplifying assumptions:

– The electric field is small, such that

J N

q

n n

 

qD N

n

x

qD N

n

x J P

q

p p

 

qD P

p

x

qD P

p

x

in p-type material in n-type material –

n

0 and

p

0 are independent of

x

(uniform doping) – low-level injection conditions prevail Spring 2007 EE130 Lecture 9, Slide 4

• Starting with the continuity equation for electrons: 

n

t

  

n

0 

t

 1

q

J N

x

( 

n

 

x

) 1

q

  

x

n

n

G L

 

qD N

 

n

0  

x

n

    

n

n

G L

 

n

t

D N

 2 

n

x

2  

n

n

G L

Spring 2007 EE130 Lecture 9, Slide 5

Carrier Concentration Notation

The subscript “n” or “p” is used to explicitly denote n-type or p-type material, e.g.

p

n is the hole (minority-carrier) concentration in n type material

n

p is the electron (minority-carrier) concentration in n-type material •

Thus the minority carrier diffusion equations are

  

t n p

D N

 2  

x

2

n p

  

n n p

G L

Spring 2007  

p n

t

D P

 2 

p n

x

2  EE130 Lecture 9, Slide 6 

p n

p

G L

Simplifications (Special Cases)

• • •

Steady state:

 

n p

t

No diffusion current:

D

 0  

p n

t N

 2 

n p

x

2   0 0

D P

 2 

p n

x

2  0

No R-G:

n p

n

 0 

p n

p

 0 •

No light:

G L

 0 Spring 2007 EE130 Lecture 9, Slide 7

Example

Consider the special case:

– constant minority-carrier (hole) injection at

x

=0 – steady state; no light absorption for

x

>0 

p n

( 0 )  

p n

0 0 

D P

 2 

p n

x

2  

p n

p

 2 

p n

x

2  

p n D

P 

p

 

p n L

P 2

L

P is the

hole diffusion length

:

L P

D P

p

Spring 2007 EE130 Lecture 9, Slide 8

The general solution to the equation is 

p n

(

x

) 

Ae

x

/

L P

Be x

/

L P

 2 

p n

x

2  

p n L

P 2 where

A, B

are constants determined by boundary conditions: 

p n

(  )  0 

B

 0 

p n

( 0 )  

p n

0 

A

 

p n

0 Therefore, the solution is 

p n

(

x

)  

p n

0

Ae

x

/

L P

Spring 2007 EE130 Lecture 9, Slide 9

Minority Carrier Diffusion Length

• Physically,

L

P and

L

N represent the average distance that minority carriers can diffuse into a sea of majority carriers before being annihilated.

• Example:

N D

=10 16 cm -3 ;  p = 10 -6 s Spring 2007 EE130 Lecture 9, Slide 10

Quasi-Fermi Levels

• Whenever 

n =

p

 0

, np

n i 2

. However, we would like to preserve and use the relations:

n

n i e

(

E F

E i

) /

kT p

n i e

(

E i

E F

) /

kT

• These equations imply

np = n i 2

, however. The solution is to introduce two

quasi-Fermi levels F

N and

F

P such that

n F N

 

n i e

(

F N E i

 

E i

) /

kT kT

ln  

n n i

 

p F P

 

n i e

(

E i

F P

) /

kT E i

kT

ln  

p n i

  Spring 2007 EE130 Lecture 9, Slide 11

Example: Quasi-Fermi Levels

Consider a Si sample with

N

D = 10 17 cm -3 

n

= 

p

= 10 14 cm -3 .

and

What are p and n ?

What is the np product ?

Spring 2007 EE130 Lecture 9, Slide 12

Find F

N

F N

E i

and F

P

kT

ln

:

 

n n i

 

F P

E i

kT

ln  

p n i

  Spring 2007 EE130 Lecture 9, Slide 13

Summary

• The

continuity equations

are established based on conservation of carriers, and therefore are general: 

n

t

 1

q

J N

x

(

x

)  

n

n

G L

p

t

  1

q

J P

x

(

x

)  

p

p

G L

• The

minority carrier diffusion equations

are derived from the continuity equations, specifically for minority carriers under certain conditions (small

E

field, low-level injection, uniform doping profile):  

n p

t

D N

 2 

n p

x

2  

n p

n

G L

 

p n

t

D P

 2 

p n

x

2  

p n

p

G L

Spring 2007 EE130 Lecture 9, Slide 14

• The

minority carrier diffusion length

is the average distance that a minority carrier diffuses before it recombines with a majority carrier:

L N

D N

n L P

D P

p

• The

quasi-Fermi levels

can be used to describe the carrier concentrations under non-equilibrium conditions:

F N

E i

kT

ln  

n n i

 

F P

E i

kT

ln  

p n i

  Spring 2007 EE130 Lecture 9, Slide 15