Hydrogen Storage Alex Bevan Hydrogen materials Group www.hydrogen.bham.ac.uk www.hydrogen-wm-scratch.info 16th September 2009 Metallurgy and Materials, University of Birmingham Hydrogen Materials Group Dr David Book, Professor Rex Harris,
Download ReportTranscript Hydrogen Storage Alex Bevan Hydrogen materials Group www.hydrogen.bham.ac.uk www.hydrogen-wm-scratch.info 16th September 2009 Metallurgy and Materials, University of Birmingham Hydrogen Materials Group Dr David Book, Professor Rex Harris,
Slide 1
Hydrogen Storage
Alex Bevan
Hydrogen materials Group
www.hydrogen.bham.ac.uk
www.hydrogen-wm-scratch.info
16th September 2009
Slide 2
Metallurgy and Materials, University of Birmingham
Hydrogen Materials Group
Dr David Book, Professor Rex Harris, Dr John Speight, Dr Allan Walton,
Dr Vicky Mann, Dr Alex Bevan, Dan Reed, Sean Fletcher
PhD/EngD: Rob Bell, Steven Tedds, Yinghe Zhang, David Brampton,
Dr Ruixi Liu, Xiaodong Yi
MRes:
Dan Amos, Lydia Pickering, James Warren, George Simpson,
Peter Abell, Zhuo Wang
Technician: Simon Cannon
Slide 3
Slide 4
Slide 5
Hydrogen
Storage
Slide 6
Solid-state Hydrogen Storage
4 kg hydrogen
Louis Schlapbach &
Andreas Züttel,
NATURE, 414, p.353,
(2001)
6
26l
33l
57l
Mg2FeH6
LaNi5H6
H2 (liquid)
110l
H2 (200 bar)
Andreas Züttel, Switzerland, 11/2/2015
Slide 7
Hydrogen Storage Densities
Metal
hydrides
H-
Hcov
H2
Andreas Züttel, “Materials for hydrogen storage”, Materials Today, September 2003, pp.18-27
7
Andreas Züttel, Switzerland, 11/2/2015
Slide 8
Hydrogen Storage Densities
H-
H2
Hcov
Search for new
lighter materials
Andreas Züttel, “Materials for hydrogen storage”, Materials Today, September 2003, pp.18-27
8
Andreas Züttel, Switzerland, 11/2/2015
Slide 9
The Protium Project
PEM Fuel Cell
• 5 large cylinders, each containing
30 kg of metal hydride power.
• Gives about 2.5 kg of hydrogen.
• Operating pressure is < 10 bar
Batteries & Motor
Slide 10
Slide 11
Effect(s) of cycling and presence of impurity gases
(EPSRC SCRATCH project)
Burst disk/ blow out
H2 In
Buffer
Sample
Pressure Tx
Pressure Tx
Vacuum
Metal hydride store cycling system
Slide 12
Cycling of Ti0.93Zr0.05(Mn0.73V0.22Fe0.04)2
70 cycles in 100 hours (~ 4 days)
1000 cycles
would take
~60 days
(for this
alloy)
Alex Bevan, et al
Slide 13
New Metal Hydrides for Hybrid “HighPressure / Hydride” Stores
PCT curves of the Ti(1−x)VxMn
alloys at 293 K.
M. Shibuya et al.JALCOM 466 (2008) p.558
Slide 14
Ti0.5 V0.5 Mn
Ti0.5 V0.4 X0.1 Mn
Ti0.5 V0.45 X0.05 Mn
90000
Pressure (mbar)
80000
70000
60000
50000
40000
30000
20000
10000
0
0
0.2
0.4
0.6
0.8
Wt%
1
1.2
1.4
1.6
Slide 15
Other activities
Slide 16
Hydrogen flow rate (Ltrs/min)
30
25
20
15
10
5
0
0
500
1000
1500
2000
2500
Power (W)
35
100
90
80
25
70
20
60
50
15
40
10
30
20
5
10
0
0
500
1000
1500
Power (W)
2000
0
2500
Voltage (Volts)
Current (A)
30
Slide 17
Uninterruptible/ Power Supplies
Slide 18
Hydrogen reggae
26th February 2009
Slide 19
Slide 20
Thank you for your attention
www.hydrogen.bham.ac.uk
Slide 21
Research Projects & Networks
EC FP6 “Novel Efficient Solid Storage for Hydrogen” (Jan 06 - Dec 10)
(inc. Daimler, JM, Air Liquide, Max Planck, CNRS, NCSRD, EMPA, Delft,…)
EPSRC SUPERGEN “UK Sustainable Hydrogen Energy Consortium” (Apr 03 - Apr 11)
(inc. Bham-Chem, Nott-Mat, Nott-Chem, UCL, Oxford, STFC, Bath, Glasgow, Salford)
EPSRC SUPERGEN “Delivery of Sustainable Hydrogen” (Oct 08 - Oct 12)
(inc. St Andrews, Leeds, Warwick, Imperial, Cambridge, Manchester, Cardiff Uni’s)
“Polymer-based Hydrogen Storage Materials” (July 06 - July 10)
with Cardiff Uni (Neil McKeown), Manchester Uni (Peter Budd)
“Supply Chain Research Applied To Clean Hydrogen (SCRATCH)” (Apr 07 - Apr 10)
ChemEng (Kevin Kendall), Biosci (Lynne Macaskie), Econ (Richard Green), Met&Mat (David Book)
Department for Business, Enterprise and Regulatory Reform / TSB (Dec 06 - May 09)
“Hydrogen Permeable Novel Membranes” (HYPNOMEM)
AWM Science City “Hydrogen Energy Project” (April 07 - March 09)
£6.3M for equipment for Birmingham and Warwick Universities
International Energy Agency Task 22 (2002-06, 2006-10, …)
“Fundamental and applied hydrogen storage materials development”
“UK-Japan Hydrogen Storage Research Network” (Apr 07- May 09)
Workshops for Universities / National Labs in the UK & Japan
DIUS / FCO “UK/KOREA Focal Point Programme for H2 Storage” (Apr 07 - Apr 09)
Workshops for Universities in the UK & Korea
Hydrogen Storage
Alex Bevan
Hydrogen materials Group
www.hydrogen.bham.ac.uk
www.hydrogen-wm-scratch.info
16th September 2009
Slide 2
Metallurgy and Materials, University of Birmingham
Hydrogen Materials Group
Dr David Book, Professor Rex Harris, Dr John Speight, Dr Allan Walton,
Dr Vicky Mann, Dr Alex Bevan, Dan Reed, Sean Fletcher
PhD/EngD: Rob Bell, Steven Tedds, Yinghe Zhang, David Brampton,
Dr Ruixi Liu, Xiaodong Yi
MRes:
Dan Amos, Lydia Pickering, James Warren, George Simpson,
Peter Abell, Zhuo Wang
Technician: Simon Cannon
Slide 3
Slide 4
Slide 5
Hydrogen
Storage
Slide 6
Solid-state Hydrogen Storage
4 kg hydrogen
Louis Schlapbach &
Andreas Züttel,
NATURE, 414, p.353,
(2001)
6
26l
33l
57l
Mg2FeH6
LaNi5H6
H2 (liquid)
110l
H2 (200 bar)
Andreas Züttel, Switzerland, 11/2/2015
Slide 7
Hydrogen Storage Densities
Metal
hydrides
H-
Hcov
H2
Andreas Züttel, “Materials for hydrogen storage”, Materials Today, September 2003, pp.18-27
7
Andreas Züttel, Switzerland, 11/2/2015
Slide 8
Hydrogen Storage Densities
H-
H2
Hcov
Search for new
lighter materials
Andreas Züttel, “Materials for hydrogen storage”, Materials Today, September 2003, pp.18-27
8
Andreas Züttel, Switzerland, 11/2/2015
Slide 9
The Protium Project
PEM Fuel Cell
• 5 large cylinders, each containing
30 kg of metal hydride power.
• Gives about 2.5 kg of hydrogen.
• Operating pressure is < 10 bar
Batteries & Motor
Slide 10
Slide 11
Effect(s) of cycling and presence of impurity gases
(EPSRC SCRATCH project)
Burst disk/ blow out
H2 In
Buffer
Sample
Pressure Tx
Pressure Tx
Vacuum
Metal hydride store cycling system
Slide 12
Cycling of Ti0.93Zr0.05(Mn0.73V0.22Fe0.04)2
70 cycles in 100 hours (~ 4 days)
1000 cycles
would take
~60 days
(for this
alloy)
Alex Bevan, et al
Slide 13
New Metal Hydrides for Hybrid “HighPressure / Hydride” Stores
PCT curves of the Ti(1−x)VxMn
alloys at 293 K.
M. Shibuya et al.JALCOM 466 (2008) p.558
Slide 14
Ti0.5 V0.5 Mn
Ti0.5 V0.4 X0.1 Mn
Ti0.5 V0.45 X0.05 Mn
90000
Pressure (mbar)
80000
70000
60000
50000
40000
30000
20000
10000
0
0
0.2
0.4
0.6
0.8
Wt%
1
1.2
1.4
1.6
Slide 15
Other activities
Slide 16
Hydrogen flow rate (Ltrs/min)
30
25
20
15
10
5
0
0
500
1000
1500
2000
2500
Power (W)
35
100
90
80
25
70
20
60
50
15
40
10
30
20
5
10
0
0
500
1000
1500
Power (W)
2000
0
2500
Voltage (Volts)
Current (A)
30
Slide 17
Uninterruptible/ Power Supplies
Slide 18
Hydrogen reggae
26th February 2009
Slide 19
Slide 20
Thank you for your attention
www.hydrogen.bham.ac.uk
Slide 21
Research Projects & Networks
EC FP6 “Novel Efficient Solid Storage for Hydrogen” (Jan 06 - Dec 10)
(inc. Daimler, JM, Air Liquide, Max Planck, CNRS, NCSRD, EMPA, Delft,…)
EPSRC SUPERGEN “UK Sustainable Hydrogen Energy Consortium” (Apr 03 - Apr 11)
(inc. Bham-Chem, Nott-Mat, Nott-Chem, UCL, Oxford, STFC, Bath, Glasgow, Salford)
EPSRC SUPERGEN “Delivery of Sustainable Hydrogen” (Oct 08 - Oct 12)
(inc. St Andrews, Leeds, Warwick, Imperial, Cambridge, Manchester, Cardiff Uni’s)
“Polymer-based Hydrogen Storage Materials” (July 06 - July 10)
with Cardiff Uni (Neil McKeown), Manchester Uni (Peter Budd)
“Supply Chain Research Applied To Clean Hydrogen (SCRATCH)” (Apr 07 - Apr 10)
ChemEng (Kevin Kendall), Biosci (Lynne Macaskie), Econ (Richard Green), Met&Mat (David Book)
Department for Business, Enterprise and Regulatory Reform / TSB (Dec 06 - May 09)
“Hydrogen Permeable Novel Membranes” (HYPNOMEM)
AWM Science City “Hydrogen Energy Project” (April 07 - March 09)
£6.3M for equipment for Birmingham and Warwick Universities
International Energy Agency Task 22 (2002-06, 2006-10, …)
“Fundamental and applied hydrogen storage materials development”
“UK-Japan Hydrogen Storage Research Network” (Apr 07- May 09)
Workshops for Universities / National Labs in the UK & Japan
DIUS / FCO “UK/KOREA Focal Point Programme for H2 Storage” (Apr 07 - Apr 09)
Workshops for Universities in the UK & Korea