Chapter 9 chemical reaction

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Transcript Chapter 9 chemical reaction

Chemical Reactions

Chapter 9

Section 1 Forming New Substances 

chemical reaction

is a process in which one or more substances change to make one or more new substances.

 ◦ NEW SUBSTANCE chemical /physical properties that form in a chemical reaction differ from those of the original substances.

Chapter 9

Section 1 Forming New Substances  ◦ ◦ ◦ Signs OF chemical reaction color change formation of a gas or a solid the release or absorption of energy.

Precipitate-

solid that is produced as a result of a chemical reaction in solution

Chapter 9

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Chemical Reactions

Chapter 9

Section 1 Forming New Substances  ◦ ◦ SIGNALS OF they do not always guarantee that a reaction is happening.

most important sign - formation of new substances that have new properties.

chemical bond

-is a force that holds two atoms together in a molecule.

 ◦ ◦ ◦ For a chemical reaction to take place Chemical bonds MUST BREAK (in starting substance) Atoms rearrange new bonds form  make new substances

Chapter 9

Chemical Reactions

Chapter 9

Section 1 Forming New Substances  ◦ ◦ Energy breaks chemical bonds As new bonds form  energy is released  

exothermic reaction-

chemical reaction in which energy is released can give off energy in several forms

Chapter 9

Section 1 Forming New Substances   

endothermic reaction-

chemical reaction in which energy is taken in energy taken in  surroundings.

Ex: Photosynthesis is absorbed from the

Chapter 9

Section 1 Forming New Substances  ◦ Neither mass nor energy can be created or destroyed in chemical reactions. 

law of conservation of energy

(TRANSFER) states that energy cannot be created or destroyed but can change from one form to another

Chapter 9

Chemical Reactions

     The formation of water from its elements may be represented as follows: 2H 2 + O 2  2H 2 O What elements are present in water? ◦ Hydrogen and Oxygen How many atoms of each element are shown in the reactants?

◦ 4-H; 2-O How many atoms of each element are shown in the products?

4-H; 2-O

 The representation 2H 2 + O 2  2H 2 O is called a chemical equation. Why do you think that the numbers of atoms do not change?

Chapter 9

Section 2 Chemical Formulas and Equations  Chemical formulas are a simple way to describe which elements are in a chemical substance.

 Chemical equations are a concise way to write how atoms are rearranged in a chemical reaction.

 A balanced chemical equation shows the law of conservation of mass.

Chapter 9

Section 2 Chemical Formulas and Equations  ◦

chemical formula-

is a combination of chemical symbols and numbers to represent a substance.

shows how many atoms of each kind of element are present in a molecule.

Subscript-

to the right of a chemical symbol in a formula.

is a number written below and

Chapter 9

Chemical Reactions

Chapter 9

Section 2 Chemical Formulas and Equations  covalent compounds -written by using the prefixes in the names of the compounds.  ionic compounds- written by using enough of each ion so that the overall charge is 0.

Chapter 9

Chemical Reactions

Chapter 9

Section 2 Chemical Formulas and Equations 

chemical equation-

uses chemical formulas, chemical symbols, and coefficients to describe a reaction.  

Reactants

starting materials in a chemical reaction

Products

substances formed from a reaction are

Chapter 9

Section 2 Chemical Formulas and Equations  ◦ ◦ ◦ writing a chemical equation Must be balancing – total number of atoms of each element in the reactants must equal the total number of atoms of that element in the products #reactants=#products

Chapter 9

Chemical Reactions

Chapter 9

Section 2 Chemical Formulas and Equations 

law of conservation of mass

-states that mass cannot be created or destroyed in ordinary chemical and physical changes.

 This law means that the total mass of the reactants is the same as the total mass of the products.

Chapter 9

Chemical Reactions

Chapter 9

Section 2 Chemical Formulas and Equations  A

coefficient

is a number that is placed in front of a chemical symbol or formula.  Coefficients are used to balance an equation.  For an equation to be balanced, all atoms must be counted.

Chapter 9

Section 2 Chemical Formulas and Equations  To count all the atoms in an equation, multiply the subscript of each element in the formula by the formula’s coefficient.

 To balance an equation, change the coefficients—not the subscripts.

 Changing the subscripts in the formula of a compound changes the compound.

Chapter 9

Section 2 Chemical Formulas and Equations Look at the following formulas for chemical compounds, and identify the elements in each formula.

NaCl KBr C 12 H 22 O 11 NH 3 Fe(NO 3 ) 3 H 2 O 2 SiF 4 MgSO 4 What is the name and symbol of each element? How many atom of each element are present in each compound?

  A chemical equation describes what happens in a

chemical

reaction . ◦ ◦ ◦ ◦ ◦ The equation identifies reactants (starting materials) and products (resulting substance), the formulas of the participants, the phases of the participants (solid, liquid, gas), and the amount of each substance.

 ◦ ◦ Balancing a chemical equation refers to establishing the mathematical relationship between the quantity of reactants and products. quantities are expressed as grams or moles.

    3 steps to the process: Write the unbalanced equation.

◦ Chemical formulas of reactants are listed on the lefthand side of the equation. ◦ ◦ Balance the equation.

◦ ◦ ◦ Products are listed on the righthand side of the equation. Reactants and products are separated by putting an arrow between them to show the direction of the reaction. Reactions at equilibrium will have arrows facing both directions. Apply the Law of Conservation of Mass to get the same number of atoms of every element on each side of the equation. Tip: Start by balancing an element that appears in only reactant and product. one Once one element is balanced, proceed to balance another, and another, until all elements are balanced. Balance chemical formulas by placing coefficients in front of them. Do not add subscripts, because this will change the formulas. ◦ ◦ ◦ ◦ Indicate the states of matter of the reactants and products.

◦ Use (g) for gaseous substances. Use (s) for solids. Use (l) for liquids. Use (aq) for species in solution in water. Write the state of matter immediately following the formula of the substance it describes.

 Tin oxide is heated with hydrogen gas to form tin metal and water vapor. Write the balanced equation that describes this reaction.   Write the unbalanced equation.

SnO 2 + H 2 → Sn + H 2 O

  ◦ ◦ 1.Count the atoms Look at the equation and see which elements are not balanced.

there are two oxygen atoms on the lefthand side of the equation and only one on the righthand side. ◦ ◦ 2. Balance them out Correct by putting a coefficient of 2 in front of water: SnO 2 + H 2 → Sn + 2 H 2 O

   ◦ ◦ ◦ 2. Balance other elements This puts the hydrogen atoms out of balance. Now there are two hydrogen atoms on the left and four hydrogen atoms on the right. To get four hydrogen atoms on the right, add a coefficient of 2 for the hydrogen gas. Remember, coefficients are multipliers, so if we write 2 H 2 O it denotes 2x2=4 hydrogen atoms and 2x1=2 oxygen atoms.

SnO 2 + 2 H 2 → Sn + 2 H 2 O

    The equation is now balanced.

Be sure to double-check your math! Each side of the equation has 1 atom of Sn, 2 atoms of O, and 4 atoms of H. SnO 2 (s) + 2 H 2 (g) → Sn(s) + 2 H 2 O(g)

   Indicate the physical states of the reactants and products. To do this, you need to be familiar with the properties of various compounds or you need to be told what the phases are for the chemicals in the reaction. Oxides are solids, hydrogen forms a diatomic gas, tin is a solid, and the term 'water vapor' indicates that water is in the gas phase: SnO 2 (s) + 2 H 2 (g) → Sn(s) + 2 H 2 O(g) This is the balanced equation for the reaction.

    Balance equations How is the law of conservation of energy true for both endothermic/exothermic reactions?

What happens to bonds in chemical reaction?

As a solution of water and sugar dries, a crystal forms on the end of a string that is suspended in the solution. Is this an example of a chemical reaction? Explain.

   Energy is always 1)___________ in 2)___________..

Which are classified as 3)___________if energy is 4)________________ and stored in 5)____________such as in photosynthesis.

Which are classified as 6)___________ if energy is 7)____________ from 8)__________ such as in burning wood.

      

Absorbed Balanced Endothermic Photosynthesis Products Reactants Chemical bonds

     

Chemical equations Conserved Released Exothermic Five progress

         Precipitate Chemical reaction Chemical equation Chemical formula Chemical bonds Coefficient Subscript Yield sign Product      Reactants Exothermic reaction Endothermic reaction Law of conservation of energy Diatomic molecule

   ◦ ◦ ◦ ◦ ◦ ◦ Chemical reaction What is an example of one?

What happens to the bonds Chemical equations ◦ ◦ How to balance Why must be balanced Diagram Activation energy Energy absorbed Energy released Exothermic/endothermic reaction