Transcript Chemistry FIFTH EDITION by Steven S. Zumdahl University of

Chemistry
FIFTH EDITION
by Steven S. Zumdahl
University of Illinois
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1
Chemistry
FIFTH EDITION
Chapter 20
Transition Metals and Coordination Chemistry
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2
Figure 20.1
The Position of the Transition Elements on the Periodic Table
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Figure 20.2
Plots of the First (Red Dots) and Third (Blue Dots) Ionization Energies for the First-Row Transition Metals
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Figure 20.3
Atomic Radii of the 3d, 4d , and 5d Transition Series
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Figure 20.4
The Structures of the Chromium (VI) Anions
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Figure 20.5
The Ligand Arrangements for Coordination Numbers 2, 4, and 6
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Figure 20.8
Some Classes of Isomers
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Figure 20.9
NO2-
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Figure 20.10
Alloys Containing Copper
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Figure 20.11
Typical Compounds of Copper
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Figure 20.12
Unpolarized Light Consists of Waves Vibrating in Many Different Planes
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Figure 20.13
The Rotation of the Plane of Polarized Light by an Optically Active Substance
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Figure 20.15
A Human Hand Exhibits a Nonsuperimposable Mirror Image
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Figure 20.16
Isomers of I and II of
Co(en)33+ are Mirror Images
That Cannot Be
Superimposed
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Figure 20.17
The Optical Isomers of Co(en)2CI2+
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Figure 20.18
Hybrid Orbitals on Co3+
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Figure 20.19
The Hybrid Orbitals Required for
Tetrahedral, Square Planar, and Linear
Complex Ions
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Figure 20.20
An Octahedral Arrangement of Point-Charge Ligands and the Orientation of the 3d Orbitals
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Figure 20.21
The Energies of the 3d Orbitals for a Metal Ion in an Octahedral Complex
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Figure 20.23
The Visible Spectrum
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Figure 20.24
Violet Light
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Figure 20.26
The d Orbitals in a Tetrahedral Arrangement of Point Charges
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Figure 20.27
The Crystal Field Diagrams for Octahedral and Tetrahedral Complexes
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Figure 20.28
The d Energy Diagrams for Square, Planar, and
Linear Complexes
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Figure 20.29
The Heme Complex
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Figure 20.30
Chlorophyll
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Figure 20.31
Myoglobin
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Figure 20.32
Hemoglobin
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Figure 20.34
A Schematic Diagram of a Cyclone Separator
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Figure 20.35
A Schematic Representation of Zone Refining
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Figure 20.36
The Blast Furnace Used in the Production of Iron
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Figure 20.37
A Schematic Diagram of the Open Hearth Process for Steel Making
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Figure 20.38
The Basic Oxygen Process for Steelmaking
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