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1. Your friend Becky is sanitizing her pool by adding Ca(ClO)2 to the water. She wants to go swimming, but you are afraid she may have added to much Ca(ClO)2 and will die if she swims in the pool. You know that it is dangerous to swim in a pool with more than a .05 Molar concentration of ClO- in the water. If Becky’s swimming pool holds 275 gallons of water and she added 75 grams of Ca(ClO)2 to the water, calculate the molarity and find out if it is safe to swim in. (Hint: 1 gallon = 3.79 liters) 2. 150 grams of Hydrogen gas is reacted with 1500g O2 gas, to form H2O. How many grams of water will be made? 2H(g) + O2(g) =2H2O(l) 3. Balance the following equation and solve for how many grams of C02 are formed if 10 grams of CO are reacted with excess oxygen gas. CO+ 02 = CO2 4. Given the following balanced equation, how much C6H5Br will be produced when 30g C6H6 reacts with 65g of Br2? C6H5 + Br2 = C6H5Br + HBr 5. Balance the following equation and then use it to find out how many grams of NaI are needed to remove 1.3 Kg of O3? 6. O3 + NAI + H2O = O2 + I2 NaOH (Hint: 1Kg = 1000g) 6.) 2C6H12(l) + 5O2(g) = 2H2C6H8O4(l) + 2H2O(g) Use the provided balanced equation to answer the question. If the limiting reactant in this equation is C6H12 and 25g of it are used, what is the theatrical yield of H2C6H8O4? b) If after performing the experiment 33.5 g of H2C6H8O4 was made, what is the percent yield? 7.) 30g of an unknown organic compound are combusted, leaving you with 733g of CO2 and 30g of water. What is the empirical formula of the compound you just combusted? 8.) 2NaOH + CO2 +Na2CO3 + H2O When 1.85 mol of NaOH reacts with 1 mol Co2 which is the limiting reactant? b.) How many moles of the excess reactant are left? Answer key to the Stoich Study Guide. 1 275 Gallons H20 = 1045.25 L H2O 3.79 L 1 gallon 75 g Ca(ClO)2 1 mole Ca(ClO)2 141.1g Moles solute M = Liters solution 2 moles ClO 51.5g 1mole Ca(ClO)2 1 mole ClO = 51.5g 1042.25 L = = 54.748g ClO .05M 2 150g H2 1 mol H2 =75 mol H2 2.00g H2 1500g O2 1 mol O2 2 mol O 32.0g O2 1 mol 02 =94 moles O H2 is the limiting reactant 75 mol H2 2 mol H2O 2 mol H2 18.0g H2O 1 mol H2O =1400g H2O 2Co + O2 = 2CO2 3. 10g CO 4 30g C6H6 1 mole Co 2 mole CO2 28 g 2 mol CO 1 mole C6H6 65g Br2 1 mole C6H6 78g 1 mol C6H5Br 1 mole Br2 1 mole Br2 160g 1 mol C6H5Br 44g = 15.7g CO2 1 mole CO2 157g = 60.4g C6H5Br 1 mole C6H5Br 157g = 63.8g C6H5Br 1 mole C6H5Br C6H6 is the limiting reactant, 60.4g of C6H5Br is made O3 + 2NaI + H20 = O2 + I2 + 2NaOH 5 1.3 Kg O3 1000g 1Kg 1 mole O3 48g 2 mole NaI 150g 1 mole O3 1 mol NaI = 812.5g C6H5Br 6 25g C6H12 1 mol C6H12 84g 1 mol H2C6H8O4 146g H2C6H8O4 2 mol C6H12 1 mol H2C6H8O4 = 43.5g H2C6H8O4 = theoretical Yield b. actual Theoretical X 100% 33.5g 43.5 X 100% =77% percent yield. 7 733g CO2 1 mol CO2 =16.6 mol CO2 44g 30g H2O 1 mol H2O =16.6 mol H2O 18g 2 mol H 16.6 mol H2O =33.3 mol H 1 mol H2O 16.6 mol C 12g = 66.6% C 1 mole C 33.3 mol H 300 g 1g = 11.3% C 1 mole H 300 g 100- (66+11.3)= 22.1% O .221 O 66.3g O 300g =66.3g O 1 mole O =4.125 mol O 16.6g ÷ C H 16.6 33.3 4.13 4 ÷ 4.13 8 O ÷ 4.13 4.13 1 Formula is C4H8O 8 1.85 mol NaOH 1 mole H2O 1 mol NaOH 1 mol CO2 1 mole H2O 1 mol CO2 18g H2O 1mol H2O 18g H2O 1mol H2O =16.65g H2O =18g H2O NaOH is the limiting reactant. b. 16.65g H2O 1 mol H2O 1 mole CO2 18g H2O 1mol H2O 1 mole CO2 - .925 moles CO2 = =.925 moles CO2 used .075 mol excess reactant