Transcript Chapter 4.2

Chapter 4.2
Ionic Compounds
Naming/Formula Writing
Polyatomic ions
Polyatomic Ions
A polyatomic ion is a group of atoms,
usually of different elements, that
together have an overall charge.
Example:
Nitrate
NO3Sulfate
SO42Phosphate
PO43-
NOTICE:



They are part of ionic compounds
The name of a polyatomic ion
usually has the ending –ate or –ite
Polyatomic ions usually have a
negative charge except ammonium
which is NH4+
*****see the list of all of polyatomic ions*****
Naming Rules
1. Name the metal.
a) If the metal is multivalent, use a roman
numeral in brackets after the metal name to
indicate the charge of the ion.
b) If NH4 is present write its name ammonia
2. Name the non-metal
a) Write the name of the negative polyatomic
ion as it is shown on your list OR
b) Write the name of your non-metal and
change the ending to -ide
Examples – Name the following
compounds
LiOH
Mg3(PO4)2
Al2(SO3)3
NH4S
Examples – Naming compounds with
multivalent metals and polyatomic ions
Fe2(SO3)3
CuOH
You must
Mn(PO3)3
mathematically
determine the
charge on the
NiCO3
metal
Writing the formula of an Ionic
compound with a polyatomic ion
Rules
1.
Write the symbol of the metal/polyatomic ion
with its ion charge as a superscript
2.
Write the symbol of the non-metal/polyatomic
ion with its ion charge as a superscript
3.
Criss cross the charges so that they become
subscripts for the opposite element and remove
+ or – signs
4.
Use brackets around polyatomic ions if there is
more than one ion after criss crossing
5.
Simplify the subscripts if possible.
Example of formula writing
Potassium nitrate
Magnesium sulfate
Ammonium phosphite
Examples of formula writing
Copper (II) sulfite
Chromium (VI) hydroxide
Cobalt (III) permanganate
Homework
Worksheet
“Polyatomic Ions Naming and Formula
Writing”