Transcript Slide 1

Notes: 13.1 and 13.3
• OBJECTIVES: Students will be able to (SWBAT)
1. Explain how intermolecular forces affect states of matter
• QUESTIONS TO PONDER:
1. How does the kinetic molecular theory affect atoms and
molecules?
2. How are the actions of particles different between gases,
liquids and solids?
3. Which interactions or forces would most likely be found in
each type of state (gas, liquid and solid)?
4. How is viscosity and surface tension affected by IMFs?
5. How do the 4 types of solids differ in their interactions?
Gases (13.1)
• Kinetic molecular theory explains gas behavior,
especially in motion
– Kinetic energy is energy of motion
– Particles are always in motion
Properties of Gases
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Particles are spaced far apart (low density)
Particles have low attraction to each other
Have fluidity (ability to flow)
Are compressible (can be squeezed)
Have fastest and most random motion
Moving gas particles…
Compression and Expansion
EXPANSION
COMPRESSION
movable
pistons
gas
cylinders
Diffusion
- Gas particles
move to be
evenly
distributed
- Particles diffuse
because of
random motion
Heat affects motion
• Heat (energy)
increases kinetic
energy
– Warmer  particles
moving faster
– Cooler  particles
moving slower
Liquids and Solids (13.3)
• Review: 3 States of Matter
– solid, liquid and gas
Just add (or take away heat)…
Which state has the strongest intermolecular attractions?
REMOVE HEAT
States of Matter and Intermolecular
Forces (IMFs)
• Stronger the IMF  particles will be more
compacted (close together)
– Strongest  solids
• ionic bonds
• covalent network bonds
• At very low temperatures, most substances can be solids
– Liquids
• mostly polar (dipole-dipole) interactions
• Heavy, non-polar molecules
– Weakest  gases
• nonpolar molecules
• If temperature is high enough, most can be gases
Properties of Liquids
• Liquids
– Denser than gases (more compact)
– Ability to flow
Viscosity
• Resistance of a liquid to flow because of IMFs
– High viscosity  thick  flows more slowly
• Honey, syrup
– Low viscosity  more “liquidy”  flows more rapidly
• Water, many other liquids
– As temperature increases, viscosity will decrease (flows
faster)  less IMF because particles are farther apart
Surface Tension
• Surface of liquid sticking together (cohesiveness)
due to IMFs
• The reason why drops of liquid form
• molecules at or near the surface tend to contract
the surface into smallest possible area
Properties of Solids
• Solids
– Densest state (particles packed close together)
– Not very compressible (hard to squeeze further)
– Solid particles do move  they vibrate in place
Types of Solids: Crystals
• crystalline solids: particles arranged in a geometric,
3-D structure
– Ionic crystals: ions in lattice structure (salts)
– Molecular crystals: molecules in lattice structure (ice 
any molecule if cold enough)
– Metallic solids: metal atoms held together by metallic
bonds in a sea of electrons (any solid metals)
– Covalent network solids: nonmetal atoms held together
in repeating pattern by covalent bonds which are very
strong (diamonds)
Types of Solids: Crystals
• crystalline solids: particles arranged in a geometric, 3-D structure
BOND TYPE
DESCRIPTION
IONIC
Ions form lattice structure  salts
METALLIC
Metal atoms held by “sea of electrons”
COVALENT
Non-metal elements held tightly by covalent
bonds (e.g. diamonds)
BETWEEN
COVALENT
MOLECULES
Distinct (separate) molecules held together by
IMFs (dipole-dipole, London, H-bond)
INTER or
INTRA
Types of Solids: Crystals
• crystalline solids: particles arranged in a geometric, 3-D structure
BOND TYPE
DESCRIPTION
INTER or
INTRA
IONIC
Ions form lattice structure  salts
INTRA
METALLIC
Metal atoms held by “sea of electrons”
INTRA
COVALENT
Non-metal elements held tightly by covalent
bonds (e.g. diamonds)
INTRA
BETWEEN
COVALENT
MOLECULES
Distinct (separate) molecules held together by
IMFs (dipole-dipole, London, H-bond)
INTER