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Thermoelectric Analysis for Optimized Waste Heat Power Generation in Marine Applications Tucker Doane Angela Fouquette Philep Levesque Summary • • • • • • Potential benefits of thermoelectrics Objectives for this year How thermoelectric materials work Background on previously done work This year’s progress and development Future work Potential Benefits Thermoelectric Generators Applied to Marine Diesel Exhausts • Increase efficiency and plant performance • Decrease in fuel consumption • Decrease in operating costs • Decrease environmental impact Objectives • Understand the fundamental properties of thermoelectric generators • Provide the lab with devices to characterize these properties and model various applications • Model material properties of thermoelectric modules and elements • Compare heat transfer with flow rates and pressure drops for the most efficient performance values • Comparing results to industry standard tests and modules Thermoelectric Introduction Seebeck Effect: A voltage is created in the presence of a temperature difference between two dissimilar metals Z = Figure of Merit S = Seebeck Coefficient σ = Electrical Conductivity κ = Thermal Conductivity Thermoelectric Introduction Seebeck Coefficient: used to characterize the sensitivity of different materials V = Voltage T = Temperature Background •Previous work at Maine Maritime Academy focused on improvement and implementation on existing systems •R/V Friendship and Gas Micro-Turbine (2009) •Hybrid lifeboat test platform development and implementation (2010) •Improved heat exchanger development (2013) Seebeck Coefficient Measurement Apparatus (SCMA) • Device to measure temperature and voltage output of manufactured modules, elemental samples, wires, etc. • Used to understand fundamental properties of existing and newly generated materials • Testing initially done with several types of Hi-Z modules Design and Development • Copper chosen due to its excellent heat transfer characteristics • Each copper block measures 2 x 2 x 5/8 inches • Capable of accepting existing modules, new samples, wires, etc. Control Schematic 8 4 7 3.5 7 3.5 6 3 6 3 5 2.5 5 2.5 4 2 4 2 3 1.5 3 1.5 2 1 2 1 1 0.5 1 0.5 0 0 0.2 0.4 0.6 0.8 1 1.2 1.4 Current (A) 1.6 1.8 0 0 0 2 0.2 0.6 0.8 1 1.2 1.4 1.6 Current (A) Delta T = 300 deg F Delta T = 200 deg F 4 8 4 7 3.5 7 3.5 6 3 6 3 5 2.5 5 2.5 4 2 4 2 3 1.5 3 1.5 2 1 2 1 1 0.5 1 0.5 0 0 0 0 0.2 0.4 0.6 0.8 Current (A) 1 1.2 1.4 1.6 Voltage (V) 8 Power (W) Voltage (V) 0.4 0 0 0.2 0.4 0.6 0.8 Current (A) 1 1.2 1.4 1.6 Power (W) 0 Voltage (V) 4 Power (W) Voltage (V) 8 Power (W) Delta T = 400 deg F Delta T = 500 deg F Max Power vs Temperature Differential 3.5 3 Power (W) 2.5 2 1.5 1 0.5 0 0 100 200 300 Temperature Differential (deg F) 400 500 SCMA Uses and Future Work • Can be used to test and characterize newly made samples and materials, as well as other unknown devices •Stabilize temperature differential: •Automate temperature control •Establish a better way of cooling Test Bed Development • Provide the ability to test different modules, materials, and scenarios in a controlled and designated environment • Designed to accept newly made thermoelectric devices • Will be designed to utilize gas as the heating medium • Will have an associated cooling system to promote a greater temperature differential System Overview Heat Sink Heat Engine (Heat Source) Exhaust Heat Recovery Device TEG Modules To Atmosphere Heat Exchanger Design Mass flow Heat Exchanger Slot Height Pdrop Boundary Layer Convective Coefficient • Designed to replicate existing marine applications Re, Pr, Nu Temp in Qtransfer • Heat provided to simulate pressure and air flow through the exhaust of a diesel engine, boiler, or gas turbine Preliminary Design • The test bed needs to have the largest possible range of fluid flow characteristics to better simulate a number of known exhaust systems • Initial calculations and visualization done in Microsoft Excel • The basic parameters of flow and temperature were sized based on Hatz Single Cylinder Diesel to Caterpillar 2.2 L Basic Flow and Heat Modeling CAT 2.2 Calculated specs (Normal Operating Range/ Naturally Aspirated) RPM Liters(Disp) m^3 Density (STP) (kg/m^3) m^3/min 2200 2.2 0.0022 1.169 2.42 2300 2.2 0.0022 1.169 2.53 2400 2.2 0.0022 1.169 2.64 2500 2.2 0.0022 1.169 2.75 2600 2.2 0.0022 1.169 2.86 2700 2.2 0.0022 1.169 2.97 2800 2.2 0.0022 1.169 3.08 2900 2.2 0.0022 1.169 3.19 3000 2.2 0.0022 1.169 3.30 Hatz Diesel (Single Cylinder 1B50 , 3.5-8 kW, 10HP) RPM Liters(Disp) m^3 Density (STP) (kg/m^3) m^3/min 1000 0.517 0.000517 1.169 0.259 1200 0.517 0.000517 1.169 0.310 1400 0.517 0.000517 1.169 0.362 1600 0.517 0.000517 1.169 0.414 1800 0.517 0.000517 1.169 0.465 2000 0.517 0.000517 1.169 0.517 2200 0.517 0.000517 1.169 0.569 2400 0.517 0.000517 1.169 0.620 2600 0.517 0.000517 1.169 0.672 2800 0.517 0.000517 1.169 0.724 3000 0.517 0.000517 1.169 0.776 CFM 85.46 89.34 93.23 97.11 101.00 104.88 108.77 112.65 116.54 m^3/s 0.040 0.042 0.044 0.046 0.048 0.050 0.051 0.053 0.055 kg/min 2.83 2.96 3.09 3.21 3.34 3.47 3.60 3.73 3.86 kg/sec 0.047 0.049 0.051 0.054 0.056 0.058 0.060 0.062 0.064 CFM 9.129 10.955 12.780 14.606 16.432 18.258 20.083 21.909 23.735 25.561 27.387 m^3/s 0.004 0.005 0.006 0.007 0.008 0.009 0.009 0.010 0.011 0.012 0.013 kg/min 0.302 0.363 0.423 0.483 0.544 0.604 0.665 0.725 0.786 0.846 0.907 kg/sec 0.005 0.006 0.007 0.008 0.009 0.010 0.011 0.012 0.013 0.014 0.015 RESULTS Min Flow Mass Flow(kg/s) 0.010 Max Flow 0.030 Temp (Celsius) 250 500 250 500 Power (kW) 2.33 5.21 6.99 15.62 Heat Load Requirements Enthalpy Rate Equation 𝑄 = 𝑚𝐶𝑝 (𝑇𝑖𝑛 − 𝑇𝑎𝑚𝑏) Heat Exchanger Fluid Flow Analysis • How varying flow area, temperature, and length effect velocity and flow regime (turbulent vs laminar) for simple rectangular slot • Turbulent preferred for fluid mixing Heat Exchanger Basic Arrangement Restriction Plate Air Flow Air Flow Heat Transfer Area Cooling Water Cooling Plate Cooling Water Advanced Modeling using MATLAB • To understand the tradeoff of pressure to convective heat transfer, in addition to other effects • An attempt to predict the conditions within the designed heat exchanger during operation and testing Illustrating the Tradeoff Important Dimensionless Groups • Reynolds Number ▫ Ratio of flow momentum rate to viscous force 𝜌∗𝜗∗𝐷 𝑅𝑒 = 𝜂 • Nusselt Number (Pr,Re) ▫ Ratio of convective conductance to molecular conductance over hydraulic diameter 𝑁𝑢 = ℎ 𝑘 𝐷 Important Non-typical Equations & Estimators • Prandtl Number ▫ 𝑃𝑟 = 𝜂∗𝐶𝑝 𝑘 • Nusselt Number ▫ NuL = 0.664*Pr^(1/3)*Re^0.8 ▫ NuT = 0.036*Pr^(1/3)*Re^0.8 • Fluid Boundary Layer ▫ ▫ 5∗𝑥 𝐵𝐿𝐿 = 𝑅𝑒𝐿 0.5 0.16∗𝑥 BLT = 𝑅𝑒𝐿1/7 MATLAB Model INPUTS Tin, Mdot, Hs, Ws, L 𝑓 ,Pdrop Ө ,Cp,SW, η ρ Each element generates an array based upon the input parameters. 𝑄 Pr NuL (Pr,Re) NuT (Pr,Re) Area, P, HR, D h Vel Rt, Qtransfer Re, ReL BLL (ReL) BLT (ReL) Heating System Electric Heat Watlow Finned Strip Heaters 1kW Centrifugal Blower Fossil Fuel Heater Metro Services Ratiomatic 147 kW Metro Services Thermair Burner 44 kW Final Design Sizing Restriction & Cooling Plate Instrumentation Construction • Future Work • Complete construction of heat exchanger • Order or build Heating System • Utilize the R/V Quickwater Acknowledgments • • • • • • • • • Travis Wallace Richard Kimball Paul Wlodkowski Lynn Darnell Joshua Henry Timothy Allen Alan Trundy Stephen Collins James Stefanski Questions