Transcript Nuclear Chemistry - Celina City Schools Home

Nuclear Chemistry
Chapter 23
n/p too large
beta decay
X
Y
n/p too small
positron decay or electron capture
Nuclear Stability
•
Certain numbers of neutrons and protons are extra stable
•
n or p = 2, 8, 20, 50, 82 and 126
•
Like extra stable numbers of electrons in noble gases
(e- = 2, 10, 18, 36, 54 and 86)
•
Nuclei with even numbers of both protons and neutrons
are more stable than those with odd numbers of neutron
and protons
•
All isotopes of the elements with atomic numbers higher
than 83 are radioactive
•
All isotopes of Tc and Pm are radioactive
Atomic number (Z) = number of protons in nucleus (element symbols)
= charge (particles)
Mass number (A) = number of protons + number of neutrons
= atomic number (Z) + number of neutrons
Mass Number
A
ZX
Atomic Number
Element Symbol
proton
1p
1H
or
1
1
neutron
1n
0
electron
0b
0e
or
-1
-1
positron
0b
0e
or
+1
+1
a particle
4He
4a
or
2
2
A
1
1
0
0
4
Z
1
0
-1
+1
2
Other relevant particles of interest:
 Gamma photon
0
0
 neutrino
0
0
0
0

Anti-neutrino
Balancing Nuclear Equations
1. Conserve mass number (A).
The sum of protons plus neutrons in the products must equal
the sum of protons plus neutrons in the reactants.
235
92 U
+ 10n
138
55 Cs
+
96
37 Rb
+ 2 10n
235 + 1 = 138 + 96 + 2x1
2. Conserve atomic number (Z) or nuclear charge.
The sum of nuclear charges in the products must equal the
sum of nuclear charges in the reactants.
235
92 U
+ 10n
138
55 Cs
+
96
37 Rb
92 + 0 = 55 + 37 + 2x0
+ 2 10n
212Po
decays by alpha emission. Write the balanced
nuclear equation for the decay of 212Po.
4
alpha particle - 42He or 2a
212Po
84
4He
2
+ AZX
212 = 4 + A
A = 208
84 = 2 + Z
Z = 82
212Po
84
4He
2
+ 208
82Pb
?
Nuclear Stability and Radioactive Decay
Beta decay
+-10b + 
14C
6
14N
7
40K
19
40Ca
20
Decrease # of neutrons by 1
+ -10b + 
1n
0
Increase # of protons by 1
1p
1
+ -10b + 
Positron decay
++10b + 
Increase # of neutrons by 1
++10b + 
Decrease # of protons by 1
11C
6
11B
5
38
19K
38Ar
18
1p
1
1n
0
++10b + 
 and  have A = 0 and Z = 0
Nuclear Stability and Radioactive Decay
Electron capture decay
+
37Ar
18
+ -10e
37Cl
17
55Fe
26
+ -10e
55Mn
25
1p
1
Increase # of neutrons by 1
+
Decrease # of protons by 1
+ -10e
1n
0
+
Alpha decay
212Po
84
4He
2
+ 208
82Pb
Spontaneous fission
252Cf
98
1n
2125
In
+
2
49
0
Decrease # of neutrons by 2
Decrease # of protons by 2
Nuclear binding energy (BE) is the energy required to break
up a nucleus into its component protons and neutrons.
BE + 199F
911p + 1010n
E = mc2
BE = 9 x (p mass) + 10 x (n mass) – 19F mass
BE (amu) = 9 x 1.007825 + 10 x 1.008665 – 18.9984
BE = 0.1587 amu
1 amu = 1.49 x 10-10 J
BE = 2.37 x 10-11J
binding energy
binding energy per nucleon =
number of nucleons
2.37 x 10-11 J
= 1.25 x 10-12 J
=
19 nucleons
Nuclear binding energy per nucleon vs Mass number
nuclear binding energy
nucleon
nuclear stability
Kinetics of Radioactive Decay
N
daughter
DN
rate = Dt
rate = lN
DN
= lN
Dt
N = the number of atoms at time t
N0 = the number of atoms at time t = 0
l is the decay constant
First Order Equations:
N
ln  t
 N0

   lt

ln 2
l
t1
2
Nt  N0 e( lt )
ln  Nt   ln  No   lt
0.693
or l 
t1
2
or t 1 
2
0.693
l
Kinetics of Radioactive Decay
ln[N] = ln[N]0 - lt
ln [N]
[N]
[N] = [N]0exp(-lt)
Radiocarbon Dating
14N
7
+ 01n
14C
6
14C
6
14N
7
+ 11H
+ -10b + 
t½ = 5730 years
Uranium-238 Dating
238U
92
206Pb
82
+ 8 24a + 6-10b
t½ = 4.51 x 109 years
Nuclear Transmutation
14N
7
27Al
13
14N
7
Cyclotron Particle Accelerator
+ 24a
+ 24a
+ 11p
17O
8
+ 11p
30P
15
+ 01n
11C
6
+ 42a
Nuclear Transmutation
110
111
112
1940
1940
1944
1944
1949
1950
1952
1952
1955
1956
1961
1966
1970
1984
1981
1984
1982
1994
1994
2002
Darmstadtium
Roentgenium
Copernicium
Ds
Rg
Cn
62
269
Pb  28
Ni  110
Ds  01n
64
272
Bi  28
Ni  111
Rg  01n
208
70
278
277
1
82 Pb  30 Zn  112 Cn  112 Cn  0 n
208
82
209
83
Nuclear Fission
235U
92
+ 01n
90Sr
38
1n + Energy
+ 143
Xe
+
3
0
54
Energy = [mass 235U + mass n – (mass 90Sr + mass 143Xe + 3 x mass n )] x c2
Energy = 3.3 x 10-11J per 235U
= 2.0 x 1013 J per mole 235U
Combustion of 1 ton of coal = 5 x 107 J
Nuclear Fission
Representative fission reaction
235U
92
+ 01n
90Sr
38
1n + Energy
+ 143
Xe
+
3
0
54
Nuclear Fission
Nuclear chain reaction is a self-sustaining sequence of
nuclear fission reactions.
The minimum mass of fissionable material required to
generate a self-sustaining nuclear chain reaction is the
critical mass.
Non-critical
Critical
Schematic Diagram of a Nuclear Reactor
Nuclear Fission
Annual Waste Production
35,000 tons SO2
4.5 x 106 tons CO2
3.5 x 106
ft3 ash
1,000 MW coal-fired
power plant
70 ft3
vitrified
waste
1,000 MW nuclear
power plant
Nuclear Fission
Hazards of the
radioactivities in spent
fuel compared to
uranium ore
From “Science, Society and America’s Nuclear Waste,” DOE/RW-0361 TG
Chemistry In Action: Nature’s Own Fission Reactor
Natural Uranium
0.7202 % U-235 99.2798% U-238
Measured at Oklo
0.7171 % U-235
Nuclear Fusion
Fusion Reaction
2
2
3
1
1 H + 1H
1 H + 1H
2H
1
+ 13H
6Li
3
+ 12H
4He
2
2
+ 10n
4He
2
Tokamak magnetic
plasma
confinement
Energy Released
6.3 x 10-13 J
2.8 x 10-12 J
3.6 x 10-12 J
Radioisotopes in Medicine
•
1 out of every 3 hospital patients will undergo a nuclear
medicine procedure
•
24Na,
•
131I,
t½ = 14.8 hr, b emitter, thyroid gland activity
•
123I,
t½ = 13.3 hr, ray emitter, brain imaging
•
18F,
t½ = 1.8 hr, b emitter, positron emission tomography
•
99mTc,
t½ = 14.8 hr, b emitter, blood-flow tracer
t½ = 6 hr, ray emitter, imaging agent
Brain images
with 123I-labeled
compound
Radioisotopes in Medicine
Research production of 99Mo
98Mo
42
+ 10n
99Mo
42
Commercial production of 99Mo
235U
92
99Mo
42
99mTc
43
+ 10n
99Mo
42
99mTc
43
99Tc
43
+ other fission products
+ -10b + 
+ -ray
t½ = 66 hours
t½ = 6 hours
Bone Scan with
99mTc
Geiger-Müller Counter
Biological Effects of Radiation
Radiation absorbed dose (rad)
1 rad = 1 x 10-5 J/g of material
Roentgen equivalent for man (rem)
1 rem = 1 rad x Q
Quality Factor
-ray = 1
b=1
a = 20
Chemistry In Action: Food Irradiation
Dosage
Effect
Up to 100 kilorad
Inhibits sprouting of potatoes, onions, garlics.
Inactivates trichinae in pork. Kills or prevents insects
from reproducing in grains, fruits, and vegetables.
100 – 1000 kilorads
Delays spoilage of meat poultry and fish. Reduces
salmonella. Extends shelf life of some fruit.
1000 to 10,000 kilorads
Sterilizes meat, poultry and fish. Kills insects and
microorganisms in spices and seasoning.