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ACADEMIC INSTITUTIONAL PROGRAM OF NANOTECHNOLOGY **** PRINATEC Coordinator: Dr. Daniel Glossman-Mitnik Main research centers in México with activities in Nanoscience and/or Nanotechnology UNISON CIMAV UANL CIQA CINVESTAV-QRO CINVESTAV-DF IPICYT UAM UASLP IPN CIATEC UNAM IMP BUAP PRINATEC Academic Institutional Program of Nanotechnology • • • • • In CIMAV, most of the researchers perform activities related to Nanotechnology • During 2006, more than 78% of the publications were related to Nanotechnology, and a large number is expected for 2007 •We have current research projects with the private industry related to Nanotechnology •Present infraestructure is adequate, but it needs improvements Increasing world activity To avoid to be left behind To explore potential new markets The need of specialized human personal Objective To be national leaders and to have international presence in Nanoscience and Nanotechnology • • • • • • • Interacting with prestigeous world leaders in Nanoscience and Nanotechnology Adquisition of new equipment UT (Austin) – CIMAV agreement -- CIMAV – SUNY/Albany agreement Binational Laboratories México-USA, México-Germany (Nanotechnology) Nanotechnology Consortium Strategic Program of Nanotechnology, National Laboratory of Nanotechnology, Nanotecnology National Initiative NANOMEX Academic Institutional Program of Nanotechnology • Computational Simulation of the Molecular Structure and Properties of Nanomaterials • Computational Nanotechnology (CAN) • Synthesis of Nanostructured Materials • Chemical and Physical Characterization of Nanomaterials • Industrial Applications of Nanotechnology Functional Molecular Nanomaterials Co m p o s ite P o ly m e r c h a in Synthesis and Incorporation of Quantum Dots within Polymeric Matrices via Mini-Emulsion Polymerization: Development of a New Generation of Sensores for Hydrocarbons P a rtic le P o ly m e r + Na n o c o m p o s ite P o ly m e r c h a in Na n o p a rtic le s P a rtic le Nanocomposites formed by Ag/carbon and PMMA nanoparticles LATEX PMMA LATEX Nanocomposite THEORETICAL STUDY OF TRANSFERENCE AGENTS TO BE USED FOR RAFT POLYMERIZATION, SIMULATED BY MEANS OF DFT MAGNETIC FLUIDS without a magnetic field in the presence of a magnetic field The stability of the magnetic fluid is by far superior to 2 years Metallic and Molecular Nanoclusters Production and Characterization of Composite Materials Formed by Carbon Nanotubes and Aluminium Intermetallic Compounds YCo5 Applications: Magnetic materials based on SmCo5 are used in the automobile and electronic industries as well and others. YCo5 could be an interesting alternative. ZnFe2O4 Nanoparticles Other nanoparticles • Silica • Alumina • Carbon nanotubes • Nickel oxides • Clays • Magnetic ferrites • CdSe Theoretical and Conceptual DFT Computational Nanotechnology (CAN) • Modelling and Design of Nanomaterials using Computers • Computational Characterization of the Molecular Structure of Nanomaterials • Prediction of the IR, Raman, UV-Vis and NMR Spectra of the Nanostructures • Determination of the Electric and Magnetic Properties of the Nanomaterials • Computational Simulation of the Thermochemicla Properties of the Nanomaterials in Gas Phase, Solid Phase and in Solution • Analysis of the Chemical Reactivity of the Nanomaterials • Simulation of Chemical and Physical Processes of the Nanostructures Nanomaterials for Storage and Energy Conversion Computational Simulation of the Molecular Structure and Properties of Nanomaterials for DELFOS (Dispositivos de Emisión de Luz y Fotovoltaicos Orgánicos) Organic Photovoltaic and Light-Emitting Devices CONJUGATED POLYMERS • Organic semiconductors • Good processability • Low cost OPTOELECTRONIC APPLICATIONS FULLERENES PHOTOVOLTAIC DEVICES h Al ITO eC12H25O Me N C12H25O C60-3PV ePhotocurrent e- e- Corrosion Inhibitors Pharmaceutical Drugs, Foods and Agrochemicals Computational simulation of the molecular structure and properties of antichagasic compounds linked to fullerenes Fondo Sectorial SALUD-CONACYT Computational Simulation of the Molecular Structure and Propertes of Apple Flavonoids Linked to Fullerenes and Carbon Nanotubes Computational simulation of the molecular structure and properties of steroidal precursors obtained from potato • Fondo Sectorial SAGARPA • Computational Simulation of the Molecular Structure and Properties of Solanine and Solanidine Computational Study of the Molecular Structure and Properties of C60 Derivatives with Applications in Nanomedicine • • • • • • Discovery of some C60 derivatives that are water-soluble and thus of potential application if nanomedicine Computational molecular characterization of fullerene derivatives recently synthetized Determination of the structure, molecular properties, spectroscopy (IR, UV, NMR) and chemical reactivity Density Functional Theory (DFT) Electric, magnetic and optical properties Study of the chemical reactivity in order to find the active reaction sites Figura 1. Computational modelling of the molecular structure and properties of antifimic compounds linked to fullerenes and carbon nanotubes Nanomolecular Catalysis NANOCATALYSTS HAS-MoSxCy (High Adsorptive Sulfur) Molecular Nanoelectronics and Nanobiosensors MOLECULAR BEACONS When the fluorofore and the switch are linked there is no color, but when the hybridization with the target DNA takes place, there is a bright and shine fluorescence. TAMU Molecular Dynamics study of self-assembled monolayers of organic molecules on metallic surfaces Organic Semiconductors for Nanolectronics and DELFOS Nanotechnology Consortium CONACYT • • • • • Research Projects and Technological Development with the Private Industry: DESC MABE GCC IMSA COMEX COMEX • Computational modelling of new cromophores for their application in the painting industry • Computational simulation of the rate constants and reactivity relationships of differentes monomers of common use in the painting industry • Computational simulation of the solubility of the complex Co[(Ethylendiamine) (2 Ethylhexanoate)2] in different solvents IMSA • Development and characterization of nanostructured alloys • Reinforcement of metals for resistance to scratchs using polyester films with added inorganic nanoparticles PROLEC • Bibliography search on nanotechnology and it potential applications to electrical equipment Research Agreements with Academic USA Institutions • UT – Austin • SUNY – Albany • • • • • Optoelectronics and Nanophotonics Chemical Sensors Carbon Nanostructures Nanoparticules Computational Simulation of Nanostructures The University of Texas at Austin • Development of new nanomaterials for fuel cells • Computational Nanotechnology • Mechanical and microstructural characterization of aluminium based nanocomposites CINT Users Workshop, Albuquerque, NM, January 2006 New equipment Nova 200 NanoSEM JSM 7401F M.Sc. and Ph.D programs in Materials Science Orientation Nanotechnology • Introduction to Nanotechnology • Introduction to BioNanotechnology • Appplications of Computational Nanotechnology • Science and Technology of Nanocomposites • Computational Chemistry for Nanotechnology • Supramolecular Chemistry • Molecular Nanoelectronics Forty eight students have been finished their studies during 2006 and the first months of 2007. From them, about 71%, that is, 34 students have presented a M.Sc. or Ph.D. Thesis related with the Nanotechnology research lines of CIMAV. Thanks for your attention !!!