Transcript Slide 1

Biodiesel Basics
What is Diesel?
• Diesel is not a fuel
• Diesel is a compression ignited internal
combustion engine
• Spark ignited internal combustion engines
(gasoline) burn high distillate fuels
• Diesel engines burn middle distillate fuels
Diesel Engine and Biomass Fuels
• Invented in 1890’s by Rudolf Diesel
• Designed as engine for the people
• Farmer friendly
• All diesels ran on biomass fuels until the 1920’s
• Diesel engines will burn just about anything
• Most fatty acids or hydrocarbons from plant, animal
or fossil sources
What is Biodiesel?
• Biodiesel is a fuel comprised of mono-alkyl
esters of long chain fatty acids derived from
vegetable oils or animal fats
• Biodiesel is typically produced by a reaction of a
vegetable oil or animal fat with an alcohol such
as methanol or ethanol in the presence of a
catalyst to yield mono-alkyl esters and glycerin
www.nbb.org
What is Biodiesel?
• Slightly modified vegetable oil (or animal fat):
• 90% vegetable oil : 10% alcohol
• With glycerin (waxy stuff) removed
• Biodiesel improves the cold flow properties
(viscosity and gel point) and reduces emissions
compared to straight vegetable oil (SVO)
• Methyl ester most common
• Ethyl ester may offer some advantages
Current Primary Feedstocks
• United States: Soybean Oil
• Europe: Rapeseed Oil (RME)
• Germany and France
• Australia: Rapeseed and Mustard Seed Oil
• Many other feedstocks used to a lesser degree
throughout the world
Biodiesel in a Nutshell
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Made from renewable resources
Clean burning
Greenhouse gas neutral
Domestically producible in most regions
Highly biodegradable
Non-toxic
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Flashpoint over 300°f
No odor to pleasant odor (French fries)
High lubricity
High solvent characteristics
Biodiesel
Solution or Problem
Difficult to find peer reviewed negative conclusions
published in the last five years
Biodiesel vs. Food
• Biodiesel produced from feedstocks such
soybean oil:
• utilize a valuable food resource
• compete for space on highly productive land
• Are not efficient producers of oil
(Pimentel and Patzek, 2005)
• Soybeans and other similar feedstocks are likely
not the long-term future of biodiesel
Biodiesel and Energy Balance
• Pimentel and Patzek (2005) reported a negative
energy balance for biodiesel produced from
soybean oil and sunflower oil
• 0.8 for soybean oil
• There are problems with this study
• Did not include full value of soybean meal
• Included costs not normally included in energy
balance studies
• Does not mention gasoline energy balance is 0.8
Biodiesel and Subsidies
• Current biodiesel production requires
government subsidies in order to be price
competitive with petroleum fuels
(IRS, 2005; EO 13149, 2000)
• It currently does, but is this a problem
• Capturing externalities (the incomplete market)
• A newly emerging industry
(Tyson, 2005)
Alternative Feedstocks and $
• One of the most promising feedstocks for large
scale biodiesel production is high-lipid algae, but
after 20 years of research US DOE concluded it
was not commercially viable (Sheehan, et al., 1998)
• Private firms utilizing new technology are
coming to a different conclusion
(Huntly, 2005 (pending publication))
Technical Problems
• Biodiesel increases nitrous oxide emissions (NOX)
• Biodiesel has a higher gel point and viscosity than
petrodiesel
• Both of the above are being successfully
addressed through technological advances
References
EO 13149. 2000. Greening of the Government Through Federal Fleet and Transportation
Efficiencies: Executive Order 13149. Federal Register/Vol 65, No. 81/ Wednesday,
April, 2000
IRS. 2005. Fuel Tax Credits and Refunds. Publication 378. Department of the Treasury,
Internal Revenue Service.
NBB. National Biodiesel Board. www.nbb.org
Pimentel, D., and Patzek, T. 2005. Ethanol Production Using Corn, Switchgrass, and
Wood; Biodiesel Production Using Soybean and Sunflower. Natural Resource
Research, Vol. 14, No. 1
Sheehan, J., et al. 1998. A Look Back at the US Department of Energy’s Aquatic Species
Program-Biodiesel from Algae. National Renewable Energy Laboratory. Golden,
Colorado
Tyson, K. 2005. DOE Analysis of Fuels and Coproducts from Lipids. Fuel Processing
Technology, Vol. 86