Transcript Document

Kirchoff’s Loop Theorem
Two different materials with different emission and absorptions coefficients:
Ei and Ai, i =1,2
Energy flow from material i to material j : Fij - all energy is absorbed or reflected
1
2
E1
Energy flow F21 from 2 to 1: emission + reflection
Total power reflected by 1: F21(1 – A1)
E2
F12 = E1 + (1 – A1)F21
=
F21 = E2 + (1 – A2)F12

E1
E
= 2 = U
A1
A2
Must be true for all frequencies individually (use of filters…)
Kirchhoff - Loop Theorem (1859): Emission proportional to absorption
E(f, T) = U(f, T) A(f, T)
(total emission (E) and absorption coefficient (A) are material specific, U is universal)
A ≡ 1: all radiation absorbed  black body, E = U
Three Empirical Laws for Black Bodies
Stefan’ s Law (1879):
Empirical relation between temperature and power radiation per unit area:
R =  U ( f, T) df / A = sT 4 with the Stefan-Boltzmann constant: s = 5.67×10-8 W/m²/K4
R depends ONLY on T!!!
Wien’s Displacement Law (1893):
U ( f, T) has a maximum for a given T: fmax  T
lmaxT = 2.898×10-3 m K
For T < 300 °C: no significant emission in visible spectrum, max visible: ~4000 – 7000 K
Wien’s Exponential Law:
attempt to find a distribution that fulfills both empirical laws
(Stefan’s law and Wien’s displacement law) and is in accordance with the general
Boltzmann distribution. The proposed distribution is: U ( f, T) = A f ³ exp(-bf/T)
Good fit for high frequencies, but fails at low frequencies
Cavity Radiation
Best example for black body: small hole in cavity:
 Study radiation in cavity,
choose simple setup:
cubic box with metallic walls;
possible radiation: standing
waves with nodes at walls
a
n l/2 = a
Cavity Radiation
Interaction between waves and walls
(absorption and re-emission):
distribution of energy among different modes
l = (lx² +ly²)
n = (nx²+ ny²)
ly = 2a/3
ny = 3
n = (1+9)
l = 2a (1+1/9)
l = 2a (1/4+1/9)
l = 2a (1/9+1/9)
n = (1+4)
ly = 2a/2
ny = 2
l = 2a (1+1/4)
l = 2a (1/4+1/4)
l = 2a (1+1)
ly = 2a/1
ny = 1
n = (1+1)
nx = 1; lx = 2a/1
nx = 2; lx = 2a/2
nx = 3; lx = 2a/3
30
ny = 20
¼ 2pndn = 31.4
ny = 15
ny = 10
ny = 5
ny = 1
20 ≤ n < 21
(nx²+ny²= n²)
Rayleigh Jeans Formula
Number of degrees of freedom:
2a )3 f 2df )
N(f) df = 2 ( –1 4p (––
8
c
n2dn
2 polarizations
number of boxes
Energy per degree of freedom:
Edof = kT (= Ekin + Epot)
Energy density in box:
p kT f 2df
u = Etot /V= Edof  Ndof /V = 8–––––
c3
l = 2a/n
f = c / l = n c/2a
n = 2a/c f
Planck’s Formula
Interpolation between Wien’s exponential law and Rayleigh-Jeans formula:
u(f, T) =
8 ph f ³
1
c³
exp(h f /kT) – 1
with Planck’s constant h = 6.626×10 -34 Js
Max-Planck in Stockholm:
“But even if the radiation formula proved to be perfectly correct, it would after all
have been only an interpolation formula found by lucky guess-work and thus would
have left us rather unsatisfied. I therefore strived from the day of its discovery to give
it a real physical interpretation and this led me to consider the relations between
entropy and probability according to Boltzmann’s ideas. After some weeks of the
most intense work of my live, light began to appear to me and unexpected views
revealed themselves in the distance.”
Understanding Planck’s Formula
-- Discrete Boltzmann distribution --
E cont.
DE = kT
DE = 3kT
e–E/kT
P(E) =
kT
E cont.  Eav = 1.00 kT
DE = kT  Eav = 0.92 kT
DE = 3kT  Eav = 0.50 kT
E e–E/kT
kT
Average energy: (E exp(-E/kT)/kT) dE = kT
→ S (E exp(-E/kT)/kT)DE - decreases rapidly with step size
E = h f  S (…) = h f / (eh f kT – 1)
Planck’s Limited Postulate
(first interpretation)
The energy of oscillators (electrons) in the wall of the cavity can only assume
certain values that are multiples of hn
(Planck also derived the factor N(f ) from studying these oscillating electrons).
“Act of Desperation”
in a letter to R.W. Wood:
“I knew that the problem is of fundamental significance for physics; I knew the
formula that reproduces the energy distribution in the normal spectrum; a
theoretical interpretation had to be found at any cost, no matter how high.”
Black Body Spectrum
Clarification: a “Black Body” is an object
that absorbs all incident (EM) radiation –
but it also emits thermal radiation and
depending on the temperature may appear
very different from “black”!!
Apparent Color
10000
1000 K
3000
5000
7000
From: http://www.midnightkite.com/color.html
From: http://casswww.ucsd.edu/public/tutorial/Planck.html