Collapsing Can
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Transcript Collapsing Can
Formation of a Mirror
A solution is added to a flask. Within seconds a
brilliant mirrored surface forms on the inner wall of
the flask
Purpose
To observe a silver plating reaction
Demonstration
Sugar was one of the solutions in the
flask
A silver ion solution was the other
solution
Oxidation of the carbon occurred when
silver ion was reduced
Ag+
reduction
Ag
The silver metal reduction product
adhered to the glass
Concepts
1.
Redox Reactions
2.
Selective Organic Reactions
1. Redox Reactions
In a redox reaction, one substance loses
electrons while another substance gains
electrons
“Redox” is a conventional term which is
a combination of the words “reduction”
AND “oxidation”
The substance that loses electrons is
said to be oxidized and/or the reducing
agent
The substance that gains electrons is
said to be reduced and/or the oxidizing
agent
2. Selective Organic Reactions
Organic compounds may be totally
oxidized to carbon dioxide and
water
gasoline oxidation (combustion)
Organic compounds may be
selectively oxidized by adding an
oxygen atom to just one carbon
H
C
O
oxidation
O H
C O
Conclusions
The formation of silver metal
was due to the reduction of silver
ion
The reducing agent for silver ion
was the sugar
The sugar was simultaneously
oxidized as the silver ion was
reduced
Comments
Oxidation (the loss of electrons) of
one specie is always accompanied
by the reduction (the gain of
electrons) of another specie
The reaction in this demonstration
is the “Tollen’s Reaction” and is a
test for the presence of oxidizable
sugars