Transcript Slide 1

Our Energy Challenge
IEEE 2004
International Electron Devices Meeting,
San Francisco, December 14, 2004
R. E. Smalley
Rice University
PhD Degrees in Science and Engineering
25000
Asians citizens
All fields of Science &
Engineering
PhD per year
20000
15000
US citizens, all fields of Science
and Engineering, (excluding
psychology & social sciences)
10000
US citizens,
Physical Sciences and
Engineering only
5000
0
1985
1990
1995
2000
2005
Year
Source: Science and Engineering Indicators, National Science Board, 2002
World Energy
Millions of Barrels per Day (Oil Equivalent)
300
200
100
0
1860
1900
1940
1980
2020
2060
2100
Source: John F. Bookout (President of Shell USA) ,“Two Centuries of Fossil Fuel Energy”
International Geological Congress, Washington DC; July 10,1985.
Episodes, vol 12, 257-262 (1989).
see “Uppsala Code” analysis of IEA 2004 Outlook by Kjell Aleklett on www.peakoil.net
Global warming over
the past millennium
Very rapidly we have entered
uncharted territory -– what some call
the anthropocene climate regime.
Over the 20th century, human
population quadrupled and energy
consumption increased sixteenfold.
Near the end of the last century, we
crossed a critical threshold, and
global warming from the fossil fuel
greenhouse became a major, and
increasingly dominant, factor in
climate change. Global mean surface
temperature is higher today than it’s
been for at least a millennium.
Slide from Marty Hoffert NYU
Humanity’s Top Ten Problems
for next 50 years
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
ENERGY
WATER
FOOD
ENVIRONMENT
POVERTY
TERRORISM & WAR
DISEASE
EDUCATION
DEMOCRACY
POPULATION
2004
2050
6.5
~ 10
Billion People
Billion People
The ENERGY REVOLUTION
(The Terawatt Challenge)
50
50
45
40
35
30
25
20
15
10
5
0
2050
45
2004
40
14.5 Terawatts
35
220 M BOE/day
30
30 -- 60 Terawatts
450 – 900 MBOE/day
25
20
15
as
s
yd
ro
ele
w
in
ctr
d,
ic
ge
ot
he
rm
al
10
5
0
al
th
ec
t
el
ar
,w
in
d
,g
eo
ro
er
m
ric
s
Bi
o
n
m
as
So
l
20st Century = OIL
21st Century = ??
Hy
d
The Basis of Prosperity
Fu
s
io
n
/F
i ss
io
Ga
s
l
Oi
l
Co
a
Source: BP & IEA
So
la
r,
H
Bi
om
io
n
Fi
ss
as
G
Co
al
O
il
0.5%
PRIMARY ENERGY SOURCES
Alternatives to Oil
TOO LITTLE
• Conservation / Efficiency
-- not enough
• Hydroelectric
-- not enough
• Biomass
-- not enough
• Wind
-- not enough
• Wave & Tide
-- not enough
CHEMICAL
• Natural Gas
• Clean Coal
-- sequestration?, cost?
-- sequestration?, cost?
NUCLEAR
• Nuclear Fission
• Nuclear Fusion
• Geothermal HDR
• Solar terrestrial
• Solar power satellites
• Lunar Solar Power
-------
radioactive waste?, terrorism?, cost?
too difficult?, cost?
cost ? , enough?
cost ?
cost ?
cost ?
165,000 TW
of sunlight
hit the earth
Solar Cell Land Area Requirements
6 Boxes at 3.3 TW Each = 20 TWe
Slide from Nate Lewis
@ Cal. Tech
World Energy Scheme
for 30-60TW in 2050:
The Distributed Store-Gen Grid
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•
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Energy transported as electrical energy over wire, rather than by transport
of mass (coal, oil, gas)
Vast electrical power grid on continental scale interconnecting ~ 100 million
asynchronous “local” storage and generation sites, entire system continually
innovated by free enterprise
“Local” = house, block, community, business, town, …
Local storage = batteries, flywheels, hydrogen, etc.
Local generation = reverse of local storage + local solar and geo
Local “buy low, sell high” to electrical power grid
Local optimization of days of storage capacity, quality of local power
Electrical grid does not need to be very reliable
Mass Primary Power input to grid via HV DC transmission lines from
existing plants plus remote (up to 2000 mile) sources on TW scale,
including vast solar farms in deserts, wind, NIMBY nuclear, clean coal,
stranded gas, wave, hydro, space-based solar…”EVERYBODY PLAYS”
Electricity, Diesel, Hydrogen and Methanol are the transportation fuels
Enabling Nanotech Revolutions
1.
2.
3.
Photovoltaics -- drop cost by 10 fold.
Photocatalytic reduction of CO2 to methanol.
Direct photoconversion of light + water to produce H2.
4.
Batteries, supercapacitors, flywheels -- improve by 10-100x for the
distributed Store/Gen Grid, and automotive applications.
5.
H2 storage -- light weight materials for pressure tanks and LH2
vessels, and/or a new light weight, easily reversible hydrogen
chemisorption system (material X).
6.
Fuel cells -- drop the cost by 10-100x + low temp start + reversible
7.
Power cables (superconductors, or quantum conductors) with which
to rewire the electrical transmission grid, and enable continental, and
even worldwide electrical energy transport; and also to replace
aluminum and copper wires -- particularly in the windings of electric
motors and generators.
Single Walled Carbon Nanotubes
( Buckytubes)
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A New Miracle Polymer like Kevlar, Zylon, Spectra
The Strongest fiber that will ever be made.
Electrical Conductivity of Copper or GaAs.
Thermal Conductivity of Diamond.
The Chemistry of Carbon.
The size and perfection of DNA.
Semiconducting SWNT
Electronic States of Semiconducting SWNT
5
4
conduction
3
c2
2
c1
Energy
1
van Hove
singularities
0
v1
-1
v2
-2
-3
valence
-4
-5
0
2
4
6
8
Density of Electronic States
10
Nanotube Infrared Emitter
Slide Courtesy of
Phaedon Avouris, IBM Yorktown
SWNT Current Carrying Capacity
over 109 amps/cm2
Hongjie Dai et. al.
“High-Field Quasiballistic Transport
In short Carbon Nanotubes”
Phys. Rev. Lett. 92,106804 (2004)
Weak Accoustic Phonon scattering
lap ~ 300 nm
Strong Optical Phonon scattering
lop ~ 10 nm (threshold 0.15 eV)
Tube-to-Tube Quantum Tunneling
Alper Buldum and Jian Ping Lu, Phys. Rev. B 63, 161403 R (2001).
Buia, Buldum, and Lu, Phys. Rev. B 67, 113409 (2003).
QUANTUM WIRE PROJECT
ELECTRICAL CONDUCTIVITY
OF COPPER AT 1/6 THE WEIGHT
WITH NEGLIGIBLE EDDY CURRENT LOSS
• cut SWNT to short lengths (< 50 nm)
• select out the (n,m) tubes with n=m
(the “armchair tubes”)
• Attach catalyst to open ends
• grow from these seeds to >10 micron lengths
( “cloning”)
• spin them into continuous fibers
• SWNT cloning technology also enables
optimization of all other swnt applications
including molectronics, RFI shielding, sensors,
batteries, and microwave absorption
SWNT Fiber Spinning in Oleum
ONR DURINT (4th yr of 5 yr grant)
Fiber Spinning in Progress Close-up
Take-up of Spun fiber
An overview of SWNT Fiber
A close look at the ropes
SWNT Amplification
1.
2.
3.
4.
5.
6.
Cut to short lengths (< 50 nm)
Solubilize in Ethanol
Attach catalyst
Inject into reactor and grow clone
Harvest cloned product
Feedback to step 1
(start with initial swnt
Sorted & selected by end chemistry)
Same old chemistry.
But these organic molecules conduct electricity!
SWNT Amplifier
Cloning Reactor
500 < T < 700 C
( input signal)
SWNT+ FeMoC Catalyst
CO + H2
feed
Monoclonal SWNT
Catalyst
Prep.
Gain = output/input = mass of product swnt / mass of swnt seeds
10 nm long seeds  10 micron long product;
gain ~ 1000
Cloning from Selected SWNT Seeds
Attach FeMoC to swnt seed
Growth in CO + H2
Deposit on Surface
Reductive Docking in H2
Iron Molybdate Cluster ( FeMoC )
a Precursor for SWNT Cloning Catalyst
• Icosahedral capsule
Mo(VI)72Fe(III)30
– Internal cavity diameter: ~16 Ǻ
– Diameter: ~ 21 Ǻ
• Keggin anion guest
{[HxPMo12O40]3-}
– Diameter: ~14 Ǻ
Agnew. Chem. Int. Ed. 2000, 39, No. 19
Carbon
Nanotechnology
Laboratory
Making BuckyTubes
Be All They Can Be.
• Established at Rice Univ. - September, 2003
• Dr. Howard K. Schmidt - Executive Director
• Dr. Robert H. Hauge – Technology Directo
The biggest single challenge for the next few decades:
ENERGY
for 1010 people
•
. At
MINIMUM we need 10 Terawatts (150 M BOE/day)
from some new clean energy source by 2050
•
For worldwide peace and prosperity we need it to be cheap.
•
We simply can not do this with current technology.
•
We need Boys and Girls to enter Physical Science and Engineering as
they did after Sputnik.
•
Inspire in them a sense of MISSION
( BE A SCIENTIST
SAVE THE WORLD )
• We need a bold new APOLLO PROGRAM
to find the NEW ENERGY TECHNOLOGY
The Nickel & Dime Solution
•
For FY05-FY10 collect 5 cents from every gallon of oil product
Invest the resultant > $10 Billion per year as additional funding in
frontier energy research distributed among DOE, NSF, NIST, NASA,
and DoD.
•
For the next 10 years collect 10 cents from every gallon;
invest the >$20 Billion per year in frontier energy research.
•
Devote a third of this money to New Energy Research Centers
located adjacent to major US Research Universities.
•
At worst this endeavor will create a cornucopia of new technologies
and new industries.
•
At best, we will solve the energy problem before 2020,
and thereby lay the basis for energy prosperity & peace worldwide.
Reading Assignments
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Out of Gas, Daniel Goodstein
The End of Oil, Paul Roberts
The Prize, Daniel Yergin
Hubbert’s Peak, Kenneth Deffeyes
Matt Simmons web site (www.simmons-intl.com)
ASPO web site ( www.peakoil.net)
Gal Luft web site (www.iags.org)
Amory Lovins web site (www.rmi.org)
M.I. Hoffert et. al., Science, 2002, 298, 981,
DOE BES Workshop Report on Hydrogen
(www.sc.doe.gov/bes/hydrogen.pdf)