Transcript Template for SFR Presentations

3rd Annual SFR Workshop, November 8, 2000
8:30 –
9:00 –
9:50 –
10:10 –
11:00 –
12:00 –
1:00 –
1:50 –
2:40 –
3:30 –
4:30 –
9:00
9:50
10:10
11:00
11:50
1:00
1:50
2:40
4:30
4:30
5:30
Research and Educational Objectives / Spanos
Plasma, Diffusion / Graves, Lieberman, Cheung, Haller
break
Lithography / Spanos, Neureuther, Bokor
Sensors & Metrology / Aydil, Poolla, Smith, Dunn
lunch
CMP / Dornfeld, Talbot, Spanos
Integration and Control / Poolla, Spanos
Poster Session and Discussion, 411, 611, 651 Soda
Steering Committee Meeting in room 373 Soda
Feedback Session
2
Chemical Mechanical Planarization
SFR Workshop
November 8, 2000
Andrew Chang, Tiger Chang, David
Dornfeld, Tanuja Gopal, Edward I. Hwang,
Jianfeng Luo, Zhoujie Mao, Costas Spanos,
Jan Talbot
Berkeley, CA
11/8/2000
3
CMP Milestones
• September 30th, 2001
– Build integrated CMP model for basic mechanical and chemical
elements. Develop periodic grating metrology (Dornfeld, Talbot,
Spanos).
• September 30th, 2002
– Integrate initial chemical models into basic CMP model. Validate
predicted pattern development. (Dornfeld, Talbot) .
• September 30th, 2003
– Develop comprehensive chemical and mechanical model. Perform
experimental and metrological validation. (Dornfeld, Talbot,
Spanos)
11/8/2000
4
Abstract
2001 Milestone: Build integrated CMP model for basic
mechanical and chemical elements. Develop periodic
grating metrology
Key elements involved in this are:
–
–
–
–
–
–
Chemical Aspects of CMP (J. Talbot and T.Gopal)
Particle Size Distribution in CMP: Modeling and Verification (J. Luo)
Slurry Flow Analysis and Integrated CMP Model (Z. Mao)
Scratch Testing of Silicon Wafers for Surface Characterization (E. Hwang)
Process Monitoring of CMP using Acoustic Emission (A. Chang)
Development of periodic grating metrology (C. Spanos and T. Chang)
We will review the recent activities in these areas
11/8/2000
5
Overview
Model Structure
& Development
Chem Mech
Chemical
Aspects
(JT/TG)
Particle Size
Distribution
(JL)
Slurry Flow
(ZM)
Surface Effects
(EH)
Process
Monitoring
(AC)
Grating
Metrology
(CS/TC)
Process control
(KP)
11/8/2000
X
X
Basic
Process
Mechanism
Model
Validation
Metrology, Process
Control, &
Optimization
X
X
X
X
X
X
X
X
X
X
X
X
6
Overview of Integrated Model
Pad Roughness
Pad Hardness
Chemical Reaction
Model (RR0)chem
Wafer Hardness
Fluid Model
Slurry Concentration,
Abrasive Shape, Density,
Size and Distribution
Down Pressure
Slurry Chemicals
Relative Velocity
Model of
Active Abrasive
Number N
Model of Material
Removal VOL
by a Single Abrasive
Physical Mechanism; MRR: N´VOL
Preston’s Coefficient Ke
Dishing &
Erosion
11/8/2000
Surface
Damage
Wafer, Pattern,Pad and
Polishing Head Geometry
and Material
Contact Pressure
Model
Pressure and Velocity
Distribution Model
(FEA and Dynamics)
(RR0 )mech
WIWNU
WIWNU
MRR
WIDNU
7
Chemical Aspects of CMP
Role of Chemistry - Tanuja Gopal, Jan Talbot UCSD
• Chemical and electrochemical reactions between
material (metal, glass) and constituents of the slurry
(oxidizers, complexing agents, pH)
– Dissolution and passivation
• Solubility
• Adsorption of dissolved species on the abrasive
particles
• Colloidal effects
• Change of mechanical properties by diffusion &
reaction of surface
11/8/2000
8
Mass Transfer Processes
• (a) movement of solvent
into the surface layer under
load imposed by abrasive
particle
• (b) surface dissolution under
load
• (c) adsorption of dissolution
products onto abrasive
particle surface
• (d) re-adsorption of
dissolution products
• (e) surface dissolution
without a load
11/8/2000
Ref. L. M. Cook, J. Non-Crystalline Solids,
120, 152 (1990).
9
Reaction Chemistries
• Dissolution of glass
(SiO2)x + 2H2O = (SiO2 )x-1 + Si(OH)4
R+(glass) + H2 O = H+(glass) + ROH
• Dissolution and passivation of W
-2
-4
+
W + 6Fe(CN)-3
+
4H
O

WO
+
6Fe(CN)
+
8H
2
6
4
6
-4
+
W + 6Fe(CN)-3
+
3H
O

WO
+
6Fe(CN)
+
6H
2
3
6
6
11/8/2000
10
Generic Chemical Reactions
• Dissolution: M(s) + A -> M(aq) + B
M(s) + A -> Mn+ + ne- + B
• Oxidation: M(s) + O -> M-oxide(s)
• Oxide dissolution:
M-oxide(s) + A -> M(aq) + B
M-oxide(s) + A -> Mn+ + ne- + B
• Complexation (to enhance solubility)
11/8/2000
11
Colloidal Effects
• Surface charge (zeta potential
or isoelectric point, IEP, the pH
where the surface charge is
neutral) of polished surface
and abrasive particle is
important
(Malik et al.)
11/8/2000
12
Colloidal effects
• Maximum polishing rates for
glass observed compound IEP ~
solution pH > surface IEP
(Cook, 1990)
• Polishing rate dependent upon
colloidal particle - W in KIO3
slurries
(Stein et al., J. Electrochem. Soc. 1999)
11/8/2000
13
Experimental Program
• Electrochemical/chemical
experiments with rotating
disk electrode with and
without abrasion
• Measurement of zeta
potential of abrasives as
function of pH (IEP) and
solution chemistry
11/8/2000
Potentiostat
Counter
Electrode
RDE
Reference
Electrode
Polishing Pad
14
Modeling of Chemical Effects
• Electrochemical/chemical dissolution and passivation
of surface constituents
• Colloidal effects (adsorption of dissolved surface to
particles or re-adsorption)
• Solubility changes
• Change of mechanical properties (hardness, stress)
11/8/2000
15
Pad Roughness
Pad Hardness
Chemical Reaction
Model (RR0)chem
Wafer Hardness
Fluid Model
Slurry Concentration,
Abrasive Shape, Density,
Size and Distribution
Down Pressure
Slurry Chemicals
Relative Velocity
Model of
Active Abrasive
Number N
Model of Material
Removal VOL
by a Single Abrasive
Physical Mechanism; MRR: N´VOL
Preston’s Coefficient Ke
Dishing &
Erosion
11/8/2000
Surface
Damage
Wafer, Pattern,Pad and
Polishing Head Geometry
and Material
Contact Pressure
Model
Pressure and Velocity
Distribution Model
(FEA and Dynamics)
(RR0 )mech
WIWNU
WIWNU
MRR
WIDNU
16
Synergistic Effects
• MRR = kchem (RRmech)o + kmech (RRchem)o
(RRmech)o = mechanical wear = Ke PV
(RRchem)o = chem. dissolution = kr exp(-E/RT)PCin
Ke affected by surface chemical modification
Ci affected by mass transport (i.e., V)
Ref.: Y. Gokis & R. Kistler, ECS Meeting Abstract 496, Phoenix, Oct. 2000.
11/8/2000
17
Potential Results for Chemical MP Modeling
• Selective chemical slurries:
1) control reaction chemistry
2) control colloidal properties of abrasives and
removed material
3) enhance solubility of removed material
• Material wear properties (eg, hardness)
• Chemically active pads
11/8/2000
18
Chemical Effects of CMP
• Synergistically enhances the rate of material removal
with mechanical polishing
• Influences the colloidal stability of the abrasive
particles
• Undesired effects are unwanted etching and dishing
of features and increased surface roughness
Er osion
11/8/2000
Dis hing
19
Effect of Particle Size Distribution in CMP
Modeling Abrasive Geometry and Size - J. Luo UCB
100nm
Two Abrasive Geometries
• Spherical Shape for Obtuse Abrasives
• Conical Shape for Sharp Abrasives
X
X
Schematic of Spherical and Conical
Abrasive Shapes in the Model
SEM Picture of Slurry Abrasives for Si CMP
(Moon, PhD Thesis, 1999)
60
y
50
40
Abrasive Size and Size Distribution
30
Xmax
20
10
• Nano-Scale Size X
• Normal Distribution (Xavg , ) and p((Xavg , )
• Xavg, Xmax and Standard Deviation 
11/8/2000
0
-8
-6
-4
-2
0
2
Xavg
4
6
8
Portion of Active
Abrasive
Schematic of Abrasive Size Distribution
20
Xmax-Y=2
n
Detailed Fluid
Model
11/8/2000
local single points
Pad
Hardness
Schematic of Wafer-Abrasive-Pad Interaction to
Model the Number of Active Abrasive Number
7000
6000
5000
4000
3000
2000
1000
0
-1000
-2000
-3000
-4000
-5000
-6000
-7000
-40
40
30
20
10
-30
-20
-10
X Ax
is (m
0
m)
10
20
30
0
-10
-20
-30
-40
)
a22= F2/Hp
Surface
Damage
8000
m
Contact Mechanics( Pad
Topography/Abrasive Size/Pressure )
(m
N
Material Removal Rate Function:
MRR= N Vol= C1Hw-3/2 {1-(1C2P01/3}P01/2V. Correct on both average scale &
is
1
Schematic of Wafer-ChemicalAbrasive-Pad Interaction to
Model the Volume Removed by
A Single Abrasive
Slurry pH Value and so on
Ax
 V = Vol
?
Chemical
Reaction
Y
a12= F2/Hw
Z Axis (A)
Contact Mechanics( Pad
Topography/Abrasive Size/Pressure )
Role of Abrasive Size in the
Architecture of the Integrated CMP
Model
40
Pressure and velocity
distribution over waferscale
Pattern
Density
WIWNU
WIDNU
21
MRR As A Function of Particle Size Distribution Before
Saturation (Luo & Dornfeld, 2000)
MRR=
X  3  



p 3 - C4 avg

X avg  3  


C3 




1

3
C
X



4
avg
3 




X avg  3  
X avg 



 
  3 - C4
 





Contribution of
Active Particle
Number
Contribution of
Active Particle
Size (Larger than
Xavg)
Contribution of Total
Number of Particles over the
Wafer-Pad Interface
MRR as A Function of Particle Size and
Size Distribution
11/8/2000
2
MRR as A Function of Down
Pressure and Velocity: MRR= N
Vol= C1Hw-3/2 {1-(1C2P01/3}P01/2V.
C3: A Function of Down Pressure,
Velocity, Weight Concentration etc.
C4: 0.25(4/3)2/3(1/Hp)Ep2/3/b1P01/3 A
Function of Down Pressure, Pad
Hardness and Pad Topography.
Function p: The probability of the
appearance of abrasive size
Function : Probability density
function.
22
Particle Size Distribution Measurement (II)
Dynamical Light Scattering
*Bielmann et. al. 1999
11/8/2000
Mean
Size
(m)
Standard
Deviation
(m)
AKP50
0.29
0.070222
AKP30
0.38
0.118959
AKP15
0.60
0.210633
AA07
0.88
0.288768
AA2
2.00
1.056197
23
Particle Size Dependence on MRR:
Experiment VS. Model Predictions
Material Removal Rate (nm/min)
800
Experimental Mean MRR
(0.29, 0.07022)
700
(0.38, 0.118959)
600
Prediction of the Model
Power (Experimental Mean MRR)
500
Power (Prediction of the Model)
(0.60, 0.210633)
400
y = 325.1x-0.6411
300
(0.88, 0.288768)
200
y = 314.77x-0.6695
100
C4: 0.25(4/3)2/3(1/Hp)Ep2/3/b1P01/3= 0.015
0
0
0.5
1
1.5
Particle Size (10-6 m)
* Bielmann et. al. 1999
11/8/2000
(2.0, 1.056197)
2
2.5
24
Fraction of Active Particles Based on
Model Prediction
[0.726, 0.737m]
0.1827%
[1.213, 1.231m]
0.1798%
[0.49, 0.50m]
0.19105%
11/8/2000
[1.720, 1.746m]
0.1815%
[5.091, 5.169m]
0.1719%
25
Normalized Material Removal Rate
Relationship between Standard Deviation
and MRR Based on Model Prediction
2
Number
Dominant
Region
1.8
1.6
Xavg= 0.29um
Size
Dominant
Region
Xavg=0.38um
Xavg=0.60um
1.4
Xavg=0.88um
1.2
Xavg=2um
1
0.8
0.6
0.4
0.2
0
0
0.05
0.1
0.15
0.2
Standard Deviation (10-6 m)
11/8/2000
0.25
0.3
26
2002 & 2003 Goals
Develop comprehensive chemical and mechanical model.
Perform experimental and metrological validation, by
9/30/2003.
Down Pressure
Wafer
Smaller contact area
Larger contact area
H
H
a
11/8/2000
27
Slurry Flow Analysis and Integrated CMP Model
Zhoujie Mao UCB
Motivation
• Study the effects of slurry flow on the material removal
in CMP
• Develop integrated process model for CMP to provide
insight into the MRR and WIWNU
• Develop process model for environmental impact
analysis for CMP
11/8/2000
28
Overall Picture of Slurry Flow in CMP
Side view
Carrier
Slurry
Slurry feeder
Wafer
Polishing plate
Carrier film
Polishing pad
• Two flow stages: slurry flow on the polishing pad, slurry flow
between wafer and polishing pad
11/8/2000
29
Slurry Flow on the pad
Slurry
Polishing pad
Abrasive particle
• Estimate the abrasive particle settling mechanism on the
polishing pad
• Study the effects of slurry supply rate and slurry delivery
position on the material removal rate
11/8/2000
30
Abrasive Particle Settling Rate Vs. Slurry
Supply Rate
8
Q=50ml/min
Q=100ml/min
Q=150ml/min
7
6
2
2/s)
(n/m
Rate ofRateDeposition
of deposition (n/m/sec)
15
x 10
5
4
3
2
1
0
0
20
40
60
80
100
120
Radius (mm)
Radius (mm)
11/8/2000
140
160
180
200
31
Abrasive Particle Settling Rate Vs. Delivery Position
8
Average
Settling Rate Beneath Wafer
Average Settling Rate Underneath Wafer
e=0mm
e=100mm
e=200mm
7
6
Eccentricity
2/s)
(n/m
Rate
Settling
AverageAverage
2
Settling Rate (n/m/s)
16
x 10
5
4
3
2
1
100
120
140
160
180
200
220
Raidial Position (mm)
240
260
Radial Position (mm)
11/8/2000
280
300
32
Integrated Slurry Flow Model
•
•
•
•
Slurry flow between wafer and polishing pad
Slurry flow inside polishing pad
Deformation of wafer
Deformation of polishing pad
h(x)
hp(x)
Pad
11/8/2000
33
2002 & 2003 Goals
Develop comprehensive chemical and mechanical model.
Perform experimental and metrological validation, by
9/30/2003.
•Simulation of Integrated CMP model
•Experimental verification of integrated CMP model (role of
active abrasives in mechanical material removal)
11/8/2000
34
Scratch Testing of Silicon Wafers for Surface Characterization
Edward Hwang UCB
Motivation
• Wafer surface characterization is important
to understand and model the material
removal mechanism in CMP
- Scratch testing supports the identification and
verification of surface characteristics of the wafer
representative of the CMP process
- Scratch testing can give insight on the stress levels
occurring during the CMP Process
11/8/2000
35
Actual CMP Situations
Cross Section View
bulk
not affected by the process
Si wafer
layer 2(order of 20 nm )
plastically compressed network
– higher density
polishing pad
layer 1(order of a few nm )
highly hydrated, loosely bound network
– lower density
Trogolo et al “Near Surface Modification of Silica Structure Induced by Chemical/Mechanical Polishing”,
J. Materials Science 29 (1994) pp. 4554 - 4558
11/8/2000
36
Experimental Setup
•Workpiece:
Silicon wafer <100> p-type
Pre-CMP Wafers & Post-CMP Wafers
• Diamond tool: Nose radius: 48μm
• Feed rate:
V=399μm/s
• Tilt angles:
0.06 degrees.
• Acoustic emission sensor: DECI Pico-Z AE sensor
• Data collection: 50kHz sampling rate
11/8/2000
37
Layers vs. AE Signals (1)
Pre-CMP Wafers
1.0
0.8
AE signals (volts)
0.6
0.4
0.2
0.0
-0.2
-0.4
-0.6
-0.8
-1.0
0.00
0.05
0.10
0.15
0.20
0.25
0.30
time(s)
AE signals are proportional to the depth of cut in
11/8/2000
0.35
38
Layers vs. AE Signals (2)
Post-CMP Wafers
1.0
0.8
AE Raw Signals (volts)
0.6
0.4
0.2
0.0
-0.2
-0.4
-0.6
-0.8
-1.0
0.00
0.05
0.10
0.15
0.20
0.25
0.30
time(s)
Air-cut +
Layer 1
Layer 2
Bulk
0.35
Unlike the pre-CMP wafers, post-CMP wafers show discontinuous
transitions in the AE signal due to penetration of Layer 2.
11/8/2000
39
Results
• Observation of distinct signal changes for transitions
between Layer 1  Layer 2  bulk supports surface
characterization
• Signal for Layer 2 is observed up to 20 nm depth of cut
• Highly compressed Layer 2 is more ductile than bulk :
- Plastic deformation dominates the material removal
mechanism in this regime and should relate to removal
rate during CMP
• SEM images support the verification of the multilayered wafer surface
11/8/2000
40
2002 & 2003 Goals
Develop comprehensive chemical and mechanical model.
Perform experimental and metrological validation, by
9/30/2003.
• Replicate the scratch testing with AFM machine
in order to be closer to actual CMP situations
• Quantify the wafer surface characteristics in
CMP
11/8/2000
41
Process Monitoring of CMP using Acoustic Emission
Andrew Chang UCB
Motivation
• AE monitoring is an applicable diagnostic tool for
studying abrasive interaction during CMP
• Experimental verification for abrasive particle
interaction is needed for CMP modeling
• Alternative sensing methods are in-direct (motor
current, pad temperature, etc.) or limited to localized
areas of the wafer
11/8/2000
42
Acoustic Emission Sources in CMP
• Acoustic emission is highly sensitive to abrasive particle
interaction between wafer and pad
11/8/2000
43
Experimental Setup
Pre-amplifier
(60 dB)
PC Data Acquisition
Amplifier
(40 dB)
RMS Filter
RMS AE
Raw AE
Raw Sampling Rate = 2 MHz
RMS Sampling Rate = 5 kHz
AE Transducer
Wafer
CMP Tool
Toyoda Float Polishing Machine
Test Wafers
Oxide, aluminum, tungsten, copper blanket wafers
Slurry type
ILD 1300, abrasive size (~100 nm)
W-Slurry, abrasive size (~37 nm)
Alumina slurry, abrasive size (~100 nm)
Pad type
IC 1000/Suba IV stacked pad
Polishing Conditions
Pressure = ~ 1 psi
Table Speed = 20 – 80 RPM
Slurry flowrate = 150 ml/min
11/8/2000
44
AE Ratio Signal Processing
ASL
HFpeak
t
High Pass Filter
>100 kHz
Ratio =
Raw AE Signal
Low Pass Filter
20-60 kHz
ASL
LFpeak
t
HF/LF Ratio
AE Ratio for Oxide Wafer
1.7
1.5
1.3
1.1
0.9
0.7
0.5
Oxide-DIW
Oxide-Slurry
0
11/8/2000
20
40
60
Table RPM
80
100
HFpeak
LFpeak
45
AE Signal for Varied Materials
AE ASL (mV)
High Frequency Average Signal Level during CMP
Polishing
Background
Noise
Oxide
4000
3000
2000
Aluminum
1000
0
Tungsten
0
20
40
60
Table RPM
11/8/2000
80
100
Copper
46
Application to Endpoint Detection
• The sensitivity of acoustic emission to various materials
during polishing is ideal for endpoint detection in CMP
AE Ratio for Oxide Polishing
Oxide cleared
0.65
AE Ratio
0.6
Pad
0.55
Oxide begins
to clear
0.5
0.45
Pad
0.4
0.35
0
50
100
Time (sec)
Oxide
Wafer
Pad
11/8/2000
150
200
47
Sensitivity to CMP Process
• Background noise characterization
• AE is insensitive to low-frequency (audible) noise from CMP
tool (motors, belts, etc.)
• Sensor location (backside of wafer is ideal) isolates signal
from process and filters noise
• Signal from process is sensitive to abrasive particle
interaction
• Signal comparison between deionized water and abrasive
slurry
• Sensitivity to different materials
11/8/2000
48
2002 & 2003 Goals
Develop comprehensive chemical and mechanical model.
Perform experimental and metrological validation, by
9/30/2003.
•Future tests planned with industrial CMP tool manufacturer
•Further experimental tests for validation of integrated CMP
model (role of active abrasives in mechanical material
removal)
11/8/2000
49
Establishing full-profile metrology for CMP modeling
Costas Spanos & Tiger Chang UCB
Pattern density mask - MIT 96.4
Feature size 10 m
Die size 20mm by 20mm
Pattern density ranges
from 4% to 100%
11/8/2000
50
Process Flow
Get the mask files
PSG deposition 1 m
PECVD oxide ~2m
Design contact mask
Aluminum 0.7 m
CMP
Make emulsion mask
Pattern Aluminum
The final structure
11/8/2000
51
Results of Experiment (typical)
Wafer #2 r=0.9807 PL=2.450mm
7000
The characteristic length is about
2~3mm; this motivates a new
mask design
Oxide Removal Rate A/3 minutes
6500
6000
5500
5000
4500
4000
3500
3000
0.2
11/8/2000
0.3
0.4
0.5
0.6
0.7
effective Pattern Density
0.8
0.9
1
52
New Mask Design
• The size of the
metrology cell
is 250m by
250m
• 2m pitch
with 50%
pattern density
11/8/2000
53
Key ideas
Oxide
Substrate
• Use Scatterometry to monitor the profile evolution
• The results can be used for better CMP modeling
11/8/2000
54
Current status
• Done mask design and processing in the Lab, 12
wafers are ready to polish
• Before the characterization experiments, we want to
know
– Is the scatterometer signal sensitive enough for the profile
evolution?
• Simulated a conceptual profile evolution
– How does the initial profile look like?
• LEO can give a cross section SEM view (we need to cut the
wafer, then can’t do CMP on this wafer anymore!)
• AFM can give a smooth profile (it needs reliable deconvolution)
11/8/2000
55
CMP Profile evolution used in GTK simulation
Profile Evolution during CMP
0.5
0.45
0.4
profile (micron)
0.35
0.3
0.25
0.2
0.15
0.1
0.05
0
11/8/2000
0
500
1000
Oxide (nm)
1500
2000
56
GTK Metrology Simulation Results
Tan PSI Response to Profile Evolution
0.8
0.7
0.6
tan PSI 500nm
tan PSI
0.5
tan PSI 400nm
tan PSI 300nm
0.4
tan PSI 200nm
tan PSI 100nm
0.3
tan PSI Flat Surface
0.2
0.1
76
0
72
0
68
0
64
0
60
0
56
0
52
0
48
0
44
0
40
0
36
0
32
0
28
0
24
0
0
Wavelength(nm)
Cos DEL Response to Profile Evolution
1.5
1
cos DEL 500nm
cos DEL 400nm
cos DEL 300nm
0
-0.5
76
0
72
0
68
0
cos DEL 100nm
cos DEL Flat Surface
-1
-1.5
Wavelength(nm)
11/8/2000
64
0
60
0
56
0
52
0
48
0
44
0
40
0
36
0
32
0
cos DEL 200nm
28
0
24
0
cos DEL
0.5
• We simulated 1 m
feature size, 2 m
pitch and 500nm
initial step height, as
it polishes.
• The simulation shows
that the response
difference was fairly
strong and detectable.
57
Profiles before polishing (LEO)
11/8/2000
58
Immediate Metrology Objectives
• Do measurements using Sopra for the initial
structures, compare results with the AFM
measurements
• Build a pseudo response library
• Design experiments, polish finished wafers and do
scatterometry measurements
• AFM measurements at AMD, refine the library
11/8/2000
59
Conclusions
• Chemical effects model and synergy with mechanical effects
being developed
• Integrated model validated for abrasive size and activity
• Fluid modeling of particle behavior corroborates abrasive
activity
• Extent and behavior of surface modified layer being
characterized
• Sensing system for process monitoring and basic process
studies being validated
• Scatterometry metrology sensitivity study indicates suitability
for observing profile evolution
11/8/2000