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Emerging Clean Coal Technologies: Limiting the Environmental Impact of Coal Power Generation Michael Slanders Office of Clean Energy Systems, US Department of Energy Presentation Overview I. US/World Electricity Outlook II. Clean Coal Technologies as a Solution III. Meeting R&D Challenges 1. Gasification 2. Advanced Combustion 3. Carbon Capture and Storage IV. Demonstrating Clean Coal’s Potential 1. FutureGen 2. Clean Coal Power Initiative (CCPI) 12-11-2007 Slanders EPA Region 4, Atlanta, GA 2 U.S. & World Electricity Outlook U.S. World Renewables 9% Coa l 53% Natural Gas 14% Nuclear 21% Oil 3% 41% increase from 2005-2030 85% increase/yr. from 2004-2030 Challenge: Meet the increasing national/worldwide demand while addressing global climate change 12-11-2007 Slanders Sources: International Energy Outlook, 2007: Fig. 60; Annual Energy Outlook, 2007: Fig. 53 & 2006: Table 8 EPA Region 4, Atlanta, GA 3 Clean Coal Technologies as a Solution Near-Zero Emissions - Remove all environmental concerns over the use of coal with regard to criteria pollutants and greenhouse gas emissions (CO2) Emerging Clean Coal Technologies (CCT) - Integrated Gasification Combined Cycle (IGCC) - Ultra-Supercritical Combustion - Oxy-fuel Combustion Carbon Capture and Storage (CCS) - Stabilize greenhouse gases in the R&D Challenges 1. Limit Environmental Impact 2. Improve Cost, Efficiency, & Reliability atmosphere through safe and permanent sequestration 12-11-2007 Slanders EPA Region 4, Atlanta, GA 4 Clean Coal’s Path to Near-Zero Emissions Carbon Capture and Storage Capture Advanced Combustion Storage FutureGen Large-Scale Field Tests CCPI Core R&D Program Advanced Research 12-11-2007 Slanders Advanced Turbines Fuel Cells Fuels EPA Region 4, Atlanta, GA IGCC Carbon Sequestration 5 Overview of Advanced Gasification Advanced Gasification Features • Partial oxidation rather than complete combustion • Formation of a combustible “syngas” that can be cleaned of potential pollutants • “Combined Cycle” power generation (combustion & steam) • Hydrogen production • Marketable byproducts 12-11-2007 Slanders IGCC Flow Diagram, Source: Colorado School of Mines EPA Region 4, Atlanta, GA 6 Meeting Gasification R&D Challenges Emerging Technologies: IGCC Limiting Environmental Impact 1. Develop high-temperature syngas shift technologies for hydrogen combustion Improving Cost, Efficiency, & Reliability 1. Lower technology capital costs - Gasification - Air Separation Units - Hydrogen Turbines IGCC Power Plant, Polk County. TECO Energy - Fuel Cells 2. Develop membrane technologies for H2/CO2 separation 3. Demonstrate near-zero IGCC feasibility at large-scale 4. Reduce maintenance/operation costs 12-11-2007 Slanders EPA Region 4, Atlanta, GA 7 Overview of Advanced Combustion Advanced Combustion Features • Capable of enhancing existing power generation facilities • Reliable processes and generation methods • Higher efficiencies • Lower specific emissions 12-11-2007 Slanders Oxy-Fuel Flow Diagram, Source: www.ccsd.biz EPA Region 4, Atlanta, GA 8 Meeting Advanced Combustion R&D Challenges Emerging Technologies: Ultra-supercritical Oxy-fuel 5 4.4 Pollutants (lb/MM Btu) Limiting Environmental Impact 1. Enhance current flue gas cleanup - Flue Gas Desulfurization (SOx) - Selective Catalytic Reduction (NOx) - Electrostatic Precipitation (PM) 2. Develop advanced low NOx burners Emissions from Coal Power Plants 4 1970 3 1997 2005 2 1.4 1 0.8 1.1 0.58 0.5 Improving Cost, Efficiency, & Reliability 0.39 0.03 1. Reduce the costs of: 0 Sulfur Nitrogen Particulate - High-temperature and Dioxide Oxides Matter high-strength materials - Large-volume CO2 capture 2. Enhance low-cost membrane technologies for Air Separation Units 3. Demonstrate at large-scale 12-11-2007 Slanders EPA Region 4, Atlanta, GA 9 E Meeting Carbon Capture and Storage R&D Challenges Emerging Technologies: Capture- Advanced Selexol, Membranes, Advanced CO2 Compression Storage- Geologic Formations, Enhanced Oil Recovery Limiting Environmental Impact 1. Monitor sites to insure permanent storage 2. Develop sequestration options most suited for particular regions - Regional Partnerships - Carbon Sequestration Leadership Forum (CSLF) Improving Cost, Efficiency, & Reliability 1. Improve capture methods 2. Demonstrate at large-scale Geologic Sequestration Paths 12-11-2007 Slanders EPA Region 4, Atlanta, GA 10 Demonstrating Clean Coal’s Potential: FutureGen Objectives of the FutureGen Project: Integrate IGCC, CCS, and hydrogen production technologies to gain acceptance of the near-zero emissions coal concept Prove the effectiveness, safety, and permanence of large-scale CO2 sequestration Validate the engineering, economic, and environmental viability of coal-based nearzero emission technologies for commercial readiness by 2020. 12-11-2007 Slanders EPA Region 4, Atlanta, GA 11 Demonstrating Clean Coal’s Potential: CCPI Great River Energy Lignite Fuel Enhancement $13.5M – DOE $31.5M – Total Excelsior Energy IGCC $36 M – DOE $2,156 M – Total NeuCo, Inc. Integrated Optimization Software $8M – DOE $18M – Total Pegasus Technologies Adv Sensor / Optimization Hg / Multi-pollutant $6.1 M – DOE $12.2 M – Total 12-11-2007 Slanders Wisconsin Electric Power Co. TOXECON Multi-Pollutant Control $25M – DOE $50M – Total WMPI PTY., LLC Coal-to-Clean Fuels & Power $100M – DOE $612M – Total Western Greenbrier Clean Coal Co-Production $107M – DOE $214M – Total U. of Kentucky Research Foundation Multi-Product Coal Utilization $4M – DOE $9M – Total EPA Region 4, Atlanta, GA So. Co. Services IGCC-Transport Gasifier $294 M – DOE $844 M – Total 12 Summary Remarks Coal will continue to play a large role in domestic/worldwide power generation Clean Coal Technologies offer the potential for coal power production with near-zero emissions and limited environmental impact While ultra-low emission technologies have been, and will continue to be, demonstrated, R&D currently focuses on improving performance efficiencies and reducing costs through technology advances Further large-scale projects such as FutureGen and those demonstrated in CCPI are needed to gain acceptance of clean coal technologies’ ability to achieve near-zero emissions. 12-11-2007 Slanders EPA Region 4, Atlanta, GA 13 12-11-2007 Slanders EPA Region 4, Atlanta, GA 14 12-11-2007 Slanders EPA Region 4, Atlanta, GA 15 Technology Improvements to Meet Challenges 12-11-2007 Slanders EPA Region 4, Atlanta, GA 16 Polk Emissions Improvements Emissions (pounds per million Btu) 2.5 2.07 2 SO2 1.5 1.2 0.6 to 1.2 NOx 1 0.47 0.5 0.07 (15 ppm) 0.1 0 Older Coal Plant 12-11-2007 Slanders Fleet Avg. TECO CCT Plant Older Coal Plant EPA Region 4, Atlanta, GA Fleet Avg. TECO CCT Plant 17 Wabash Emissions Improvements Emissions (pounds per million Btu) 3.1 3 SO2 2 NOx 0.8 1 0.15 0.1 0 Before CCT 12-11-2007 Slanders After CCT Before CCT EPA Region 4, Atlanta, GA After CCT 18 National SO2 Emissions 1989-91 12-11-2007 Slanders Source: http://www.epa.gov/castnet EPA Region 4, Atlanta, GA 2004-06 19 DOE Budget by Organization 12-11-2007 Slanders EPA Region 4, Atlanta, GA 20