Transcript Document

Molecular Design and Synthesis – Coordination Chemistry
Subjects for Master Thesis
Wavelength (nm)
550
600
650
700
750
800
850 900 950
c
Intensity (a.u.)
E'
A1'
-1
 (L.mol .cm )
30
-1
20
b
a
d
e
f
10
g
E"
18000
15000
A1'
12000
-1
0
30000
Wavenumber (cm )
28000
26000
24000
22000
20000
18000
-1
wavenumber (cm )
• Lanthanide-containing liquid crystals
(lanthanidomesogens)
• EXAFS-study of the local coordination
environment of uranyl complexes
• Synthesis and spectroscopy of lanthanidedoped nanocrystals
• Luminescent ionogels
• Chemical study of anti-tumoractive
polyoxometalate complexes
• Synthesis and biological applications of
lanthanide-containing polyoxometalates
U= Oax
1.0
• Photochemistry and spectroscopy of uranyl
complexes
FT
U-Oeq
0.5
U-N
• Task-specific ionic liquids for solubilizing
metal oxides
MS U-Oax
+ MS N-Oeq
U-Odist
• Oxidation reactions with tetravalent cerium in
ionic liquids
+ MS Odist
0.0
0
1
2
3
4
R+[Å]
S
O
O
N
O
N
O
Eu
O
N
F3C
CN
O
CN
N
H
O
O
CN
3
A
B
C
5
6