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FORENSIC CHEMISTRY
AS SCIENTIFIC AND EDUCATIONAL SPECIALISATION
AT THE JAGIELLONIAN UNIVERSITY
Paweł Kościelniak
JAGIELLONIAN UNIVERSITY, Faculty of Chemistry
INSTITUTE OF FORENSIC RESEARCH
Cracow, Poland
Jagiellonian University
(1364)
Jagiellonian University
Faculty of Law and Administration
Collegium Medicum
Faculty of Philosophy
Faculty of History
Faculty of Philology
Fac. of Medicine & Div. of Dentistry
Fac. of Math., Phys. and Comp. Sciences
Fac. of Pharmacy & Div. of Medical Anal.
Faculty of Biology and Earth Sciences
Faculty of Health Care
Faculty of Biotechnology
Faculty of Chemistry
Fac. of Management and Social Comm.
Fac. of Internat. and Political Studies
JU in numbers (2006)
Students
Total:
44 214
Regular studies:
27 653
Extramural studies:
15 552
External studies:
1 099
Postgraduate studies:
2 091
Academic staff
total:
6 710
academic teachers:
3 605
professors:
486
doctores habilitati:
503
Faculty of Chemistry
Karol Olszewski (1846-1915)
Chemist, physicist and expert of low
temperatures; the first scholar who liquefied
nitrogen and oxygen; he also discovered a
method of hydrogen liquefaction and
constructed machinery for that purpose,
which enabled him to reach the then-lowest
world temperature, -225 C.
1950-52
Faculty of Chemistry
Department of Inorganic Chemistry
Department of Organic Chemistry
Department of Analytical Chemistry
Department of Physical Chemistry
Department of Chemical Physics
Department of Theoretical Chemistry
Department of Crystal Chemistry
Department of Chemical Technology
Department of Chemical Education
Department of Computational Methods in Chemistry
DEPARTMENT OF
ANALYTICAL CHEMISTRY
(25)
LABORATORY
FOR
FORENSIC CHEMISTRY
(11)
GROUP OF
CHEMOMETRICS
(4)
GROUP OF ANALYTICAL
FLOW TECHNIQUES
(10)
Pure analytical chemistry & Flow Analysis
Optimization of analytical conditions
Development of calibration methods
Examination of interference effects

Analytical techniques
Atomic absorption spectrometry
Atomic fluorescence spectrometry
UV/VIS spectrophotometry
Electrochemical techniques
Capillary electrophoresis
Liquid chromatography

Forensic Chemistry
Development of analytical methods and procedures for forensic purposes
EDUCATIONAL STRUCTURE
Chemistry
undergraduate study
graduate study
Organic
synthesis
Catalysis
Forensic
chemistry
Institute of Forensic
Research
It is the only research centre of its kind in
Poland, working under the aegis of the
Ministry of Justice.
Its statutory duties include:
- research in the field of forensic
science,
- preparation of expert opinions for
courts and public prosecutor's
offices in criminal and civil cases,
- the development and promotion of
the forensic sciences.
The Institute carries out expert
investigations and research in the following
units:
1929





Department of Forensic Toxicology
Department of Criminalistics
Department of Road Accidents
Department of Forensic Psychology
Forensic Genetics Section
MILESTONES
before 1997 – informal collaboration between FCh JU and IFR
1997 – common idea of educational module called „forensic chemistry” as one of
objectives of the TEMPUS project „Transformation of University Chemistry
Studies at the Jagiellonian University”(TRUCS),
1997/98 – formal introduction of this module to the chemical study at FCh JU
2000 – establishment of the Laboratory for Forensic Chemistry at FCh JU as one of
the objectives of the TEMPUS project „National Training Program for Forensic
Science Experts” (NATFOSE),
2001 – formal agreement between FCh JU and IFR in the field of forensic chemistry
2000/2001 – modification of the curriculum of module „forensic chemistry”
from 2002 – teaching of „forensic chemistry” according to new curriculum
LABORATORY FOR FORENSIC CHEMISTRY
founded in 2000
- system for capillary electrophoresis
(PrinCe 550 CSD, Prince)
- HPLC system (LaChrom, Merck)
- atomic fluorescence spectrometer with
the flow system for hydride generation
(AFS 230, Beijing Haiguang Instrument Co.)
- system for microwave digestion
(MARS 5X, CEM),
- audiovisual equipment (video-projectors,
digital photo-cameras, video-camera,
video-recorders)
Sem.
No. of hours
Subject
lectures
VI
seminars
total
Electronics and automatics
30
30
Optional
60
60
90
90
Total
Electronics and automatics
VII
classes
60
60
Advanced analytical chemistry
45
Chemometrics and biometrics
30
Analysis in forensic chemistry
15
15
Radiometric analysis
30
30
Toxicology
30
30
Flow analysis
15
15
Optional
60
60
Total
225
45
15
60
15
45
300
Sem.
No. of hours
Subject
lectures
VIII
classes
total
Radiometric analysis
45
Forensic toxicology
60
15
75
60
15
90
Criminalistics
Low aspects of the forensic
expert work
15
Optional
45
15
15
Student’s report
30
60
Total
100
Laboratory for master thesis
30
60
100
100
450
Seminar for master thesis
IX
i
X
seminars
315
450
60
60
Clinical toxicology
15
15
GLP
15
15
Optional
60
60
Total
90
450
60
600
LABORATORY CLASSES
Place
No.
1
Toxicological analysis of drugs
IFR
2
Ethanol- selected toxicological and analytical aspects
IFR
3
Application of the GC/MS method to analysis of medicines in biological
materials
IFR
4
Determination of inorganic toxicants in biological material
IFR
5
Chemical examinations of car paints
IFR
6
Chemical examinations of fibers
IFR
7
Chemical examinations of gun-shot residuals
IFR
8
Chemical examination of inks by TLC
IFR
9
Chemical analysis of inks by CE
JU
10
Determination of Se and As in biological materials by AFS-HG
JU
11
Comparative examination of psychotropic medicines by HPLC and CE
JU
12
Profiling of drugs – physicochemical and chemometric examination
JU
RESERCH SUBJECTS
Subject
Examination of questioned documents on the basis of
identification of chemical composition of inks
Development of analytical procedures for determination of
psychotropic drugs, particularly of phenotiazines and
tricyclic antidepressants
Development of analytical procedures for determination of
selenium and arsenic in biological materials (blood, urine,
hair, body tissues)
Analytical method
FCh JU
IFR
CE
FTIR, TLC,
RAMAN
HPLC, CE
GC/MS
AFS, AAS
UV/VIS
Identification and discrimination of car traces (paint, oil) physicochemical and chemometric examinations
ASA
FTIR, XRF
Profiling of amphetamine - physicochemical and
chemometric examinations
TLC
GC/MS
PUBLICATIONS
- J. Zięba-Palus, P. Kościelniak, An Analysis of the Similarity of Motor Oils on the Basis of Their Elemental
Composition, Forensic Sci. Int., 112, 81-90 (2000).
- J. Zięba-Palus, P. Kościelniak, M. Łącki, Differentiation of Motor Oils on the Basis of Their IR Spectra with
Application of the Cluster Analysis, J. Molec. Struct., 596, 221-228 (2001).
- J. Zięba-Palus, P. Kościelniak, M. Łącki, Differentiation of Motor Used Oils on the Basis of Their IR Spectra with
Application of the Correlation Method, Forensic Sci. Int., 122, 35-42 (2001).
- K. Madej, Capillary Electrophoresis as a New Tool in Forensic Toxicological Analysis, Problems of Forensic
Sciences, 48, 31-52 (2001).
- R. Wietecha, R. Stanaszek, Determination of Morfine, Codeine and 6-monoacetylomorphine in Hair of Addicted
Persons, Problems of Forensic Sciences, 49, 38-45 (2002).
- J. Mania, K. Madej, P. Kościelniak, Inks Analysis by Capillary Electrophoresis – Analytical Conditions
Optimisation, Chem. Anal., 47, 585-594 (2002).
- P. Kościelniak, W. Piekoszewski, (ed.) Forensic Chemistry (in Polish), IFR, Kraków 2002.
- Z. Chłobowska, E. Chudzikiewicz, P. Kościelniak, W. Piekoszewski, A. Stolarz, Application of Gas
Chromatography with NPD Detection to the Analysis of Tricyclic Antidepressants in Blood, Chem. Anal.
48, 255-263 (2003).
PUBLICATIONS
- J. Zięba-Palus, P. Kościelniak, Differentation Between Used Motor Oils on the Basis of Their IR Spectra for
Criminalistic Purposes, The Forensic Scientist, 1, 23-28 (2003).
-
R. Wietecha, P. Kościelniak, T. Lech, M. Rymanowski, Determination of Selenium in Human Blood Using
Atomic Fluorescence Spectrometry, Problems of Forensic Sciences, 52, 21-30 (2003).
-
Z. Chłobowska, Cz. Świegoda, P. Kościelniak, W. Piekoszewski, Identification and Determination
of Flunitrazepam and Its Metabolites in Blood by Gas Chromatography, Chem. Anal., 49, 71-77 (2004).
-
R. Wietecha, P. Kościelniak, T. Lech, T. Kielar, Simple Method for Simultaneous Determination of Selenium
and Arsenic in Human Hair by Means of Atomic Fluorescence Spectrometry with Hydride Generation
Technique, Microchim. Acta, 149, 137-144 (2005).
-
K. Madej, M. Woźniakiewicz, M. Kała, Method for Screening and Quantification of Seven Phenothiazines in
Whole Blood Samples by Non-aqueous Capillary Electrophoresis, Chromatographia, 61, 259-263 (2005).
-
K. Madej, M. Kała, M Woźniakiewicz Application of Liquid Chromatography and Non-aqueous Capillary
Electrophoresis to the Determination of Phenothiazines in Six Cases of Poisonings: Comparative Analysis,
Chromatographia, 62, 533-538 (2005).
-
R. Wietecha, J. Dobrowolska, P. Kościelniak, Simple Analytical Method for Determination of Selenium and
Arsenic in Human Urine, 39, 2787-2796 (2006).
PROJECTS
TEMPUS program, project no. 12236/97 „Transformation of University
Chemistry Studies at the Jagiellonian University” (TRUCS); 1997-2000
TEMPUS program, project no. 13514/98 „National Training Program for Forensic
Science Experts” (NATFOSE); 1998-2001
LEONARDO DA VINCI program, project PL/01/A/Exd/14054 „Vocational Training
System in Forensic Sciences - Exchange of Educational Experiences”
(VITSFOS-E); 2001-2003
NATO program, project no. PST.CLG.980067 “Sensors for Chemical Weapons
Detection Based on Molecularly Imprinted Polymers”; 2004-2005
TEMPUS program, project no. 41105 - 2006
„Education System In Forensic Sciences for the Republic of Macedonia”
(EDUFORMAK); 2007-2009
Ph.D. STUDY
Student
Subject
Defense
Renata Wietecha
Development of the analytical procedure for the selenium
determination in human tissues by the AFS-HG technique
2004
Rafał Borusiewicz
Examination of arson traces
2004
Joanna Mania
Examination of inks by capillary electrophoresis
2005
Małgorzata Świst
Profiling of drugs
2005
Maria Pawluk-Kołc
Classification and discrimination of glass traces
2005
Agnieszka Skulska
Profiling of drugs
2006
Agnieszka Zakrzewska
Profiling of drugs
2006
Maciej Kochanowski
Analytical examination of illicit drugs
2007
Michał Woźniakiewicz
Analysis of psychotropic drugs by HPLC and CE
2008
Justyna Dobrowolska
Elemental analysis of biological materials
2008
Jakub Mielczarek
Classification and discrimination of car paint traces
2008
FUTURE
•
to make specialisation in forensic chemistry more and more attractive
(e.g. to organise „artificial” trials, to prepare new interactive classes with
the use of audiovisual and computer tools),
•
to organise and open post-graduate study in the field of forensic
chemistry,
•
to organise and open the „forensic” courses in the frame of „virtual
university”
•
to increase the scientific level of the forensic research performed,
•
to expand the collaboration with national and foreign forensic/analytical
centres
„FORENSIC CHEMISTRY” IN NUMBERS
• first and still only one activity of this kind in Poland
• 2 years of studying (4th and 5yh year of chemical study)
• 10 years of activity (since 1997/78)
• 12 - 14 students a year
• 31 publications (with the student contribution)
• 34 master’s theses
• 82 graduates
• a lot of students interested in the subject every year