Transcript Document

234th ACS National Meeting
Boston, MA
August 19-23, 2007
Chemical Compliance Analytical System
C-CAS
Chemical Compliance Systems, Inc.
706 Route 15 South, Suite 207 • Lake Hopatcong, NJ 07849
973-663-2148 • (fax) 973-663-2378
www.chemply.com
“Smart” Inventory System Primary Databases
Chemical
Cross-Reference
Dictionary
Product
Container
Data
Regulatory
List of Lists
Chemical
Hazard Data
(H/S/E
“SMART”
INVENTORY
SYSTEM
Additional
Data &
Criteria
MSDS
Index &
Images
CCS
Sample Chemical Cross-Reference Database
CAS No.
Name
3734-97-2
78-53-5
3734-97-2
106-87-6
101-25-7
CHIPMAN 6199
CHIPMAN 6200
CHIPMANR-6, 199
CHISSONOX 206 MONOMER
CHKHZ 18
78-67-1
80-17-1
CHKHZ 57
CHKHZ 9
5675-7
87-86-5
7782-50-5
74-87-3
108-90-7
12789-03-6
75-00-3
3691-35-8
76-06-2
7647-01-0
1336-36-3
7782-50-5
12789-03-6
74-87-3
76-06-2
79-11-8
78-95-5
107-14-2
532-27-4
CHLOMYCOL
CHLON
CHLOOR (DUTCH)
CHLOOR-METHAN (DUTCH)
CHLOORBENZEEN (DUTCH)
CHLOORDAAN (DUTCH)
CHLOORETHAAN (DUTCH)
CHLOORFACINON (DUTCH)
CHLOORPIKRINE (DUTCH)
CHLOORWATERSTOF (DUTCH)
CHLOPHEN
CHLOR (GERMAN)
CHLOR KIL
CHLOR-METHAN (GERMAN)
CHLOR-O-PIC
CHLORACETIC ACID
CHLORACETONE (FRENCH)
CHLORACETONITRILE
CHLORACETOPHENONE
CAS No.
78-67-1
CAS No.
80-17-1
Synonyms
2,2’-AZOBIS(2-CYANOBUTANE)
2,2’-AZOBIS(2-METHYLPROPIONITRILE)
2,2’-AZOBIS(ISOBUTYRONITRILE)
2,2’-AZOBIS(2-METHYLPROPANENITRILE)
2,2’-AZODIISOBUTYRONITRILE
2,2’-DICYANO-2,2’-AZOPROPANE
2,2’-DIMETHYL-2,2’-AZODIPROPIONITRILE
ACETO AZIB
AIBN
AIVN
ALPHA,ALPHA’-AZOBIS(ISOBUTYRONITRILE)
ALPHA,ALPHA’AZOBISISOBUTYLONITRILE
ALPHA,ALPHA’-AZODIISOBUTYRIC ACID DINITRILE
ALPHA,ALPHA’-AZODIISOBUTYRONITRILE
AZDH
AZDN
Synonyms
AZOBISISOBUTYLONITRILE
BENZENESULFOHYDRAZIDE
AZOBISISOBUTYRONITRILE
BENZENESULFONIC ACID, HYDRAZIDE
AZODIISOBUTYRONITRILE
BENZENESULFONIC HYDRAZIDE
AZODIISOBUTYRONITRILE (DOT)
BENZENESULFONOHYDRAZIDE
CHKHZ 57
BENZENESULFONYLHYDRAZINE
GENITRON
CELOGEN BSH
GENITRON AZDN
CHKHZ 9
GENITRON AZDN-FF
GENITRON BSH
N,N’-BIS(2-CYANO-2-PROPYL)DIAZENE
HYDRAZIDE BSG
PIANOFOR AN
NITROPORE OBSH
POLY-ZOLE AZDN
PHENYLSULFOHYDRAZIDE
POROFOR 57
PHENYLSULFONYL HYDRAZIDE
POROFOR N
POROFOR BSH
POROPHOR N
POROFOR CHKHZ 9
PROPANENITRILE, 2,2’-AZOBIS(2-METHYL)POROFOR-BSH-PULVER
PROPIONITRILE, 2,2’-AZOBIS(2-METHYL)UN 2952 (DOT)
VAZO
VAZO 64
CCS
Sample Product Container Data
BAR CODE
LOCATION
QUANTITY
MANUFACTURER
MFR. DATE
DATE RCVD.
EXP. DATE
TRADE NAME
ITEM NO.
UNIT OF ISSUE
PHYSICAL STATE
SIZE
STORAGE CODE
DISPOSAL CODE
CCS
Sample of Regulated Chemical Lists
A1
C1
D1
ACGIH TLV Chemicals
California—Title 22 Section 12201 Subdivision A
USDOT Hazardous Materials—Title 49 CFR Part 172.101
D2
USDOT Optional Hazardous Materials—Title 49 CFR Part 172.102
E1
E2
E3
E4
I2
N1
EPA: List of Extremely Hazardous Substances
EPA: List of Toxic Chemicals Section 313 SARA
EPA: List of Hazardous Substances and Reportable Quantities
EPA: Hazardous Wastes from the P and U Lists
IARC: Human Carcinogens
NIOSH: Pocket Guide to Chemical Hazards
N3
NFPA 325M
N4
O1
O2
O3
O4
O5
P1
S1
S2
NTP: 4th Annual Report on Carcinogens
OSHA: Table Z-1
OSHA: Table Z-2
OSHA: Table Z-3
OSHA: Table Z-4
OSHA: Human Carcinogens
NJDEP Prohibited and Restricted Use Pesticide List
Alaska: Designated Toxic and Hazardous Substances
California: Permissible Exposure Limits for Chemical Contaminants
78-67-1
S3
Florida Substance List
S4
S5
Illinois Toxic Substance List
Kansas: Section 302/313 Chemical List
SB
S6
Massachusetts Substance List
S7
S8
Minnesota List of Hazardous Chemicals
Missouri: Employer Information-Toxic Substance List
S9
New Jersey: Right to Know Hazardous Substance List
SA
North Dakota: List of Hazardous Chemicals and Reportable Quantity
SB
Pennsylvania: Hazardous Substance List
SC
SD
SE
SF
Rhode Island: Hazardous Substance List
Texas: Hazardous Substance List
West Virginia: Hazardous Substance List
Wisconsin: Toxic and Hazardous Substances
S3
N3, S3, S6
D2, S9
CCS
Sample of Regulated Chemical Lists Content
American Conference of Governmental
Industrial Hygienists (ACGIH)
TLVs & BEIs
CAS No.:
Chemical Name:
Primary:
1998 ADOPTION:
Change notice:
Adopted value:
TWAppm:
TWAmg/m3:
STELppm:
STELmg/m3:
CEILppm:
CEILmg/m3:
Skin Notation:
Carcinogen Cat.:
BEI:
Molecular Weight:
TLVBASIS:
LISTID:
UTIL:
COMMENTS:
75-07-0
Acetaldehyde
X
(OSHA 200)
(OSHA 360)
25
45
A3
44.05
Irritation
001
F
DOT Hazardous Material Table
49 CFR 172.101
CASNO:
CHEMNAME:
Shipping Name:
Symbols:
Hazard Class:
ID No.:
Packing Group:
Label Codes:
Special:
Exceptions:
NonBulk:
Bulk:
Passenger:
Cargo:
Vessel Stowage Loc:
Other:
LISTID:
UTIL:
COMMENTS:
75-07-0
Acetaldehyde
Acetaldehyde
3
UN1089
I
FLAMMABLE LIQUID
A3, B16, T20, T26, T29
one
201
243
Forbidden
30 L
E
025
F
CCS
Comprehensive Chemical Hazard
Evaluation Criteria
ACUTE HEALTH
LD50 (O/D)
S/E Irritation
pH
TLV
FIRE
Vapor Density
Boiling Point
CHRONIC HEALTH
LC50
Stench
IDLH
PEL
Carcinogenicity
Reproduction Effects
Organ Effects (Neurotoxicity)
Bioconcentration Factor
SPECIAL
Radioactive
Water Reactive
Oxidizer
Corrosive
REACTIVITY (NFPA)
Explosivity
Shock Sensitivity
Stability
Heat/Pressure Sensitivity
ENVIRONMENTAL (AIR-WATER-SOIL)
Vapor Density
Odor Index
Fish LD50
Specific Gravity
Volatilization
Vapor Pressure
Water Solubility
Adsorptivity
Biological Exposure Index
Biological Oxygen Demand (BOD)
Chemical Oxygen Demand (COD)
Total Oxygen Demand (TOD)
Persistence
Groundwater Mobility Factor
Hydrolysis
Ambient Aquatic Life Advisory Concentration -AALAC
Photolysis
Maximum Contaminant Level-MCL
Biodegradation Maximum Contaminant Goal-MCLG
CCS
Complex & Confusing “Green” Criteria Options
PHYSICAL/
CHEMICAL
Kow LEL UEL
Flashpoint
Acute
Vapor Pressure
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LD50
Inhalation
Solubility
Cancer Chronic
Specific Gravity
STEL Irritants
Teratogens
Henry’s Law
Poisons
TLV Organ Effects
REL Sensitizers Mutagenicity
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?
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Fire
Customer
CCS
Integrated Biobased Score Scheme (BBP-CAS)
Regulated under Air
REGULATORY
SCORE
Regulated under Water
Regulated under Soil
(0-100%)
_____% A.W.
Regulated under Human Health
Regulated under Safety
FINAL
BIOBASED
GRADE
(0 - 100%)
Plant Score
BIOMASS
SCORE
(0-100%)
Forest Score
Wood
Wood Residues
Fibers
Residues
Animal Score
Parts
Fats, Oils, Greases
Residues
Marine Score
Parts
Residues
Waste Score
Wood Waste
Animal Waste
Plant Waste
Marine Waste
_____% A.W.
ECONOMIC
PERFORMANCE
SCORE
First Cost
Availability
Renewability
Performance
Jobs
Savings
Costs for Purchase
Installation/Preparation
Product Manufacture
Future Cost
Maintenance
Repair
Replacement
Residual Value
Life Cycle Cost
Environmental
Health
Safety
Regulatory
Biomass
(0-100%)
_____% A.W.
Grains
Other Agricultural
Aquatic
Grasses
CCS
Integrated Biobased Score Scheme (BBP-CAS)
Air Score
Persistence
Exposure
Toxicity
Long-Term Effects
Water Score
Persistence
Exposure
Toxicity
Long-Term Effects
Soil Score
Persistence
Exposure
Toxicity
Long-Term Effects
ECOLOGICAL
SCORE
(0-100%)
_____% A.W.
FINAL
BIOBASED
GRADE
(0 - 100%)
HEALTH
SCORE
Acute Health Score
Oral LD50
Dermal LD50
IDLH
STEL/Ceiling
Inhalation LC50
Eye Irritation
Odor Threshold
Chronic Health Score
Reproductive Effects
Carcinogenicity
RfC
RfD
Radioactivity
Sensitizer
Neurotoxicity
TLV
(0-100%)
_____% A.W.
SAFETY
SCORE
(0-100%)
_____% A.W.
Fire Score
Special Score
Reactivity Score
TOXICITY - AIR
(V.P.  LC50)  BCF
LONG-TERM EFFECTS - AIR
Global Warming Potential
Ozone-Depleting Potential
Smog
Acidification
TOXICITY-WATER
Fish LC50
Daphae LC50
Green Algae EC50
(Solubility  W-LC50)  BCF
LONG-TERM EFFECTS - WATER
Eutrophication
Theoretical Oxygen Demand
TOXICITY - SOIL
(Koc  O-LD50)  BCF
14-day Worm LC50
LONG-TERM EFFECTS - SOIL
Groundwater Mobility Factor
CERCLA RQ
Flammability
Radioactivity
Oxidizer
Water-Reactive
Corrosive
FLAMMABILITY
Flash Point
Boiling Point
Explosivity
CCS
MSDS No. 4
Centari® Acrylic Enamel Tints and
Miscellaneous Factory Packaged Colors
SECTION 2. COMPOSITION INFORMATION ON INGREDIENTS
INGREDIENTS
1,2,4-trimethyl benzene
2,2,4-trimethyl-1,3-pentanediol
monoisobutyrate
2,2,4-trimethylpentane
CAS #
95-63-6
25265-77-4
VAPOR PRESSURE
[email protected]°C
0.0
EXPOSURE LIMITS
A 25.0 ppm, O 25.0 ppm
A None, O None
540-84-1
None
A 300.0 ppm, O 500.0 ppm
SECTION 3. HAZARDS IDENTIFICATION
Other Potential Health Effects in addition to those listed above:
ACETONE
The following medical conditions may be aggravated by exposure: lung disease, eye disorders,
skin disorders. Overexposure may cause damage to any of the following organs/systems: blood,
central nervous system, eyes, kidneys, liver, respiratory system, skin.
SECTION 11. ADDITIONAL INFORMATION
767A™ Acrylic polymer-B, Alkyd resin, Aromatic hydrocarbon-A, Azxo yellow pigment, Butyl
acetate, Ethylbenzene(2.1-5.2%*@), Methyl ethyl ketone, Naphthalene(0.0-0.2%*@),
Toluene(12-12%*@), Vm&p naphtha, Xylene(16-19%*@)
GAL WT: 8.20 WT PCT SOLIDS: 46.82 VOL PCT SOLIDS: 37.99
SOLVENT DENSITY: 7.02 VOC LE: 4.4 VOC AP: 4.4
FLASH POINT: 20°F to below 73°F H:2 F:3 R:0 OSHA STORAGE:1B
TSCA STATUS: In Compliance PHOTO-CHEMICALLY REACTIVE: YES
No 817A Listed
CCS
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(R-CPD)
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20+ Agents
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•
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•
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•
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•
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— Use
— Chemical
— Conditions
— Containers
a
STORAGE
RECOMMENDATIONS
— Container
— Conditions
— Distances
— HSASa Variables
HSAS = Homeland Security Advisory System
CCS
Incompatible Chemical Database
(CCS Published Book)
CHEMICAL
CLASS
CHEMICAL
INCOMPATIBLE
CHEMICAL
I.C.
CLASS
INTERACTION
HAZARD
Corrosives
Acetic Acid
Nitric Acid
Chlorine
Hydrogen Peroxide
Acetylene
Aluminum Powder
Oxidizer
Flammable
Metal
Explosion
Explosion
Spontaneous Fire
Flammables
Acetone
Benzene
Carbon Disulfide
Chloroform
Chlorine
Potassium
Carcinogen
Corrosive
Flammable
Explosion
Explosion
Violent Explosion
Reactives
Nitrotoluene
Nitroethane
Acrylonitrile
Sulfuric Acid
Hydrocarbons
Bromine
Corrosive
Combustible
Corrosive
Explosion
Explosion
Explosion
Products
Toilet Bowl Cleaner
Bleach
Paint Solvent
Metal Powders
Ammonia
Chloroform
Metals
Product
Carcinogen
Explosion
Poisonous Gas
Explosion
CCS
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Extreme
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Radioactives
Explosives
Shock Sensitives
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Priority Pollutants
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Security
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European Community
CCS
CPSC Specialty Regulated Substances
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DEA Precursor Chemicals
DOC Export Restrictions
EU Black/Gray Lists
IATA Air Transport Forbidden
Precursor
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Sources
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CCS
Chemical Homeland Security System (C-HoSS)
Centralized and Relational Databases
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or Existing System
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(PS-CAS)
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Locations & Types
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Data
Sources
CCS
MACS Integration Into Facility ISO 14001 EMS
POLICY
OBJECTIVES/
GOALS
TARGETS/
REQUIREMENTS
ASPECTS/
IMPACTS
MANAGEMENT
PROGRAM
RESPONSIBILITIES
SCHEDULE
TRAINING
DOCUMENTATION
Multi-functional DoD Green Procurement Program Fulfillment
Munition/Nonmunition P2 and Regulatory Compliance
Munition/Nonmunition Security
By Demil Operation
By Specific Range & Operation
For Procurement—Hazard Acquisition Constraints
Security Incident Prevention
C-HoSS
Plasma Arc
Feedrate
Demil
By Level, Function, Product Type & Restricted Constituents
Within Permit Constraints
By Demil/Range Operation & Regulation
Storage Requirements by Area & Function
Incinerator
Feedrate
Decrease/Increase Acquisition, Usage Releases, Exposures & Compliance
Security Risks, Incidences, First Responder Analyses
Chemical Tracking
(NEW)
Definable by Area, Level, Function, Process, Operation & Regulation
Periodic Interim Status Reports By & Across Module(s)
Integrated Documentation & Validation
TRACS
Hazardous Waste
Simplified by Criteria, Pass/Fail Values
Operation, Process & Area-Specific
GP-CAS
Green Nonmunitions
Within Each Module
Product & Constituent Data by Hazard, Area, Operation & Process
Imaged Documents
Decreased Incidence Likelihood & Severity
MEASUREMENTS
Within Each Module—Hazards & Compliance
MANAGEMENT
REVIEW
C-CAS
Risk Module
Dispersion
No Hierarchical Data Calls
“Broad Picture” of Operations, Processes, Areas & Functions
Integration of Munition, Nonmunition & Security Analyses & Compliance
EMERGENCY
PREPAREDNESS
RECORDKEEPING
MACS-1
Chemical Security
(NEW)
Within Each Module
Annual Executive Review & Interim Detailed Reports
MACS-3
Theoretical
Compliance Analyses
G-MACS
Green Munitions
MACS-2
(Ranges)
CCS
For information,
contact:
Dr. George Thompson
[email protected]
973-663-2148
Chemical Compliance Systems, Inc.
706 Route 15 South, Suite 207 • Lake Hopatcong, NJ 07849
973-663-2148 • (fax) 973-663-2378
www.chemply.com