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ALTERNATIVE FUELS AND THEIR APPLICATION IN URBAN TRANSPORT

(PART 2)

Eddy Versonnen

[email protected]

KdG University College Antwerp

GREENHOUSE EFFECT

AIR QUALITY THE GREENHOUSE EFFECT - GREENHOUSE GASES - DEVELOPMENT OF ECONOMICAL CARS

-

- USE OF ALTERNATIVE FOSSIL FUELS - USE OF RENEWABLE FUELS WIND ENERGY AND SOLAR ENERGY HYDROGEN AS AN ENERGY CARRIER

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

USE OF RENEWABLE FUELS:

Experiments with bio-energy

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

USE OF RENEWABLE FUELS:

Basic principle: Make fuels out of bio-mass • Mostly bio-mass from plants • • Plants store solar-energy by photosynthesis under the physical form of carbon compounds In theory renewable fuels are CO 2 neutral: the CO 2 caused by the combustion of bio-fuels has been taken out of the air by the plants while they were growing • In reality some energy is needed for the production of renewable fuels out of bio-mass, but the use of it surely makes a CO 2 reduction possible (watch out: fertilizing leads to N 2 O!)

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

USE OF RENEWABLE FUELS:

• • • Renewable fuels (wood) are the first fuels used by men.

Fossil fuels were formed out of bio-mass a few million years ago. Different kinds of Renewable Fuels: – Biodiesel – Pure Plant Oil (PPO) – Bio-methanol – Bio-ethanol – Biogas – Bio-methane – Bio-Hydrogen – ...

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

USE OF RENEWABLE FUELS:

• • ADVANTAGES: • Renewable A lot of CO 2 reduction Liquid bio-fuels are easy to handle • • Some bio-fuels can be used in conventional combusting engines with small adaptations ‘Revival’ of the European agriculture

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

USE OF RENEWABLE FUELS:

DISADVANTAGES: • • • • Different studies preconceive that there is not enough cultivated land available to produce enough renewable fuels. An ethical question: use the available cultivated land for the production of food or for the production of energy Not necessary sustainable and renewable energy: for example cutting down the rain forest None or hardly any impact on the poisonous emission components

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

USE OF RENEWABLE FUELS:

Bio-Diesel (Plant Oils)

* FAME: Fatty Acid Methyl Ester  Obtained from Rape Seed, Soybean, ..

* World Production: 5 400 000 tons (4 000 000 in EUROP) * EU Commission: Blends of:  2010: > 5,75% Bio-Diesel  2020: > 10% Bio-Diesel with Fossil Diesel * Using Bio-Diesel substantially reduces Emissions of  Unburned Hydrocarbons (CH)  Carbon Monoxide (CO)   Sulphate Particular Matter * Emissions of NO X increases

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

USE OF RENEWABLE FUELS:

-

Biodiesel (Plant Oils)

* Can be used in Conventional Diesel Engines * Bio-Diesel Blends higher than B20 can cause problems with Natural Rubber Components  Damage to Seals and Hoses of the Fuel System

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

USE OF RENEWABLE FUELS:

Biodiesel: PPO (Pure Plant Oils)

* PPO tends to solidify at low temperature * Vehicle Modification to heat the fuel * 5% to 8% less Power * If PPO gets mixed with the lubricating Oil  It reacts with the Oil  This creates “Sludge”  Change Oil more often

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

USE OF RENEWABLE FUELS: -

Bio-Ethanol Conventional Bio-Ethanol

* Obtained from Sugar or Starch in Crops and other Agriculture Produce  Grain Starches   Sugar beats Maïs * 30% CO 2 Reduction

Cellulosic Bio-Ethanol

* Derived from any Cellulose or other Renewable Bio-mass  Forrestary Waste  Municipal Waste * 80% CO 2 Reduction

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

USE OF RENEWABLE FUELS:

Bio-Ethanol

* World Production: 40 000 000 tons  Mostly in Brazil and USA  1 500 tons in Europe * EU Commission: Blends of  2010: > 5,75% Bio-Ethanol  2020: > 10% Bio-Ethanol with Gasoline

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

USE OF RENEWABLE FUELS:

Bio-Ethanol

* All Gasoline Vehicles can operate on gasoline/ethanol blends up to 10% Ethanol  18 - 29% CO 2 Reduction (Compared with Gasoline) * E5: 5% Bio-Ethanol in Gasoline (EU) * E10: 10% Bio-Ethanol in Gasoline (USA) * E25: 25% Bio-Ethanol in Gasoline (Brazil)

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

USE OF RENEWABLE FUELS:

Bio-Ethanol FFV (Flexible Fuel Vehicle)

* Capable of operating on  85% Bio-Ethanol and 15%Gasoline  Or any Blend in between * E85: 85% Bio-Ethanol in Gasoline (USA, Sweden) * With 113 Octane Rating: E85  Is the highest Performance Fuel on the Market  Keeps High-Compression Engines running smoothly

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

GREENHOUSE EFFECT

AIR QUALITY THE GREENHOUSE EFFECT - GREENHOUSE GASES - DEVELOPMENT OF ECONOMICAL CARS - USE OF ALTERNATIVE FOSSIL FUELS

-

- USE OF RENEWABLE FUELS WIND ENERGY AND SOLAR ENERGY HYDROGEN AS AN ENERGY CARRIER

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

WIND ENERGY AND SOLAR ENERGY:

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

WIND ENERGY AND SOLAR ENERGY:

• • Advantages: • • No CO 2 emission No emissions Inexhaustible No geographical concentration Disadvantages • • No constant production: no solar energy when the sun is not shining, ...

Not directly usable for transport applications • Hard to store

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

WIND ENERGY AND SOLAR ENERGY:

- Battery - Electric

* Energy Storage in the Chemical Energy of the Batteries.

* Zero Emission: no Emissions while being driven.

* Disadvantages:  Costs  Speed  Driving Range

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

WIND ENERGY AND SOLAR ENERGY:

- Battery - Electric

* Lead - Acid Batteries: Reduced Capacity if discharged beyond 75% on regular basis.

* Better Choice but more expensive are:  NiMH Batteries  Lithium Batteries

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

WIND ENERGY AND SOLAR ENERGY:

- Battery - Electric

* New developments:  ELLICA (Japan)  Lithium Batteries    0 to 100 km/h in 4 s Maximum Speed: 400 km/h Autonomy: 320 km

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

WIND ENERGY AND SOLAR ENERGY:

- Solar Cars

* Electrical Vehicle powered by Solar Panels * Not a practical Form of Transportation

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

GREENHOUSE EFFECT

AIR QUALITY THE GREENHOUSE EFFECT - GREENHOUSE GASES - DEVELOPMENT OF ECONOMICAL CARS

-

- USE OF ALTERNATIVE FOSSIL FUELS - USE OF RENEWABLE FUELS WIND ENERGY AND SOLAR ENERGY HYDROGEN AS AN ENERGY CARRIER

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

Well to Wheel Efficiency (vehicle km per ha)

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

Hydrogen - The lightest chemical element on earth - Most existing chemical element in the universe It almost never exists as a free element on earth, but most of the time in a chemical bond * Water (H 2 O): chemical bond with oxygen * Fossil fuels: chemical bond with carbon (C) (‘hydrocarbons’, for instance CNG: ~CH 4 )

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

Production methods: ‘Steam reforming’ of CNG In general from any fossil fuel (for example coal) Microbial from waste etc.

B y using Electricity for the Electrolyses of Water (2H 2 O  This Electricity can be produced by: 2H 2 +O 2 ) * Wind Energy * Solar Energy * Nuclear Energy Hydrogen: a new fuel?

- City Gas = coal – gas - Up to 60% Hydrogen

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

H 2 : most energy per kg

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

Zero Emission: - No emission while being driven Two different Applications: - Internal Combustion Engines * Combustion with oxygen from the ambient air 2H 2 +O 2  2H 2 O + heat - Fuel Cells * Electro-Chemical reaction with oxygen from the ambient air 2H 2 +O 2  2H 2 O + e -

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

* Hydrogen is an Energy Carrier, not an Energy Source (like a Battery) * Hydrogen can be stored more easy than Electricity

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

Hydrogen as an energy buffer

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

Hydrogen as an Energy Buffer • Hydrogen can be used to store energy which is provided by door fluctuating sustainable sources as: – Wind Energy – Solar Energy – Hydroelectric Energy Hydrogen as an Energy Carrier • Manageable way to store electricity on board of a vehicle – Vehicles running on hydrogen – Hydrogen as an alternative Energy Carrier for road transport

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

- Hydrogen Internal Combustion Engines

* Slightly Modified Version of the Traditional Gasoline Internal Combustion Engine

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

Hydrogen: Advantages

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

Hydrogen Energy and Fuel Cells Vision of our future by the European Commission European Commission EUR 20719 EN – Hydrogen Energy and Fuel Cells – A vision of our future

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

Hydrogen: Challenges • Storage: H 2 is a very light gas: 14 times lighter than air • 1 kg of Hydrogen contains as much energy as 3.6 litres of gasoline • At ambient pressure and temperature: - 3.3 m³ of Hydrogen contains as much energy as 1 litre of gasoline (a tank with 50 litres of gasoline contains as much energy as 165 m³ of Hydrogen)

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

Hydrogen Storage

* Compressed Gas  350 - 700 bar * Special Tanks reinforced with carbon fibres * 9 litres of compressed Hydrogen (700 bar) is equivalent to 1 litre of gasoline

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

Hydrogen Storage LH 2

* Liquid Gas  -253 °C * A super isolated Tank protects the Liquid Hydrogen from heat * After 3 days a critical pressure is reached * 4 litres of Liquid Hydrogen is equivalent to 1 litre of gasoline

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

Hydrogen: Storage * In solid state, adsorbed in metal hydrides * In the future: Storage in Carbon Nanotubes This will have important repercussions concerning the weight and the volume of the Hydrogen Storage

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

Hydrogen: Challenges * Production: Big investments in sustainable energy are necessary to replace a small fraction of the worldwide oil consumption by Hydrogen * Transport: Same challenges as for Hydrogen storage Advantage: the existing network to transport natural gas can be used for the transportation of Hydrogen. (with small adaptations) * The cost-price must be reduced: – Production cost – Storage (expensive tanks) – Internal Combustion Engines – Fuel Cells

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

Hydrogen: Safety As with any other energy carrier: safety risk Characteristics: * Wide flammability: mixtures between 4 and 75% Hydrogen and air are inflammable (gasoline in air is inflammable between 1 and 7.6%) * Low ignition energy * Much lighter than air * Very diffuse: spreads out very fast * C olourless flame * Few radiant heat

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

Safety: Hydrogen versus Gasoline * Left: Hydrogen powered vehicle * Right: Gasoline powered vehicle After 3 seconds After 1 minutes

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

After 1min30

HYDROGEN AS AN ENERGY CARRIER:

Research at KdG University College • Internal Combustion Engines running on Hydrogen

HCNG

pressure

bus running on a mixture of 20% Hydrogen and 80% CNG, stored under • Opel Combo running on Hydrogen * VW Caddy demonstration vehicle running on Hydrogen • • Future plans concerning Hydrogen • Developing a specialised motor management system Maritime Internal Combustion Engine 6.2l V8 running on Hydrogen Fork-lift truck running on Hydrogen Adaptation of an Internal Combustion Engine to run on Methanol

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

HCNG - Engines

* Hydrogen can be used in different blends with CNG in in Internal Combustion Engines.

* This is an essential step to the 15% HCNG Hydrogen  27% CO 2 based Reduction Transportation of the Future

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

HYDROGEN AS AN ENERGY CARRIER:

Potential of Internal Combustion Engines running on Hydrogen • • • • • • More powerful than Internal Combustion Engines running on gasoline Higher efficiency than Diesel engines The most stringent emission standards achievable, without complicated after treatment of the exhaust gasses Flex-fuel is possible Reduced costs Well known technology Adaptation of existing Internal Combustion Engines for Hydrogen

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen

THANK YOU FOR YOUR ATTENTION

KdG University College - Drive Systems/Hydrogen - Eddy Versonnen