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Module 03 Energy Impacts Ecological impacts of energy generation from non-renewable energy sources in global & local scale and probable mitigation measures Prof. R. Shanthini January 07, 2012 Global scale: greenhouse gas emissions, global warming, and climate change Local scale: acid rain, particulate pollution, thermal pollution and related impact, fresh-water exploitation, and altering land use Non-renewable Energy Source: Fossil Fuels - formed during Carboniferous Period (from about 360 to 286 million years ago). - the land was then covered with swamps filled with vegetations and the water and seas were filled with algae. Prof. R. Shanthini January 07, 2012 http://www.thecosmosphere.com/green-sea-in-china/ Non-renewable Energy Source: Coal - carbonaceous matter was first compressed into peat (a spongy material with 90% water) - peat, when got deeply buried, turned into coal owing to being subjected to increased pressure and temperature - coal is made up of carbon, hydrogen, oxygen, nitrogen and varying amounts of sulphur. Prof. R. Shanthini January 07, 2012 Non-renewable Energy Source: Coal The three main types of coal: Lignite Bituminous Anthracite 30% carbon 45-78% carbon 80-86% carbon softest hardest lowest energy output relatively low amounts of smogcausing sulfur greatest energy output Prof. R. Shanthini January 07, 2012 highest sulfur content and sulfur dioxide is released into the atmosphere. Smog = smoke + fog Non-renewable Energy Source: Coal Smog: Sulfuric - Sulfur smog started occurring in the 1800’s (Industrial Revolution). That was when coal was used for heating and smelting iron. - In the Black Fog of London, 1852, thousands died of smog inhalation. - The two ingredients in this smog, sulfur dioxide and water vapor, don’t become extremely harmful until they chemically react and then bond together. This combination is sulfuric acid. - Smog of this sort is like acid rain, it eats away and vegetation and can erode specific buildings and statues. Prof. R. Shanthini January 07, 2012 By installing scrubbers and electrostatic precipitators in the smokestacks of power plants, sulfur emissions lower have been lowered (though not eliminated totally). http://airawareness.webs.com/smog.htm Non-renewable Energy Source: Coal EKC for sulfur dioxide was discussed Prof. R. Shanthini January 07, 2012 Non-renewable Energy Source: Coal Smog: Photochemical Photochemical smog refers to ground-level ozone (O3). Ozone is formed when nitrogen oxides (primarily from vehicle exhaust) and volatile organic compounds (from paints, solvents, and fuel evaporation) interact in the presence of sunlight. Ozone in the stratosphere protects earth from harmful UV radiation, ozone on the ground is hazardous to human health. The catalytic converters break down the vehicular pollutants when they are released through them. Nitrogen oxides are split into pure oxygen and nitrogen. Water vapors and carbon dioxide are released instead of carbon particles. Prof. R. Shanthini January 07, 2012 Non-renewable Energy Source: Coal - Sulfur contained in coal forms sulfur dioxide when burned. - Harmful nitrogen oxides is also released into the air during coal burning. - Heavy metals (such as lead, mercury, nickel, tin, cadmium, antimony and arsenic) are released into the environment during mining and burning of coal. - Radio isotopes of uranium and thorium are also released. - The toxic fly ash remaining after coal burning is also an environmental concern and is usually disposed into landfills. - Coal sludge is the liquid generated by washing coal. It is disposed of at impoundments or directly injected back into abandoned underground mines. Prof. R. Shanthini January 07, 2012 Non-renewable Energy Source: Coal Global CO2 emissions from the burning of fossil fuels & the manufacture of cement (in 109 kg CO2): 12000 10000 8000 6000 from solid fuel burning from liquid fuel burning from gas fuel burning from cement production from gas flaring 4000 2000 0 1750 Prof. R. Shanthini January 07, 2012 1800 1850 1900 Year 1950 2000 Source: http://cdiac.ornl.gov/trends/emis/glo.html Non-renewable Energy Source: Coal 29.6% of global primary energy needs in 2010. Global Coal Production (Million Tonnes) 42% of global electricity needs is provided by coal. 8000 7273 6000 4000 4718 4693 1990 2000 year 2000 0 Prof. R. Shanthini January 07, 2012 2010 BP Statistical Review of World Energy 2011 Non-renewable Energy Source: Coal Reserves-to-Production (R/P) ratios: World proved coal reserves in 2010 were sufficient to meet 118 years of global production, which is well below the 2000 value of 210 years. World R/P ratio Prof. R. Shanthini January 07, 2012 BP Statistical Review of World Energy 2011 Non-renewable Energy Source: Coal Peak Coal Prof. R. Shanthini January 07, 2012 Source: TW Patzek and GD Croft A global coal production forecast with multi-Hubbert cycle analysis Energy, Vol 35, Issue 8, August 2010, Pages 3109-3122 Non-renewable Energy Source: Coal Coal is most cheaply mined from near-surface deposits using strip mining techniques. Prof. R. Shanthini January 07, 2012 Strip mining for coal (1) Blast hole drilled, explosives planted Coal deposits (1) (2) (3) (4) (5) Cross-section of typical mountain and valley in Kentucky Prof. R. Shanthini January 07, 2012 Source: www.wesjones.com/death.htm Strip mining for coal (2) Blast hole fractures overburden Overburden: Foliage, top soil, rocks (1) (2) (3) (4) Cross-section of typical mountain and valley in Kentucky Prof. R. Shanthini January 07, 2012 (5) Bench cuts made by blasting Source: www.wesjones.com/death.htm Strip mining for coal (3) Overburden Removed by dragline excavator Overburden: Foliage, top soil, rocks (1) (2) (3) (4) Cross-section of typical mountain and valley in Kentucky Prof. R. Shanthini January 07, 2012 (5) Bench cuts made by blasting Source: www.wesjones.com/death.htm Strip mining for coal Dragline excavator Prof. R. Shanthini January 07, 2012 Source: http://www.pbs.org/independentlens/razingappalachia/mtop.html Strip mining for coal (4) Overburden Dumped into valley Overburden: Foliage, top soil, rocks (1) (2) (3) (4) Cross-section of typical mountain and valley in Kentucky Prof. R. Shanthini January 07, 2012 (5) Bench cuts made by blasting Source: www.wesjones.com/death.htm Strip mining for coal (5) Coal removed Overburden: Foliage, top soil, rocks (1) (2) (3) (4) Cross-section of typical mountain and valley in Kentucky Prof. R. Shanthini January 07, 2012 (5) Bench cuts made by blasting Source: www.wesjones.com/death.htm Strip mining for coal Let us discuss the sustainability issues in strip mining for coal Cross-section after mountaintop has been removed Prof. R. Shanthini January 07, 2012 Valley filled with spoil Nine men – that is all it takes to bring this mountain low Source: www.wesjones.com/death.htm Mountaintop removal coal mines have changed the shape, altitude, and ecology of large areas of the Appalachian coalfields. This photograph shows part of the Kayford Mountain Mine in West Virginia on October 22, 2006. Prof. R. Shanthini January 07, 2012 http://earthobservatory.nasa.gov/Features/MountaintopRemoval/ Mountaintop removal coal mines have changed the shape, altitude, and ecology of large areas of the Appalachian coalfields. This photograph shows part of the Kayford Mountain Mine in West Virginia on October 22, 2006. Prof. R. Shanthini January 07, 2012 http://earthobservatory.nasa.gov/Features/MountaintopRemoval/ Prof. R. Shanthini January 07, 2012 Non-renewable Energy Source: Coal - Downstream of mountaintop removal and valley fill sites, water quality and stream life are often degraded. - Water, streambed sediments, and fish tissue often harbor concentrations of potentially toxic trace elements, including nickel, lead, cadmium, iron, and selenium, that exceed government standards. - The diversity of fish and other aquatic life declines. Hundreds of thousands of acres of some of the world’s most biologically diverse forests outside of the tropics have been lost or degraded, and, to date, efforts to restore them have had limited success. - Valley fills have worsened flash flooding during heavy rain events. Blasting has cracked house foundations. - Floods from the collapse of valley fills and coal sludge impoundments, though rare, have devastated some watersheds and communities. Prof. R. Shanthini January 07, 2012 http://earthobservatory.nasa.gov/Features/MountaintopRemoval In 2000, 60 out of the 170 million tons of coal mined in West Virginia were from strip mines. 300,000 acres of hardwood forest in West Virginia have been destroyed by mountaintop removal practiced in strip mining. 75% of West Virginia's streams and rivers are polluted by mining and other industries. Prof. R. Shanthini January 07, 2012 Over 1000 miles of streams have been buried by strip mine waste in Appalachian Mountains that run through 13 states. Source: http://www.pbs.org/independentlens/razingappalachia/mtop.html Non-renewable Energy Source: Coal - Sub-surface mining of coal is less damaging to the surface environment, but is much more hazardous for the miners due to tunnel collapses and gas explosions. Prof. R. Shanthini January 07, 2012 Non-renewable Energy Source: Crude Oil - Crude oil (liquid petroleum) forms underground in rock such as shale, which is rich in organic materials. - After the oil forms, it migrates upward into porous reservoir rock such as sandstone or limestone, where it can become trapped by an overlying impermeable cap rock. - Wells are drilled into these oil reservoirs to remove the gas and oil. - Over 70 percent of oil fields are found near tectonic plate boundaries. Prof. R. Shanthini January 07, 2012 Non-renewable Energy Source: Crude Oil - Primary stage of oil recovery involves pumping oil from reservoirs under the normal reservoir pressure. About 25% of the oil in a reservoir can be removed during this stage. - Secondary oil recovery stage involves injecting hot water into the reservoir around the well. This water forces the remaining oil toward the area of the well from which it can be recovered. - Tertiary stage of recovery is used in order to remove as much oil as possible. This involves pumping steam, carbon dioxide gas or nitrogen gas into the reservoir to force the remaining oil toward the well. It is known as enhanced oil recovery (EOR). Prof. R. Shanthini January 07, 2012 Non-renewable Energy Source: Crude Oil - EOR is very expensive and can cost up to half of the value of oil removed. - Carbon dioxide used in this method remains sequestered in the deep reservoir, thus mitigating its potential greenhouse effect on the atmosphere. Carbon Capture and Storage (CCS) Prof. R. Shanthini January 07, 2012 Non-renewable Energy Source: Crude Oil Naptha Gasoline Gas Kerosene Diesel Prof. R. Shanthini January 07, 2012 Crude Oil Fuel Oil Lubricating Oil Tar Laboratory scale production Naptha Gasoline Distillation Gas Kerosene Diesel Prof. R. Shanthini January 07, 2012 Crude Oil Fuel Oil Lubricating Oil Tar Industrial production Crude oil distillation products Carbon atoms Boiling range Petroleum Gas C1 to C4 < 40oC Naphtha C5 to C9 60 to 100oC Gasoline C5 to C12 40 to 205oC Kerosene C10 to C18 175 to 325oC Diesel (Gas Oil) C12 and more 250 to 350oC Lubricating Oil C20 to C50 300 to 370oC Fuel Oil (Heavy Gas) C20 to C70 370 to 600oC Residuals C70 and more > 600oC Prof. R. Shanthini January 07, 2012 Industrial production Products Uses Petroleum Gas used for cooking, heating and making plastics Naphtha intermediate that will be further processed to make gasoline Gasoline motor fuel Kerosene fuel for jet engines and tractors; starting material for making other products Diesel (Gas Oil) used for diesel fuel and heating oil; starting material for making other products Lubricating Oil used for motor oil, grease, other lubricants Fuel Oil (Heavy Gas) used for industrial fuel; starting material for making other products Residuals coke, asphalt, tar, waxes; starting material for making other products Prof. R. Shanthini January 07, 2012 LPG Industrial production Distillation column Petrol Crude Oil Kerosene Diesel Fuel oil Lubricating oil Paraffin Wax Prof. R. Shanthini January 07, 2012 Furnace Tar (Asphalt) Prof. R. Shanthini January 07, 2012 Prof. R. Shanthini January 07, 2012 Prof. R. Shanthini January 07, 2012 Non-renewable Energy Source: Crude Oil Global Oil Production (Million tonnes) 33.5% of global primary energy needs in 2010 4500 4000 3500 3000 2500 2000 1500 1000 500 0 3612 3172 1990 Prof. R. Shanthini January 07, 2012 3914 2000 year 2010 BP Statistical Review of World Energy 2011 Non-renewable Energy Source: Crude Oil - An equivalent amount of oil produces more kilowatts of energy than coal. - CO2 emissions are lower than its energy equivalent coal. - It also burns cleaner, producing about 50 percent less sulfur dioxide. Prof. R. Shanthini January 07, 2012 http://cnx.org/content/m16730/latest/ Non-renewable Energy Source: Crude Oil - Burning of oil releases atmospheric pollutants such as sulfur dioxide, nitrogen oxides, carbon dioxide and carbon monoxide. - These gases are smog-precursors that pollute the air and greenhouse gases that contribute to global warming. - Substantial oil reserves lie under the ocean. Oil spill accidents involving drilling platforms kill marine organisms and birds. - Some reserves such as those in northern Alaska occur in wilderness areas. - The building of roads, structures and pipelines to support oil recovery operations can severely impact the wildlife in those natural areas. Prof. R. Shanthini January 07, 2012 Non-renewable Energy Source: Crude Oil Global CO2 emissions from the burning of fossil fuels & the manufacture of cement (in 109 kg CO2): 12000 10000 8000 6000 from solid fuel burning from liquid fuel burning from gas fuel burning from cement production from gas flaring 4000 2000 0 1750 Prof. R. Shanthini January 07, 2012 1800 1850 1900 Year 1950 2000 Source: http://cdiac.ornl.gov/trends/emis/glo.html Non-renewable Energy Source: Crude Oil Reserves-to-Production (R/P) ratios: World proved oil reserves in 2010 were sufficient to meet 46.2 years of global production. World R/P ratio Prof. R. Shanthini January 07, 2012 BP Statistical Review of World Energy 2011 Non-renewable Energy Source: Crude Oil Peak Oil Production from Mexico's largest oilfield, Cantarell, fell from 1.99 million b/d in Jan 2006 to 1.44 million b/d in Dec 2006. Prof. R. Shanthini January 07, 2012 Source: http://www.hubbertpeak.com/mx/ Non-renewable Energy Source: Crude Oil Peak1600 Oil Proved Reserves (1000 million barrels) 1400 1383 1200 1000 800 1105 1003 600 400 200 0 1990 Prof. R. Shanthini January 07, 2012 2000 year 2010 BP Statistical Review of World Energy 2011 Well number 34 has run dry and is now pumping fossils Prof. R. Shanthini January 07, 2012 Source: www.cartoonstock.com/directory/f/fossil_fuel.asp Non-renewable Energy Source: Crude Oil Crude oil prices since 1861 US$ per barrel $2010 Money of the day Prof. R. Shanthini January 07, 2012 BP Statistical Review of World Energy 2011 Non-renewable Energy Source: Oil Shale - Oil shale is an organic-rice sedimentary rock with very fine pores that contain kerogen, a carbon-based, waxy substance. - If shale is heated to 490º C, the kerogen vaporizes and can then be condensed as shale oil, a thick viscous liquid. - This shale oil is generally further refined into usable oil products. - Production of shale oil requires large amounts of energy for mining and processing the shale. - About a half barrel of oil is required to extract every barrel of shale oil. Prof. R. Shanthini January 07, 2012 http://cnx.org/content/m16730/latest/ Non-renewable Energy Source: Oil Shale - Oil shale is plentiful, with estimated reserves totaling 3 trillion barrels of recoverable shale oil. - These reserves alone could satisfy the world's oil needs for about 100 years. - Environmental problems associated with oil shale recovery include: - large amounts of water needed for processing, - disposal of toxic waste water, and - disruption of large areas of surface lands. Prof. R. Shanthini January 07, 2012 http://cnx.org/content/m16730/latest/ Non-renewable Energy Source: Tar Sands - Tar sands (oil sands) are a combination of clay, sand, water and bitumen (a heavy black viscous oil). - This thick crude does not flow easily and thus normal oil recovery methods cannot be used to mine it. - Tar sand deposits are mined, usually using strip mining or open pit techniques, if tar sands are near the surface. - Tar sands are processed to extract the oil-rich bitumen, which is then refined into oil. - In order to extract the oil from deep-seated tar sands, steam must be injected into the reservoir to make the oil flow better and push it toward the recovery well. - The energy cost for producing a barrel of tar sand is similar to that for oil shale. Prof. R. Shanthini January 07, 2012 http://cnx.org/content/m16730/latest/ Non-renewable Energy Source: Tar Sands - The largest tar-sand deposit in the world is in Canada (Alberta) and contains enough material (about 500 billion barrels) to supply the world with oil for about 15 years. - Environmental problems associated with tar sands recovery include: - greenhouse gas emissions and global warming - impacts of wildlife and air and water quality - large amounts of water needed for processing (several barrels of water for each barrel fo water produced) - disposal of toxic waste water, and - disruption of large areas of surface lands. Prof. R. Shanthini January 07, 2012 http://cnx.org/content/m16730/latest/ Non-renewable Energy Source: Crude Oil & Oil Sands 1600 Proved Reserves (1000 million barrels) 1400 Crude oil Oil sands 1200 1000 800 600 400 200 0 1990 Prof. R. Shanthini January 07, 2012 2000 year 2010 BP Statistical Review of World Energy 2011 Non-renewable Energy Source: Natural Gas Global Gas Production (Million tonnes) 23.8% of global primary energy needs in 2010 3500 3000 2500 2881 2000 1500 2179 1790 1000 500 0 1990 Prof. R. Shanthini January 07, 2012 2000 year 2010 Non-renewable Energy Source: Natural Gas Reserves-to-Production (R/P) ratios: World proved oil reserves in 2010 were sufficient to meet 58.6 years of global production. World R/P ratio Prof. R. Shanthini January 07, 2012 BP Statistical Review of World Energy 2011