Transcript VERSAMID INK RESINS - Gabriel Performance Products

Gabriel Performance Products
Who We Are
 40 Acre Manufacturing Facility
located in Ashtabula, Ohio
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Formerly Occidental Chemical
Corporation – Designed Products
Gabriel Performance Products
was formed June 29, 2001
 Primary Operations – Custom &
Contract Manufacturing
Operating Disciplines
 Quality
 ISO 9001:2000
 Safety and Health
 OSHA Process Safety
Management
 Environmental
 EPA Risk Management Plan
 Responsible Care
 SOCMA Awardee 2005
Custom Manufacturing Capabilities
 Core Technology
 Safe Handling of …
-Epichlorohydrin (bulk)
- Formaldehyde (bulk)
- Hydrogen Sulfide (bulk)
- Cyanide, Isocyanates
- Solvents
- Chlorine (bulk)
 Equipment – Multi-purpose
- 750 – 6,000 gal. reactor, glass lined, nickel,
stainless (total of 12 reactor lines)
Organization – Key Contacts
 Ken Allen – President
 Len Boehm – Executive Vice President
 Ron Cimmino – Director, Distribution and
Corporate Accounts
 Kelly Lahner – Customer Service Manager/
Operations
 Linda Wright – Administrative Assistant
Formulation consultant - Dr. Dave Dunn
 Former VP of R&D and New Business
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Development for Loctite
Supported a $100MM+ business
Over 35 years experience in R&D
40+ patents and papers
4 books
BS, MS and PhD in Chemistry
Dr. Dave Dunn
Member of the Editorial Advisory Board of
Adhesives and Sealants Industry Magazine and
writes the monthly Q & A column entitled
“AskDr. Dave”
Dr. Dave Dunn
Helped to produce and was on-screen
presenter for the History Channel’s Modern
Marvels program on “Glue”
Gabriel Primary Markets
 Industrial Markets
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Adhesives
Sealants
Coatings
Lubricants
Sulfur Chemistry Expertise
 Over 40 years of manufacturing
experience making mercaptan resins
and organo-sulfides
 Safe handling of bulk hydrogen
sulfide, sulfur, and sodium
hydrosulfide
Sulfur Chemistry Expertise
R [O(C3H6O)nCH2CHCH2SH]3
OH
 GPM-800
 Mercaptan-terminated
Polymer
 Used as an epoxy-curing agent
Used in thin film cures
 Rapid-cure characteristics
 Can be used at lower temperatures
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Mercaptan History
Ashtabula Plant
1966 Capcure Launch
Diamond Shamrock
Occidental Chemical
Oxy Chem
2001
Gabriel
Ashtabula Plant
Oxy Chem
1986
Henkel
Henkel
1987
Cognis
1999
Mercaptans Today
Gabriel Performance Products is America’s
original and only manufacturer of mercaptan
epoxy curing agents
GABRIEL GPM MERCAPTAN
EPOXY HARDENERS
POLY-FUNCTIONAL MERCAPTAN
HARDENERS for FAST CURE of EPOXIES
Polymercaptan Advantages
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Rapid Cure of Epoxies
Low-Temperature Cure
Thin-Film Cure
Low Toxicity
Light Color
Excellent Adhesion
1:1 mix ratio – not critical
Acceleration ability with other curatives
e.g. amines, polyamides, anhydrides
etc.
Polymercaptan Applications
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Consumer & Industrial Adhesives
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Coatings
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Sealants
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Industrial Patch & Filler Kits
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Floor & Flooring Repair
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Electrical & Electronics
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Acceleration of Other Epoxy Systems
Polymercaptan Applications
GPM Product Line
 GPM-800
 5 min. gel time uncatalyzed product
 GPM-800LO
Low odor version of GPM-800
 GPM-888
 5 min. gel time pre-catalyzed product
 GPM-895 FC
 40 sec gel time pre-catalyzed product
 GPM-890 CB
 90 sec gel time pre-catalyzed product
 GPM-830 CB
 30 min. gel time pre-catalyzed product
 GPM-891
 5 min. gel time non-yellowing
pre-catalyzed product
 GPM-845 MT
 5 min. gel time pre-catalyzed,
low viscosity, highest moisture tolerance
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Cognis equivalent
Capcure 3800
Capcure LOF
Capcure 3830-81
Capcure 40 SEC HV
Capcure 3850-101
Capcure WR-6
GPM Product Line
Gabriel also markets GPA 30, a tertiary amine catalyst that is equivalent to Air
Products Ancamine K54 or Cognis EH 30
GPM-800 Product Characteristics
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Uncatalyzed
• Theoretical Thio Equivalent Weight – 270
• 110 Parts of GPM-800 for 100 Parts of 190 EEW
Epoxy Resin
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Five Minute Gel Time With Catalyst
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Rapid Strength Development
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Light Color / Moderate Odor
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Excellent Acceleration Properties
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Low Toxicity
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Performance offset for Cognis’ Capcure 3-800
GPM Product Line
 GPM-800
 5 min. gel time uncatalyzed product
 GPM-800LO
Low odor version of GPM-800
 GPM-888
 5 min. gel time pre-catalyzed with GPA 30
 GPM-895 FC
 40 sec gel time pre-catalyzed product
 GPM-890 CB
 90 sec gel time pre-catalyzed product
 GPM-830 CB
 30 min. gel time pre-catalyzed product
 GPM-891
 5 min. gel time non-yellowing
pre-catalyzed product
 GPM-845 MT
 5 min. gel time pre-catalyzed,
low viscosity, highest moisture tolerance
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Cognis equivalent
Capcure 3800
Capcure LOF
Capcure 3830-81
Capcure 40 SEC HV
Capcure 3850-101
Capcure WR-6
GPM-800 LO Product Characteristics
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Same performance as GPM-800 but specially treated to reduce
odor
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Performance offset for Cognis’ Capcure LOF
GPM Product Line
 GPM-800
 5 min. gel time uncatalyzed product
 GPM-800LO
Low odor version of GPM-800
 GPM-888
 5 min. gel time pre-catalyzed product
 GPM-895 FC
 40 sec gel time pre-catalyzed product
 GPM-890 CB
 90 sec gel time pre-catalyzed product
 GPM-830 CB
 30 min. gel time pre-catalyzed product
 GPM-891
 5 min. gel time non-yellowing
pre-catalyzed product
 GPM-845 MT
 5 min. gel time pre-catalyzed,
low viscosity, highest moisture tolerance
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Cognis equivalent
Capcure 3800
Capcure LOF
Capcure 3830-81
Capcure 40 SEC HV
Capcure 3850-101
Capcure WR-6
GPM-888 Product Characteristics
Pre-catalyzed
• 8:1 blend of GPM-800: tertiary amine catalyst GPA 30
• Theoretical Thio Equivalent Weight – 190
• 100 Parts of GPM-888 for 100 Parts of 190 EEW Epoxy
Resin
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Five Minute Gel Time
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Rapid Strength Development
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Light Color / Moderate Odor
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Excellent Acceleration Properties
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Low Toxicity
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Performance offset for Cognis’ Capcure 3830-81
Five Minute Clear adhesive
Resin
Percent
Mixed 1:1 with
Hardener
Epoxy resin1
78
GPM-888
Epoxy resin2
20
Fumed silica
Fumed silica
2
1.
Standard BADGE epoxy,EEW 185-190
2.
Aliphatic epoxy
Percent
98
2
Five Minute Metallic Paste
Resin
Percent
Mixed 1:1 with
Hardener
Percent
Epoxy resin1
45
GPM-888
35
Barytes
20
DETDA
8
Whiting
20
Triphenyl phosphite 2
Iron oxide
14
Barytes
10
Fumed silica
1
Kaolin
6
Ca carbonate
35
TiO2
3
Fumed silica
1
1.Standard BADGE epoxy,EEW 185-190
Five Minute Epoxy Putty
Resin
Epoxy resin1
Percent
Mixed 1:1 with
35
Hardener
GPM 888
Percent
38
Glass microspheres 10
Glass microspheres 10
Zinc sulfide
Powdered talc
Powdered talc
5
50
1.Standard BADGE epoxy,EEW 185-190
52
GPM-800 or 888 Typical data/properties
Resin
Epoxy resin1
Parts
Mixed 1:1 with
100
Hardener
GPM-800
GPA-30
Gel time, 60gram mass
2.5 min
Gel time, .015” film
5.5 min
Shows relative insensitivity to mass of sample
1. Standard BADGE epoxy,EEW 185-190
Parts
100
10
GPM-800 or 888 Typical data/properties
Hardness, Shore D
After 5 mins
18
20 mins
47
1 hr
84
24 hr
84
Shows the rapid development of properties
GPM-800 or 888 Typical data/properties
Lap shear strength, psi
Aluminum, etched
2870
Aluminum, untreated
1845
Mild steel, sandblasted
3525
TPE polyester, abraded
147
Thermoplastic olefin, abraded
226
Shows outstanding adhesion to metals –epoxies have limited
performance on plastics
GPM Product Line Customized Blends
Characteristics
 GPM-800 Blends
 Cure-Time tailored to Customer
Requirements;
• 40-Seconds to 30-Minutes
 Special Effects
 Unique Applications
GPM Product Line
 GPM-800
 5 min. gel time uncatalyzed product
 GPM-800LO
Low odor version of GPM-800
 GPM-888
 5 min. gel time pre-catalyzed product
 GPM-895 FC
 40 sec gel time pre-catalyzed product
 GPM-890 CB
 90 sec gel time pre-catalyzed product
 GPM-830 CB
 30 min. gel time pre-catalyzed product
 GPM-891
 5 min. gel time non-yellowing
pre-catalyzed product
 GPM-845 MT
 5 min. gel time pre-catalyzed,
low viscosity, highest moisture tolerance
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Cognis equivalent
Capcure 3800
Capcure LOF
Capcure 3830-81
Capcure 40 SEC HV
Capcure 3850-101
Capcure WR-6
GPM-895 FC Product Characteristics
• Mix 1:1 with standard epoxy resins
• Fixture times of 40 seconds
• Leads to “instant epoxies”, as fast as superglue for
consumer adhesives
• Ideal for two-component mixing/metering equipment for
assembly line use.
• Fast cure results in greater productivity.
• Fixture time easily modified from fast to slow
Performance offset for Cognis’ Capcure 40secHV
GPM Product Line
 GPM-800
 5 min. gel time uncatalyzed product
 GPM-800LO
Low odor version of GPM-800
 GPM-888
 5 min. gel time pre-catalyzed product
 GPM-895 FC
 40 sec gel time pre-catalyzed product
 GPM-890 CB
 90 sec gel time pre-catalyzed product
 GPM-830 CB
 30 min. gel time pre-catalyzed product
 GPM-891
 5 min. gel time non-yellowing
pre-catalyzed product
 GPM-845 MT
 5 min. gel time pre-catalyzed,
low viscosity, highest moisture tolerance
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Cognis equivalent
Capcure 3800
Capcure LOF
Capcure 3830-81
Capcure 40 SEC HV
Capcure 3850-101
Capcure WR-6
GPM-890 CB and 830 CB Product
Characteristics
• These are pre-catalyzed custom blends designed for 90
second and 30 minute gel times respectively
• These blends are unique to Gabriel with no direct offsets
from competitors
GPM Product Line
 GPM-800
 5 min. gel time uncatalyzed product
 GPM-800LO
Low odor version of GPM-800
 GPM-888
 5 min. gel time pre-catalyzed product
 GPM-895 FC
 40 sec gel time pre-catalyzed product
 GPM-890 CB
 90 sec gel time pre-catalyzed product
 GPM-830 CB
 30 min. gel time pre-catalyzed product
 GPM-891
 5 min. gel time non-yellowing
pre-catalyzed product
 GPM-845 MT
 5 min. gel time pre-catalyzed,
low viscosity, highest moisture tolerance
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Cognis equivalent
Capcure 3800
Capcure LOF
Capcure 3830-81
Capcure 40 SEC HV
Capcure 3850-101
Capcure WR-6
GPM-891 FC Product Characteristics
 Blend of GPM-800 and a special catalyst
 Produces ultra-clear formulations
 Reduced tendency to yellow
 The most widely used curative in Europe for consumer
epoxy adhesives
Performance offset for Cognis’ Capcure 3850-101
GPM Product Line
 GPM-800
 5 min. gel time uncatalyzed product
 GPM-800LO
Low odor version of GPM-800
 GPM-888
 5 min. gel time pre-catalyzed product
 GPM-895 FC
 40 sec gel time pre-catalyzed product
 GPM-890 CB
 90 sec gel time pre-catalyzed product
 GPM-830 CB
 30 min. gel time pre-catalyzed product
 GPM-891
 5 min. gel time non-yellowing
pre-catalyzed product
 GPM-845 MT
 5 min. gel time pre-catalyzed,
low viscosity, highest moisture tolerance
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Cognis equivalent
Capcure 3800
Capcure LOF
Capcure 3830-81
Capcure 40 SEC HV
Capcure 3850-101
Capcure WR-6
GPM-845 MT Product Characteristics
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Use at 80 Parts of GPM-845MT for 100 Parts of 190 EEW epoxy
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Rapid Cures
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Improved Low Temperature Cures
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Rapid Thin Film Cures, even below freezing
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Improved Moisture Resistance for outdoor applications
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Low Viscosity allows high filler loadings
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Gel Time Control by adding weak acids
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Ideal for outdoor construction applications
Performance offset for Cognis’ Capcure WR-6
Concrete construction adhesive for low temperature
applications
Resin
Parts
Mixed 1:1 with
Hardener
Parts
Epoxy resin1
42
GPM 845MT
85
Epoxy Novolac
45
Wollastonite
106
Epoxy diluent
13
Silica flour
10
Silane A-187
1.5
Defoamer
0.2
Wollastonite
120
Aromatic oil
7.33
Defoamer
2.0
Fumed silica
0.3
1. Standard BADGE epoxy,EEW 185-190
Summary of GPM products
Typical Gel
time
Fastest cure
Water
resistant
Ultraclear
Pre-catalyzed
Room temp
cure
GPM800
GPM-800
LO
GPM888
GPM895FC
GPM-890
CB
GPM-830
CB
GPM891
GPM-845
MT
5 min
5 min
5min
40 sec
90 sec
30 min
5 min
5 min
The Gabriel Advantage
• Manufactured polymercaptans and organo-sulfur
compounds for over 40 years
• ISO 9001:2000 quality
• Can offer customized polymercaptans
• Not just a raw material supplier – can offer
formulation assistance
• Committed to new product development to
expand product line
• Commitment to quality, service, and VALUE.
Traditional Market Applications
 Consumer adhesives
 Auto aftermarket adhesives & repair compounds
 Hobby & crafts adhesives and coatings
 Industrial adhesives
 Electrical/electronic adhesives/potting
 Concrete grouts and repair compounds
 Coatings
Strategic Growth Plan
 Markets for Growth
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Road Markers / Traffic Paint
NSF Potable Water applications
Commercial Flooring – Low Odor [ 800LO]
Metal Tanks / Drums/ Rail / Bridge Coatings
Insulated Glass / Window Assembly [Polysulfide]
Electronics – Circuit Boards
Anchor Bolts / Cement
Joint Sealant Compounds
Composites – Aerospace
Composites – Industrial
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Manhole Covers
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Cat – Walk
Windmill Blades
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Reminder of Key Selling Points
 GPM mercaptans:
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Fast controllable curing from seconds to minutes – “dial a
speed”
Modern 2 component syringes/cartridges are ideal for
measuring and mixing fast systems with 1: 1 mix ratios
Low temperature cures to 16 deg F or below –most epoxies
do not cure below 40 deg F
No amine “blush” or induction times
Safe to handle, e.g. NSF Standard 61 approval readily
obtained
Mercaptans do not require “corrosive “labeling for shipping
Acceleration ability with other curatives
Gabriel – Value Proposition
“ Competitive Advantage”
 Flat & responsive Management Team
 Pro-active Customer Service
- Kelly Lahner
- Tammy Kassay
 Experienced Lab/ Tech Service – Formulary Expertise
- Dr. Dave Dunn
 GPM – 800 Series – Complete and Diversified portfolio
 In Depth Technology
 Manufacturing Capability
-Flexible
-Global Capacity
-Customization
-ISO Quality Certification
Gabriel – Value Proposition
“ Competitive Advantage” cont’d
 Consistent and Lower Color –Gardner Scale
 Consistent and Lower Metals – Fe “Iron” Content
-”Pinking” Phenomenon
- “Blushing”
 Lower Odor
-Variety of masking agents
 Customer Focus – Receptive to LTL custom blends
 Commitment – Investment for quality and growth
 Improved Adhesion Performance
Gabriel Performance Products
“Competitive Profile”
 Cognis – Capcure Line ™-made in Spain
 TORAY (Japan) - THIOL
-Chemistry
 LAREDO (Mexico)
-modified hydrogen sulfide chemistry
 ARNETTE LTD (USA)
-Limited line of amines
-Mercaptan Blends – select few
 HUNTSMAN (USA & UK)
-Mercaptan Blends – select few
-”ARALDITE” ™
GABEPRO – Looking Forward!
 Volume has priority relative to price
 Protect and Grow GPM Business
 Focus on “Blends”
 Customization of formulas
 The original and only domestic source of
Mercaptans
 Have fun!